Two-step methane conversion to higher hydrocarbons: Comment on the relevance of metal-carbon bond strength
Journal Article
·
· Journal of Catalysis
Herein, data available in the literature for nonoxidative, two-step CH{sub 4} homologation over SiO{sub 2}-supported transition metals are analyzed according to the principle of Sabatier. Volcano plots are constructed which provide empirical evidence to support the hypothesis that the metal-carbon bond strength is pivotal to determine catalyst efficiency, chain-growth probability, and selectivity to C{sub 2}{sup +} hydrocarbons.
- Research Organization:
- CeraMem Corp., Waltham, MA (US)
- OSTI ID:
- 20014527
- Journal Information:
- Journal of Catalysis, Vol. 189, Issue 1; Other Information: PBD: 1 Jan 2000; ISSN 0021-9517
- Country of Publication:
- United States
- Language:
- English
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