Influence of the amine salt anion on the synergic solvent extraction of praseodymium with mixtures of chelating extractants and tridodecylamine
Journal Article
·
· Solvent Extraction and Ion Exchange
- Higher Inst. of Chemical Technology, Sofia (Bulgaria)
The solvent extraction of Pr with thenoyltrifluoroacetone, (HTTA) or 1-phenyl-3-methyl-4-benzoyl-pyrazol-5-one(HP) and tridodecylammonium salt (TDAHA,A{sup -} = Cl{sup -},NO{sub 3}{sup -}, ClO{sub 4}{sup -}) in C{sub 6}H{sub 6} has been studied. The composition of the extracted species has been determined as Pr(TTA){sub 3} TDAHA and TDAH{sup +}[PrP{sub 4}]{sup -}. The values of the equilibrium constants, have been calculated. The extraction mechanism has been discussed on the basis of the experimental data. 34 refs., 6 figs., 2 tabs.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 136273
- Journal Information:
- Solvent Extraction and Ion Exchange, Vol. 13, Issue 6; Other Information: PBD: Nov 1995
- Country of Publication:
- United States
- Language:
- English
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