Trapped in the coordination sphere: Nitrate ion transfer driven by the cerium(III/IV) redox couple

Ellis, Ross J.; Bera, Mrinal K.; Reinhart, Benjamin; Antonio, Mark R.

doi:10.1039/C6CP06528G

Title: Trapped in the coordination sphere: Nitrate ion transfer driven by the cerium(III/IV) redox couple

Journal Article · Mon Nov 07 00:00:00 EST 2016 · Physical Chemistry Chemical Physics. PCCP (Print)

DOI:https://doi.org/10.1039/C6CP06528G· OSTI ID:1364644

Ellis, Ross J. ^[1]; Bera, Mrinal K. ^[1]; Reinhart, Benjamin ^[1]; Antonio, Mark R. ^[1]

Argonne National Lab. (ANL), Argonne, IL (United States)

Redox-driven ion transfer between phases underpins many biological and technological processes, including industrial separation of ions. Here we investigate the electrochemical transfer of nitrate anions between oil and water phases, driven by the reduction and oxidation of cerium coordination complexes in oil phases. We find that the coordination environment around the cerium cation has a pronounced impact on the overall redox potential, particularly with regard to the number of coordinated nitrate anions. Our results suggest a new fundamental mechanism for tuning ion transfer between phases; by 'trapping' the migrating ion inside the coordination sphere of a redox-active complex. Here, this presents a new route for controlling anion transfer in electrochemically-driven separation applications.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1364644

Journal Information:: Physical Chemistry Chemical Physics. PCCP (Print), Vol. 18, Issue 45; ISSN 1463-9076

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 8 works

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