Yttrium-succinates coordination polymers: Hydrothermal synthesis, crystal structure and thermal decomposition
- Departamentos de Quimica Fisica y Analitica y Quimica Organica e Inorganica, Universidad de Oviedo, 33006 Oviedo (Spain)
- Departement de Chimie, Faculte des Sciences, Universite Abdelmalek Essaadi, 93002 Tetouan, Maroc (Morocco)
- Department of Chemistry, CICECO, University of Aveiro, 3810-193 Aveiro (Portugal)
New polymeric yttrium-succinates, Y{sub 2}(C{sub 4}H{sub 4}O{sub 4}){sub 3}(H{sub 2}O){sub 4}.6H{sub 2}O and Y{sub 2}(C{sub 4}H{sub 4}O{sub 4}){sub 3}(H{sub 2}O){sub 2}, have been synthesized, and their structures (solved by single crystal XRD) are compared with that of Y{sub 2}(C{sub 4}H{sub 4}O{sub 4}){sub 3}(H{sub 2}O){sub 2}.H{sub 2}O. Three compounds were obtained as single phases, and their thermal behaviour is described. - Graphical abstract: In the field of coordination polymers or MOF's, few studies report on the polymorphs of Ln(III)-succinic acid. Here, we describe the hydrothermal synthesis and structural characterization of two novel yttrium-succinates coordination polymers, respectively 2D and 3D, Y{sub 2}(C{sub 4}H{sub 4}O{sub 4}){sub 3}(H{sub 2}O){sub 4}.6H{sub 2}O and Y{sub 2}(C{sub 4}H{sub 4}O{sub 4}){sub 3}(H{sub 2}O){sub 2}.
- OSTI ID:
- 21372433
- Journal Information:
- Journal of Solid State Chemistry, Vol. 182, Issue 12; Other Information: DOI: 10.1016/j.jssc.2009.09.027; PII: S0022-4596(09)00462-9; Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CRYSTAL STRUCTURE
HYDROTHERMAL SYNTHESIS
MONOCRYSTALS
POLYMERS
PYROLYSIS
SUCCINIC ACID
X-RAY DIFFRACTION
YTTRIUM COMPOUNDS
CARBOXYLIC ACIDS
CHEMICAL REACTIONS
COHERENT SCATTERING
CRYSTALS
DECOMPOSITION
DICARBOXYLIC ACIDS
DIFFRACTION
ORGANIC ACIDS
ORGANIC COMPOUNDS
SCATTERING
SYNTHESIS
THERMOCHEMICAL PROCESSES
TRANSITION ELEMENT COMPOUNDS