2D water layer enclathrated between Mn(II)-Ni(CN){sub 4} coordination frameworks

Journal Article · Thu Oct 15 00:00:00 EDT 2009 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/j.jssc.2009.05.014· OSTI ID:21372322

Ray, Ambarish; Bhowmick, Indrani ^[1]; Sheldrick, William S ^[2]; Ali, Mahammed ^[1]

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1. Department of Chemistry, Jadavpur University, Kolkata 700 032 (India)
2. Lehrstuhl fur Analytischie Chemie, Ruhr-Universitat Bochum, D-44780, Bochum (Germany)

A [Ni(CN){sub 4}]{sup 2-}based two-dimensional Mn(II) coordination polymer {l_brace}Mn(H{sub 2}O){sub 2}[NiCN]{sub 4}.4H{sub 2}O{r_brace}, in which the coordination layers are stacked on top of each other sandwiching 2D water layer of boat-shaped hexagonal water clusters has been synthesized. The complex exhibits high thermal decomposition temperature and reversible water absorption, which were clearly demonstrated by thermal and PXRD studies on the parent and rehydrated complex after dehydration. - Abstract: A coordination polymer, {l_brace}Mn(H{sub 2}O){sub 2}[NiCN]{sub 4}.4H{sub 2}O{r_brace}{sub n}, showed that the coordination layers are stacked on top of each other sandwiching 2D ice layer of boat-shaped hexagonal water clusters . Display Omitted

• OSTI ID: 21372322
• Journal Information: Journal of Solid State Chemistry, Vol. 182, Issue 10; Other Information: DOI: 10.1016/j.jssc.2009.05.014; PII: S0022-4596(09)00223-0; Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; ISSN 0022-4596
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ABSORPTION
ADSORPTION
CYANIDES
DEHYDRATION
LAYERS
MANGANESE COMPLEXES
NICKEL COMPOUNDS
POLYMERS
PYROLYSIS
STABILITY
WATER
X-RAY DIFFRACTION
CHEMICAL REACTIONS
COHERENT SCATTERING
COMPLEXES
DECOMPOSITION
DIFFRACTION
HYDROGEN COMPOUNDS
OXYGEN COMPOUNDS
SCATTERING
SORPTION
THERMOCHEMICAL PROCESSES
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS