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Title: Doppler effect in fragment autoionization following core-to-valence excitation in O{sub 2}

Journal Article · · Physical Review. A
; ;  [1]
  1. Universite Pierre et Marie Curie, Laboratoire de Chimie Physique-Matiere et Rayonnement, UMR 7614, 11 rue Pierre et Marie Curie, F-75231 Paris Cedex 05, France and Centre National de la Recherche Scientifique, Laboratoire de Chimie Physique-Matiere et Rayonnement, UMR 7614, 11 rue Pierre et Marie Curie, F-75231 Paris Cedex 05 (France)

Atomic autoionization following O 1s resonant excitation in O{sub 2} is studied using high-resolution electron spectroscopy. The resonant Auger spectrum showing evidence of ultrafast dissociation as well as the autoionization of oxygen atoms is measured and discussed. Evidence of the electronic Doppler effect is observed in both electronic decay mechanisms.

OSTI ID:
21528552
Journal Information:
Physical Review. A, Vol. 82, Issue 5; Other Information: DOI: 10.1103/PhysRevA.82.051401; (c) 2010 The American Physical Society; ISSN 1050-2947
Country of Publication:
United States
Language:
English