Intercalation of cyclic ketones into vanadyl phosphate

Journal Article · Sat Jan 15 00:00:00 EST 2005 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/j.jssc.2004.11.008· OSTI ID:20721701

Zima, Vitezslav ^[1]; Melanova, Klara ^[1]; Benes, Ludvik ^[1]; Trchova, Miroslava ^[2]; Dybal, Jiri ^[2]

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1. Joint Laboratory of Solid State Chemistry, Institute of Macromolecular Chemistry of Academy of Sciences, University of Pardubice, Studentska 84, CZ-532-10 Pardubice (Czech Republic)
2. Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Heyrovsky Sq. 2, 162 06 Prague 6 (Czech Republic)

Intercalation compounds of vanadyl phosphate with cyclic ketones (cyclopentanone, cyclohexanone, 4-methylcyclohexanone, and 1,4-cyclohexanedione) were prepared from corresponding propanol or ethanol intercalates by a molecular exchange. The intercalates prepared were characterized using powder X-ray diffraction and thermogravimetric analysis. The intercalates are stable in dry environment and decompose slowly in humid air. Infrared and Raman spectra indicate that carbonyl oxygens of the guest molecules are coordinated to the vanadium atoms of the host layers. The local structure and interactions in the cyclopentanone intercalate have been suggested on the basis of quantum chemical calculations.

• OSTI ID: 20721701
• Journal Information: Journal of Solid State Chemistry, Vol. 178, Issue 1; Other Information: DOI: 10.1016/j.jssc.2004.11.008; PII: S0022-4596(04)00607-3; Copyright (c) 2004 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); ISSN 0022-4596
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CLATHRATES
CYCLOHEXANONE
ETHANOL
INTERACTIONS
LAYERS
PROPANOLS
RAMAN SPECTRA
SPECTROSCOPY
THERMAL GRAVIMETRIC ANALYSIS
VANADIUM PHOSPHATES
X-RAY DIFFRACTION