A novel extended architecture with 4{sup 6}.6{sup 4} topology based on mixed-valence Wells-Dawson arsenotungstate and mixed-ligand Cu(I) units

Journal Article · Wed Sep 15 00:00:00 EDT 2010 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/j.jssc.2010.07.004· OSTI ID:21432470

Ruizhan, Tong; Xiaoyu, Ren; Zuoxi, Li; Bin, Liu; Huaiming, Hu ^[1]; Feng, Fu; Jiwu, Wang ^[2]

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1. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Department of Chemistry, Northwest University, Xi'an 710069 (China)
2. Department of Chemistry, Yanan University, Yan'an 716000 (China)

A novel inorganic-organic hybrid compound based on mixed-valence Wells-Dawson arsenotungstate and mixed-ligand Cu(I) units, Cu{sub 8}{sup I}(imi){sub 4}(bpy){sub 6}(H{sub 2}O)[As{sub 2}{sup V}W{sub 2}{sup V}W{sub 16}{sup Vl}O{sub 62}].2H{sub 2}O (1) (bpy=4,4'-bipydine; imi=imidazole), has been hydrothermally synthesized and characterized by elemental analysis, IR spectroscopy, thermal gravimetric analysis, luminescent spectrum and single crystal X-ray diffraction. Single-crystal X-ray diffraction revealed that four terminal and three bridging oxygen atoms of the Wells-Dawson cluster are coordinated to Cu(I) ions and form an unprecedented hepta-supporting polyoxometalate. The functionalized arsenotungstates are further connected by two kinds of tridentate linkers, Imi-Cu-(bpy)-Cu-(bpy)-Cu-(bpy)-Cu-Imi and Imi-Cu-(bpy)-Cu-(bpy)-Cu-H{sub 2}O, to construct a 3D framework with 4{sup 6}.6{sup 4} topology. The hybrid material has an intense emission at about 397 nm. - Graphical abstract: A novel organic-inorganic hybrid compound based on mixed-valence Wells-Dawson arsenotungstate and mixed-ligand Cu(I) units has been successfully synthesized. The functionalized arsenotungstate exhibits a five-connected 4{sup 6}.6{sup 4} topology network.

• OSTI ID: 21432470
• Journal Information: Journal of Solid State Chemistry, Vol. 183, Issue 9; Other Information: DOI: 10.1016/j.jssc.2010.07.004; PII: S0022-4596(10)00278-1; Copyright (c) 2010 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; ISSN 0022-4596
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
ARSENIC COMPOUNDS
COPPER COMPLEXES
HYDROTHERMAL SYNTHESIS
INFRARED SPECTRA
LIGANDS
LUMINESCENCE
MONOCRYSTALS
THERMAL GRAVIMETRIC ANALYSIS
TOPOLOGY
TUNGSTATES
X-RAY DIFFRACTION
CHEMICAL ANALYSIS
COHERENT SCATTERING
COMPLEXES
CRYSTALS
DIFFRACTION
EMISSION
GRAVIMETRIC ANALYSIS
MATHEMATICS
OXYGEN COMPOUNDS
PHOTON EMISSION
QUANTITATIVE CHEMICAL ANALYSIS
REFRACTORY METAL COMPOUNDS
SCATTERING
SPECTRA
SYNTHESIS
THERMAL ANALYSIS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
TUNGSTEN COMPOUNDS