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Title: Influence of an electric current on the crystallization of YBa{sub 2}Cu{sub 3}O{sub 7{minus}x} in BaO/CuO/CuO{sub 0.5} flux melts

Journal Article · · Journal of Low Temperature Physics

The influence of an electric current on the ternary BaO/CuO/CuO{sub 0.5} system and the quaternary YO{sub 1.5}/BaO/CuO/CuO{sub 0.5} system has been investigated by modified differential thermal analysis. Increasing the current in the ternary system leads to the crystallization of an additional phase. In the quaternary system they find a splitting of the solidification of the residual melt BaO/CuO/CuO{sub 0.5} indicating the formation of two different eutectics. In both systems, they find a preferential deposition of material at the positive electrode. Crystal growth experiments including electric current show a preferential formation of YBa{sub 2}Cu{sub 3}O{sub 7{minus}x} crystals at the positive electrode.

Research Organization:
Goethe-Univ., Frankfurt/Main (DE)
OSTI ID:
20012863
Journal Information:
Journal of Low Temperature Physics, Vol. 117, Issue 3-4; Conference: International Conference on Physics and Chemistry of Molecular and Oxide Superconductors, MOS'99, Stockholm (SE), 07/28/1999--08/02/1999; Other Information: PBD: Nov 1999; ISSN 0022-2291
Country of Publication:
United States
Language:
English

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