Structure-inheriting solid-state reactions under hydrothermal conditions

Journal Article · Mon May 15 00:00:00 EDT 2006 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/j.jssc.2006.01.060· OSTI ID:20785010

Eda, Kazuo ^[1]; Uno, Yuichi ^[1]; Nagai, Noriko ^[1]; Sotani, Noriyuki ^[1]; Chen, Chen ^[2]; Stanley Whittingham, M ^[2]

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1. Faculty of Science, Department of Chemistry, Kobe University, Nada-ku, Kobe 657-8501 (Japan)
2. Institute for Materials Research, State University of New York at Binghamton, Binghamton, NY 13902-6000 (United States)

We have explored several structure-inheriting solid-state reactions (SISSRs) under hydrothermal conditions for syntheses in the Co-Mo-O system. And we found an interesting hydrothermal SISSR from CoMoO{sub 4}.3/4H{sub 2}O to high-pressure (hp-) phase of CoMoO{sub 4}, which enabled us to considerably reduce the severe conditions for the synthesis of hp-CoMoO{sub 4}. As similar hydrothermal SISSRs are expected to be useful tools for material syntheses, we also briefly discuss them as a means of developing novel material syntheses and designs.

• OSTI ID: 20785010
• Journal Information: Journal of Solid State Chemistry, Vol. 179, Issue 5; Other Information: DOI: 10.1016/j.jssc.2006.01.060; PII: S0022-4596(06)00076-4; Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); ISSN 0022-4596
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
COBALT COMPOUNDS
HYDROTHERMAL SYNTHESIS
MOLYBDATES
PHASE TRANSFORMATIONS