Electrochemical Modeling and Performance of a Lithium- and Manganese-Rich Layered Transition-Metal Oxide Positive Electrode

Dees, Dennis W.; Abraham, Daniel P.; Lu, Wenquan; Gallagher, Kevin G.; Bettge, Martin; Jansen, Andrew N.

doi:10.1149/2.0231504jes

Title: Electrochemical Modeling and Performance of a Lithium- and Manganese-Rich Layered Transition-Metal Oxide Positive Electrode

Journal Article · Wed Jan 21 00:00:00 EST 2015 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0231504jes· OSTI ID:1392636

Dees, Dennis W. ^[1]; Abraham, Daniel P. ^[1]; Lu, Wenquan ^[1]; Gallagher, Kevin G. ^[1]; Bettge, Martin ^[1]; Jansen, Andrew N. ^[1]

Argonne National Lab. (ANL), Argonne, IL (United States)

The impedance of a lithium- and manganese-rich layered transition-metal oxide (MR-NMC) positive electrode, specifically Li_1.2Ni_0.15Mn_0.55Co_0.1O₂, is compared to two other transition-metal layered oxide materials, specifically LiNi_0.8Co_0.15Al_0.05O₂ (NCA) and Li_1.05(Ni_1/3Co_1/3Mn_1/3)_0.95O₂ (NMC). A more detailed electrochemical impedance spectroscopy (EIS) study is conducted on the LMR-NMC electrode, which includes a range of states-of-charge (SOCs) for both current directions (i.e. charge and discharge) and two relaxation times (i.e. hours and one hundred hours) before the EIS sweep. The LMR-NMC electrode EIS studies are supported by half-cell constant current and galvanostatic intermittent titration technique (GITT) studies. Two types of electrochemical models are utilized to examine the results. The first type is a lithium ion cell electrochemical model for intercalation active material electrodes that includes a complex active material/electrolyte interfacial structure. In conclusion, the other is a lithium ion half-cell electrochemical model that focuses on the unique composite structure of the bulk LMR-NMC materials.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1392636

Journal Information:: Journal of the Electrochemical Society, Vol. 162, Issue 4; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 35 works

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Title: Electrochemical Modeling and Performance of a Lithium- and Manganese-Rich Layered Transition-Metal Oxide Positive Electrode

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