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Title: Contemporary trends in the acid-base status of two acid-sensitive streams in Western Maryland

Journal Article · · Environmental Science and Technology
DOI:https://doi.org/10.1021/es071195e· OSTI ID:21004867
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  1. University of Maryland Center for Environmental Science, Frostburg, MD (United States). Appalachian Laboratory

Recovery of streamwater acid neutralizing capacity (ANC) resulting from declines in regional acid deposition was examined using contemporary (1990-2005) data from two long-term monitoring stations located on the Appalachian Plateau in western Maryland, U.S. Two computational methods were used to estimate daily, monthly, and annual fluxes and discharge-weighted concentrations of ANC, sulfate, nitrate, and base cations over the period of record, and two statistical methods were used to evaluate long-term trends in fluxes and concentrations. The methods used to estimate concentrations, as well as the statistical techniques, produced very similar results, underlining the robustness of the identified trends. We found clear evidence that streamwater sulfate concentrations have declined at an average rate of about 3 {mu}eq L{sup -1} yr{sup -1} at the two sites due to a 34% reduction in wet atmospheric sulfur deposition. Trends in nitrate concentrations appear to be related to other watershed factors, especially forest disturbance. The best evidence of recovery is based on a doubling of ANC (from 21 to 42 {mu}eq L{sup -1}) at the more acid-sensitive site over the 16-year period. A slowing, or possible reversal, in the sulfate, nitrate, and SBC trends is evident in our data and may portend a decline in the rate of or end to further recovery. 33 refs., 4 figs., 1 tab.

OSTI ID:
21004867
Journal Information:
Environmental Science and Technology, Vol. 42, Issue 1; Other Information: eshleman@al.umces.edu; ISSN 0013-936X
Country of Publication:
United States
Language:
English