The corrosion phenomena in the coin cell BR2325 of the ``superstoichiometric fluorocarbon-lithium'' system
Abstract
It was noted at the earlier study and at the longer observations of the novel various types of superstoichiometric fluorocarbon materials CF{sub 1+x}, where x = 0.1--0.33 (FCM) and their behavior, that despite of their known hygroscopity during a storage of samples in laboratory and technological utensils nevertheless occurs an appreciable sorption of atmospheric moisture. The color of samples does not change but sometimes there appears a smell of hydrogen fluoride and even corrosion of glasswares at a long storage. On the basis of these facts was assumed that at a long storage the slow reactions of HF producing with a sorption moisture can proceed. This phenomena is necessary to take into account for successful manufacturing of long life lithium cells based on superstoichiometric fluorocarbon composite cathodes (FCC). The chemistry of such slow hydrolytic process and especially of processes which can proceed at manufacturing of FCC earlier was not investigated also of any data in the literature in this occasion is not present. Just for this reason the authors undertook a study of the corrosion phenomena which can proceed in industrial sources of a current at a long storage under influence of slow hydrolysis of C-F bonds by moisture. Themore »
- Authors:
-
- and others
- Publication Date:
- Research Org.:
- Inst. of Inorganic Chemistry SB RAS, Novosibirsk (RU)
- OSTI Identifier:
- 20019124
- Resource Type:
- Conference
- Resource Relation:
- Conference: 1997 Materials Research Society Fall Meeting, Boston, MA (US), 12/01/1997--12/05/1997; Other Information: PBD: 1998; Related Information: In: Materials for electrochemical energy storage and conversion II -- Batteries, capacitors and fuel cells. Materials Research Society symposium proceedings, Volume 496, by Ginley, D.S.; Doughty, D.H.; Scrosati, B.; Takamura, T.; Zhang, Z.J. [eds.], 702 pages.
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 25 ENERGY STORAGE; CORROSION; CARBON FLUORIDES; COMPOSITE MATERIALS; CATHODES; MOISTURE; METAL-NONMETAL BATTERIES; LITHIUM; EXPERIMENTAL DATA
Citation Formats
Mitkin, V N, Galkin, P S, and Denisova, T N. The corrosion phenomena in the coin cell BR2325 of the ``superstoichiometric fluorocarbon-lithium'' system. United States: N. p., 1998.
Web.
Mitkin, V N, Galkin, P S, & Denisova, T N. The corrosion phenomena in the coin cell BR2325 of the ``superstoichiometric fluorocarbon-lithium'' system. United States.
Mitkin, V N, Galkin, P S, and Denisova, T N. 1998.
"The corrosion phenomena in the coin cell BR2325 of the ``superstoichiometric fluorocarbon-lithium'' system". United States.
@article{osti_20019124,
title = {The corrosion phenomena in the coin cell BR2325 of the ``superstoichiometric fluorocarbon-lithium'' system},
author = {Mitkin, V N and Galkin, P S and Denisova, T N},
abstractNote = {It was noted at the earlier study and at the longer observations of the novel various types of superstoichiometric fluorocarbon materials CF{sub 1+x}, where x = 0.1--0.33 (FCM) and their behavior, that despite of their known hygroscopity during a storage of samples in laboratory and technological utensils nevertheless occurs an appreciable sorption of atmospheric moisture. The color of samples does not change but sometimes there appears a smell of hydrogen fluoride and even corrosion of glasswares at a long storage. On the basis of these facts was assumed that at a long storage the slow reactions of HF producing with a sorption moisture can proceed. This phenomena is necessary to take into account for successful manufacturing of long life lithium cells based on superstoichiometric fluorocarbon composite cathodes (FCC). The chemistry of such slow hydrolytic process and especially of processes which can proceed at manufacturing of FCC earlier was not investigated also of any data in the literature in this occasion is not present. Just for this reason the authors undertook a study of the corrosion phenomena which can proceed in industrial sources of a current at a long storage under influence of slow hydrolysis of C-F bonds by moisture. The goal of the study was to search long term damages in the slightly wet FCM and based on these materials cathodic composites for fluorocarbon-lithium cells. As a model for corrosion process investigation they have chosen a standard coin lithium battery of a type BR2325.},
doi = {},
url = {https://www.osti.gov/biblio/20019124},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed Jul 01 00:00:00 EDT 1998},
month = {Wed Jul 01 00:00:00 EDT 1998}
}