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Title: Fac-Re(bpy)(CO){sub 3}(COOMe): A model metallocarboxylate complex of rhenium with a bipyridyl ligand

Journal Article · · Journal of Chemical Crystallography

The title compound fac-(2,2{prime}-bipyridyl)(carbomethoxy)rhenium tricarbonyl, crystallizes in the monoclinic system, space group P2{sub 1}/c with the following crystal data: a = 8.37551(1), b = 6.6934(1), c = 26.2098(1) {angstrom}, V({angstrom}{sup 3}) = 1,535.93(3), Z = 4, and {beta} = 90.0971(2). The metal environment is slightly distorted octahedral with a chelating bipyridyl ligand and a facial arrangement of the carbon monoxide ligands.

Research Organization:
Univ. of Louisville, KY (US)
Sponsoring Organization:
USDOE; National Science Foundation (NSF)
OSTI ID:
20013134
Journal Information:
Journal of Chemical Crystallography, Vol. 29, Issue 5; Other Information: PBD: May 1999; ISSN 1074-1542
Country of Publication:
United States
Language:
English