Conformational statistics of molecules with inner rotation and shapes of their electronic absorption bands
Journal Article
·
· Optics and Spectroscopy
OSTI ID:136076
- Kirenskii Institute of Physics, Krasnoyarsk (Russian Federation)
The effect of conformational statistics of molecules with inner rotation of {pi}-conjugated fragments on the position, intensity, and electronic absorption band shapes is studied in isotropic molecular media. It is shown that the conformational disorder of molecules with one inner rotation degree of freedom exerts an appreciable effect on the shift, inhomogeneous broadening, and asymmetry of the electronic absorption bands. An interpretation of the available experimental data is give. 19 refs., 1 fig.
- OSTI ID:
- 136076
- Journal Information:
- Optics and Spectroscopy, Vol. 77, Issue 4; Other Information: PBD: Oct 1994; TN: Translated from Optika i Spektroskopiya; 77: No. 4, 567-571(1994)
- Country of Publication:
- United States
- Language:
- English
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