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Title: A numerical study on the effect of hydrogen/reformate gas addition on flame temperature and NO formation in strained methane/air diffusion flames

Journal Article · · Combustion and Flame
;  [1]
  1. Institute for Chemical Process and Environmental Technology, National Research Council Canada, 1200 Montreal Road, Ottawa, Ontario, K1A 0R6 (Canada)

This paper investigates the effects of hydrogen/reformate gas addition on flame temperature and NO formation in strained methane/air diffusion flames by numerical simulation. The results reveal that flame temperature changes due to the combined effects of adiabatic temperature, fuel Lewis number and radiation heat loss, when hydrogen/reformate gas is added to the fuel of a methane/air diffusion flame. The effect of Lewis number causes the flame temperature to increase much faster than the corresponding adiabatic equilibrium temperature when hydrogen is added, and results in a qualitatively different variation from the adiabatic equilibrium temperature as reformate gas is added. At some conditions, the addition of hydrogen results in a super-adiabatic flame temperature. The addition of hydrogen/reformate gas causes NO formation to change because of the variations in flame temperature, structure and NO formation mechanism, and the effect becomes more significant with increasing strain rate. The addition of a small amount of hydrogen or reformate gas has little effect on NO formation at low strain rates, and results in an increase in NO formation at moderate or high strain rates. However, the addition of a large amount of hydrogen increases NO formation at all strain rates, except near pure hydrogen condition. Conversely, the addition of a large amount of reformate gas results in a reduction in NO formation. (author)

OSTI ID:
21137931
Journal Information:
Combustion and Flame, Vol. 156, Issue 2; Other Information: Elsevier Ltd. All rights reserved; ISSN 0010-2180
Country of Publication:
United States
Language:
English