Multilayered Al/CuO thermite formation by reactive magnetron sputtering: Nano versus micro
- CNRS-LAAS, 7 Avenue du Colonel Roche, F-31077 Toulouse (France)
- UPS, INSA, INP, ISAE, LAAS, Universite de Toulouse, F-31077 Toulouse (France)
- CIRIMAT, 118 route de Narbonne, 31062 Toulouse Cedex 04 (France)
- Department of Materials Science and Engineering, University of Texas at Dallas, 800 W. Campbell Rd., RL 10 Richardson, Texas 75080 (United States)
Multilayered Al/CuO thermite was deposited by a dc reactive magnetron sputtering method. Pure Al and Cu targets were used in argon-oxygen gas mixture plasma and with an oxygen partial pressure of 0.13 Pa. The process was designed to produce low stress (<50 MPa) multilayered nanoenergetic material, each layer being in the range of tens nanometer to one micron. The reaction temperature and heat of reaction were measured using differential scanning calorimetry and thermal analysis to compare nanostructured layered materials to microstructured materials. For the nanostructured multilayers, all the energy is released before the Al melting point. In the case of the microstructured samples at least 2/3 of the energy is released at higher temperatures, between 1036 and 1356 K.
- OSTI ID:
- 21476564
- Journal Information:
- Journal of Applied Physics, Vol. 108, Issue 8; Other Information: DOI: 10.1063/1.3498821; (c) 2010 American Institute of Physics; ISSN 0021-8979
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
ALUMINIUM
ARGON
CALORIMETRY
COMPARATIVE EVALUATIONS
COPPER OXIDES
CRYSTAL STRUCTURE
DEPOSITION
DIFFERENTIAL THERMAL ANALYSIS
FABRICATION
INTERFACES
LAYERS
MICROSTRUCTURE
NANOSTRUCTURES
OXYGEN
PLASMA
SPUTTERING
STRESSES
CHALCOGENIDES
COPPER COMPOUNDS
ELEMENTS
EVALUATION
FLUIDS
GASES
METALS
NONMETALS
OXIDES
OXYGEN COMPOUNDS
RARE GASES
THERMAL ANALYSIS
TRANSITION ELEMENT COMPOUNDS