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Title: Valence photodetachment of Li{sup -} and Na{sup -} using relativistic many-body techniques

Journal Article · · Physical Review. A
;  [1];  [2];  [3];  [1]
  1. Department of Physics, Indian Institute of Technology Madras, Chennai-600036 (India)
  2. Institute of Physics, Pregrevica 118, P.O. Box 68, 11080 Beograd-Zemun (Serbia)
  3. Department of Physics and Astronomy, Georgia State University, Atlanta, Georgia 30303 (United States)

The multiconfiguration Tamm-Dancoff technique (MCTD) is applied to study photodetachment of negative ions of lithium and sodium. A cusplike structure is found in the photodetachment cross section just below the first detachment-plus-excitation threshold of Li{sup -} (Li 2p), and of Na{sup -} (Na 3p), in qualitative agreement with existing theoretical and experimental results. The current work emphasizes the importance of correlation in the form of configuration interaction in the photodetachment process and demonstrates the utility of MCTD in dealing with highly correlated systems.

OSTI ID:
21546802
Journal Information:
Physical Review. A, Vol. 83, Issue 5; Other Information: DOI: 10.1103/PhysRevA.83.053419; (c) 2011 American Institute of Physics; ISSN 1050-2947
Country of Publication:
United States
Language:
English