Comparison between semiclassical and quantum mechanical calculations for collisional broadening and shift of HCO{sup +} rotational lines
Journal Article
·
· Physical Review. A
- IPCF-CNR, Largo Pontecorvo 3, I-56127 Pisa (Italy)
For eight HCO{sup +} rotational transitions we compare semiclassical and quantum calculations of the line broadening and shift induced by collisions with argon and helium atoms. A detailed analysis of the results allows better insights into the problem of the accuracy of the semiclassical model commonly used in most line shape studies.
- OSTI ID:
- 21020715
- Journal Information:
- Physical Review. A, Vol. 76, Issue 4; Other Information: DOI: 10.1103/PhysRevA.76.042509; (c) 2007 The American Physical Society; Country of input: International Atomic Energy Agency (IAEA); ISSN 1050-2947
- Country of Publication:
- United States
- Language:
- English
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