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Title: Preparation of AgInS{sub 2} chalcopyrite thin films by chemical spray pyrolysis

Journal Article · · Materials Research Bulletin

AgInS{sub 2} thin films were prepared by the spray pyrolysis technique using a water/ethanol solution containing silver acetate, indium chloride and thiourea. We reported our results on the characterization of tetragonal AgInS{sub 2} (chalcopyrite type) films, which were grown from indium deficient spraying solution. The films displayed a n-type conductivity with room temperature resistivities in the range between 10{sup 3} and 10{sup 4} {omega} cm. The absorption spectra of sprayed films revealed two direct band-gaps with characteristic energies around 1.87 and 2.01 eV, which are in good agreement with the reported energy values for interband transitions from the split p-like valence band to the s-like conduction band in tetragonal AgInS{sub 2} single crystals.

OSTI ID:
20883129
Journal Information:
Materials Research Bulletin, Vol. 38, Issue 1; Other Information: PII: S0025540802009996; Copyright (c) 2002 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); ISSN 0025-5408
Country of Publication:
United States
Language:
English

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