A new di-ruthenium complex with an intense near-infrared electronic band
Conference
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OSTI ID:140986
- Univ. of the Pacific, Stockton, CA (United States)
- Lawrence Berkeley Laboratory, CA (United States)
A new di-ruthenium complex prepared by the aerobic oxidation of trans Ru(1,4,7,11-tetraazacyclo-tetradecane) Cl{sub 2} has been investigated. The FAB mass spectrum shows mass peaks centered at m/z 732 and the isotopic ion distribution pattern gives the composition C{sub 20}H{sub 36}N{sub 8}Cl{sub 4}Ru{sub 2}. This paper gives evidence supporting characterization of this species as the ruthenium analogue of a di-iron complex with a delocalized pi system (Inorg. Chem. 1992, 31, 717) bridging two tetraazamacrocycles. The di-ruthenium complex, like the di-iron has a very intense electronic transition in the near-infrared.
- OSTI ID:
- 140986
- Report Number(s):
- CONF-930304-; TRN: 93:003688-0653
- Resource Relation:
- Conference: 205. American Chemical Society national meeting, Denver, CO (United States), 28 Mar - 2 Apr 1993; Other Information: PBD: 1993; Related Information: Is Part Of 205th ACS national meeting; PB: 1951 p.
- Country of Publication:
- United States
- Language:
- English
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