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Title: Diffuse Scattering and Phason Fluctuations in the Zn-Mg-Sc Icosahedral Quasicrystal and Its Zn-Sc Periodic Approximant

Journal Article · · Physical Review Letters
 [1];  [1]; ;  [2]
  1. Laboratoire de Thermodynamique et de Physico-Chimie Metallurgique, UMR CNRS 5614, ENSEEG-INPG, BP 75, 38402 Saint Martin d'Heres (France)
  2. Research Group of Material Physics, Graduate School of Engineering, Hokkaido University, Kita-ku, Sapporo, 060-8628 (Japan)

We report on the absolute scale measurement of the x-ray diffuse scattering in the ZnMgSc icosahedral quasicrystal and its periodic approximant. Whereas the diffuse scattering in the approximant is purely accounted for by thermal diffuse scattering, an additional signal is observed in the quasicrystal. It is related to phason fluctuations as indicated by its Q{sub per}{sup 2} dependence. Moreover, when compared to previous measurements carried out on the i-AlPdMn phase, we find that the amount of diffuse scattering is smaller in the i-ZnMgSc phase, in agreement with larger phason elastic constants in this phase. This is confirmed by the observation of a large number of weak Bragg peaks having a high Q{sub per} reciprocal space component.

OSTI ID:
20699396
Journal Information:
Physical Review Letters, Vol. 95, Issue 10; Other Information: DOI: 10.1103/PhysRevLett.95.105503; (c) 2005 The American Physical Society; Country of input: International Atomic Energy Agency (IAEA); ISSN 0031-9007
Country of Publication:
United States
Language:
English

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