Synthesis and structure of a 1,6-hexyldiamine heptaborate, [H{sub 3}N(CH{sub 2}){sub 6}NH{sub 3}][B{sub 7}O{sub 10}(OH){sub 3}]
- Beijing National Laboratory for Molecular Sciences (BNLMS), State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China)
- China University of Geoscience, X-ray Laboratory, Beijing 100083 (China)
A new 1,6-hexyldiamine heptaborate, [H{sub 3}N(CH{sub 2}){sub 6}NH{sub 3}][B{sub 7}O{sub 10}(OH){sub 3}] (1), has been solvothermally synthesized and characterized by single-crystal X-ray diffraction, FTIR, elemental analysis, and thermogravimetric analysis. Compound 1 crystallizes in monoclinic system, space group P2{sub 1}/n with a=8.042(2) A, b=20.004(4) A, c=10.103(2) A, and {beta}=90.42(3) deg. The anionic [B{sub 7}O{sub 10}(OH){sub 3}]{sub n}{sup 2n-} layers are interlinked via hydrogen bonding to form a 3D supramolecular network containing large channels, in which the templated [H{sub 3}N(CH{sub 2}){sub 6}NH{sub 3}]{sup 2+} cations are located. - Graphical abstract: A layered 1,6-hexyldiamine heptaborate, [H{sub 3}N(CH{sub 2}){sub 6}NH{sub 3}][B{sub 7}O{sub 10}(OH){sub 3}], was solvothermally synthesized at 150 deg. C. It is a layer borate and crystallized in monoclinic space group P2{sub 1}/n with a=8.042(2) A, b=20.004(4) A, c=10.103(2) A, {beta}=90.42(3) deg.
- OSTI ID:
- 21043798
- Journal Information:
- Journal of Solid State Chemistry, Vol. 180, Issue 8; Other Information: DOI: 10.1016/j.jssc.2007.05.029; PII: S0022-4596(07)00218-6; Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
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