Synthesis, structure and physical properties of LnNi(Sn,Sb){sub 3} (Ln=Pr, Nd, Sm, Gd, Tb)

Gautreaux, Dixie P; Capan, Cigdem; DiTusa, John F; Young, David P

doi:10.1016/j.jssc.2008.04.029

Title: Synthesis, structure and physical properties of LnNi(Sn,Sb){sub 3} (Ln=Pr, Nd, Sm, Gd, Tb)

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Abstract

Five new analogues of the {beta}-CeNiSb{sub 3} family have been synthesized and found to be LnNi(Sn,Sb){sub 3} and isostructural to the previously reported {beta}-CeNiSb{sub 3}. LnNi(Sn,Sb){sub 3} (Ln=Pr, Nd, Sm, Gd, or Tb) crystallizes in the orthorhombic space group, Pbcm, with lattice parameters of a{approx}12.9 A, b{approx}6.1 A, c{approx}12.0 A. The structure consists of layers of nearly square nets of X (X=Sn/Sb) atoms and highly distorted NiX{sub 6} octahedra. Lanthanide atoms are located between layers of X and NiX{sub 6} octahedra. All analogues are metallic and experimental effective magnetic moments are in agreement with the respective Ln{sup 3+} calculated moments. - Graphical abstract: Five new single crystalline analogues of the {beta}-LnNiSb{sub 3} family (Ln=Pr, Nd, Sm, Gd, or Tb) have been synthesized and determined to be LnNi(Sn,Sb){sub 3}. The structures are compared to the previously reported {beta}-CeNiSb{sub 3}. Magnetic and transport behavior are reported and discussed.

Authors:

Gautreaux, Dixie P ^[1]; Capan, Cigdem; DiTusa, John F; Young, David P ^[2]

Department of Chemistry, Louisiana State University, 232 Choppin Hall, Baton Rouge, Louisiana 70803 (United States)
Department of Physics and Astronomy, Louisiana State University, Baton Rouge, Louisiana 70803 (United States)

Publication Date:: Fri Aug 15 00:00:00 EDT 2008

OSTI Identifier:: 21128400

Resource Type:: Journal Article

Journal Name:: Journal of Solid State Chemistry

Additional Journal Information:: Journal Volume: 181; Journal Issue: 8; Other Information: DOI: 10.1016/j.jssc.2008.04.029; PII: S0022-4596(08)00217-X; Copyright (c) 2008 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0022-4596

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ANTIMONIDES; GADOLINIUM COMPOUNDS; LATTICE PARAMETERS; LAYERS; MAGNETIC MOMENTS; MAGNETISM; MONOCRYSTALS; NEODYMIUM COMPOUNDS; ORTHORHOMBIC LATTICES; PHYSICAL PROPERTIES; PRASEODYMIUM COMPOUNDS; SAMARIUM COMPOUNDS; SPACE GROUPS; SYNTHESIS; TERBIUM COMPOUNDS; TIN COMPOUNDS; X-RAY DIFFRACTION

Citation Formats


                    Gautreaux, Dixie P, Capan, Cigdem, DiTusa, John F, Young, David P, and Chan, Julia Y. Synthesis, structure and physical properties of LnNi(Sn,Sb){sub 3} (Ln=Pr, Nd, Sm, Gd, Tb).  United States: N. p., 2008. 
        Web.  doi:10.1016/j.jssc.2008.04.029.

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                    Gautreaux, Dixie P, Capan, Cigdem, DiTusa, John F, Young, David P, & Chan, Julia Y. Synthesis, structure and physical properties of LnNi(Sn,Sb){sub 3} (Ln=Pr, Nd, Sm, Gd, Tb).  United States.  https://doi.org/10.1016/j.jssc.2008.04.029

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                    Gautreaux, Dixie P, Capan, Cigdem, DiTusa, John F, Young, David P, and Chan, Julia Y. 2008.  
        "Synthesis, structure and physical properties of LnNi(Sn,Sb){sub 3} (Ln=Pr, Nd, Sm, Gd, Tb)".  United States.  https://doi.org/10.1016/j.jssc.2008.04.029.

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@article{osti_21128400,

  title        = {Synthesis, structure and physical properties of LnNi(Sn,Sb){sub 3} (Ln=Pr, Nd, Sm, Gd, Tb)},

  author       = {Gautreaux, Dixie P and Capan, Cigdem and DiTusa, John F and Young, David P and Chan, Julia Y.},

  abstractNote = {Five new analogues of the {beta}-CeNiSb{sub 3} family have been synthesized and found to be LnNi(Sn,Sb){sub 3} and isostructural to the previously reported {beta}-CeNiSb{sub 3}. LnNi(Sn,Sb){sub 3} (Ln=Pr, Nd, Sm, Gd, or Tb) crystallizes in the orthorhombic space group, Pbcm, with lattice parameters of a{approx}12.9 A, b{approx}6.1 A, c{approx}12.0 A. The structure consists of layers of nearly square nets of X (X=Sn/Sb) atoms and highly distorted NiX{sub 6} octahedra. Lanthanide atoms are located between layers of X and NiX{sub 6} octahedra. All analogues are metallic and experimental effective magnetic moments are in agreement with the respective Ln{sup 3+} calculated moments. - Graphical abstract: Five new single crystalline analogues of the {beta}-LnNiSb{sub 3} family (Ln=Pr, Nd, Sm, Gd, or Tb) have been synthesized and determined to be LnNi(Sn,Sb){sub 3}. The structures are compared to the previously reported {beta}-CeNiSb{sub 3}. Magnetic and transport behavior are reported and discussed.},

  doi          = {10.1016/j.jssc.2008.04.029},

  url          = {https://www.osti.gov/biblio/21128400},
  journal      = {Journal of Solid State Chemistry},

  issn         = {0022-4596},

  number       = 8,

  volume       = 181,

  place        = {United States},

  year         = {Fri Aug 15 00:00:00 EDT 2008},

  month        = {Fri Aug 15 00:00:00 EDT 2008}

}

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