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Title: Ionization potential for excited S states of the lithium atom

Journal Article · · Physical Review. A
 [1];  [2];  [1]
  1. Faculty of Physics, University of Warsaw, Hoza 69, PL-00681 Warsaw (Poland)
  2. Faculty of Chemistry, Nicolaus Copernicus University, Gagarina 7, PL-87100 Torun (Poland)

Nonrelativistic, relativistic, quantum electrodynamic, and finite nuclear mass corrections to the energy levels are obtained for the nS{sub 1/2},n=3,...,9 states of the lithium atom. Computational approach is based on the explicitly correlated Hylleraas functions with the analytic integration and recursion relations. Theoretical predictions for the ionization potential of nS{sub 1/2} states and transition energies nS{sub 1/2{yields}}2S{sub 1/2} are compared to known experimental values for {sup 6,7}Li isotopes.

OSTI ID:
21528868
Journal Information:
Physical Review. A, Vol. 82, Issue 6; Other Information: DOI: 10.1103/PhysRevA.82.062509; (c) 2010 American Institute of Physics; ISSN 1050-2947
Country of Publication:
United States
Language:
English