In[NC{sub 5}H{sub 3}(CO{sub 2}){sub 2}](OH{sub 2})F: A new layered indium-organic framework material (NC{sub 5}H{sub 3}(CO{sub 2}){sub 2}=2,6-pyridinedicarboxylate)
- Department of Chemistry, Chung-Ang University, 221 Heukseok-dong, Dongjak-gu, Seoul 156-756 (Korea, Republic of)
A new layered indium-organic framework material, In[NC{sub 5}H{sub 3}(CO{sub 2}){sub 2}](OH{sub 2})F has been synthesized by a hydrothermal reaction using In{sub 2}O{sub 3}, NH{sub 4}F, 2,6-NC{sub 5}H{sub 3}(CO{sub 2}H){sub 2} (2,6-pyridinedicarboxylic acid), HF, and water at 200 {sup o}C. Single-crystal X-ray diffraction was used to determine the structure of the reported material. In[NC{sub 5}H{sub 3}(CO{sub 2}){sub 2}](OH{sub 2})F has a novel layered structure consisting of InO{sub 5}NF polyhedra and the pyridinedicarboxylate organic linker. Detailed structural analyses with full characterization including infrared spectrum, thermogravimetric analysis, elemental analysis, exchange reactions for the coordinated water molecule, and gas adsorption experiments are reported. - Graphical abstract: Wire representation for the one indium-organic layer of In[NC{sub 5}H{sub 3}(CO{sub 2}){sub 2}](OH{sub 2})F in the [101] direction. Strong hydrogen bonds between the coordinated F and water molecules are observed within the layer.
- OSTI ID:
- 21421486
- Journal Information:
- Journal of Solid State Chemistry, Vol. 183, Issue 10; Other Information: DOI: 10.1016/j.jssc.2010.08.016; PII: S0022-4596(10)00350-6; Copyright (c) 2010 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ADSORPTION
AMMONIUM FLUORIDES
CARBOXYLIC ACID SALTS
HYDROFLUORIC ACID
HYDROTHERMAL SYNTHESIS
INDIUM COMPOUNDS
INDIUM OXIDES
INFRARED SPECTRA
MONOCRYSTALS
PYRIDINES
TEMPERATURE RANGE 0400-1000 K
THERMAL GRAVIMETRIC ANALYSIS
WATER
X-RAY DIFFRACTION
AMMONIUM COMPOUNDS
AMMONIUM HALIDES
AZINES
CHALCOGENIDES
CHEMICAL ANALYSIS
COHERENT SCATTERING
CRYSTALS
DIFFRACTION
FLUORIDES
FLUORINE COMPOUNDS
GRAVIMETRIC ANALYSIS
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
HYDROGEN COMPOUNDS
INORGANIC ACIDS
INORGANIC COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
QUANTITATIVE CHEMICAL ANALYSIS
SCATTERING
SORPTION
SPECTRA
SYNTHESIS
TEMPERATURE RANGE
THERMAL ANALYSIS