Bonding of Multiple Noble-Gas Atoms to CUO in Solid Neon: CUO(Ng)(n) (Ng= Ar, Kr, Xe; n= 1, 2, 3, 4) Complexes and the Singlet-Triplet Crossover Point
Journal Article
·
· Chemistry - a European Journal
Laser-ablated U atoms codeposited with CO in excess neon produce the novel CUO molecule, which forms distinct Ng complexes (Ng= Ar, Kr, Xe) with the heavier noble gases. The CUO(Ng) complexes are identified through CO isotopic and Ng reagent substitution and comparison to results of DFT frequency calculations.
- Research Organization:
- Pacific Northwest National Lab., Richland, WA (US), Environmental Molecular Sciences Laboratory (US)
- Sponsoring Organization:
- US Department of Energy (US)
- DOE Contract Number:
- AC06-76RL01830
- OSTI ID:
- 15006830
- Report Number(s):
- PNNL-SA-40721; 2385; KP1301030; TRN: US0401111
- Journal Information:
- Chemistry - a European Journal, Vol. 9, Issue 19; Other Information: PBD: 6 Oct 2003
- Country of Publication:
- United States
- Language:
- English
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