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Title: Lowering critical cooling rate for forming bulk metallic glass

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.2172160· OSTI ID:20778751
;  [1]
  1. MS G755, MST-8, Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

Small volumes of Pd{sub 44}Ni{sub 10}Cu{sub 26}P{sub 20} and Pd{sub 43.2}Ni{sub 8.8}Cu{sub 28}P{sub 20} were encapsulated in B{sub 2}O{sub 3} and thermally cycled between T{sub g}-60 deg. C and T{sub l}+60 deg. C, where T{sub g} and T{sub l} denote the alloys' glass transition and liquidus temperatures. After this thermal treatment, the critical cooling rates (CCRs) for glass formation can be lowered by an order of magnitude, resulting in a critical cooling rate significantly lower than that reported for any other glass forming alloy melt. These experiments demonstrate that the CCR is not constant but strongly dependent on the degree of heterogeneous nucleation.

OSTI ID:
20778751
Journal Information:
Applied Physics Letters, Vol. 88, Issue 9; Other Information: DOI: 10.1063/1.2172160; (c) 2006 American Institute of Physics; Country of input: International Atomic Energy Agency (IAEA); ISSN 0003-6951
Country of Publication:
United States
Language:
English