Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries

Lü, Xujie; Howard, John W.; Chen, Aiping; Zhu, Jinlong; Li, Shuai; Wu, Gang; Dowden, Paul; Xu, Hongwu; Zhao, Yusheng; Jia, Quanxi

doi:10.1002/advs.201500359

Title: Antiperovskite Li ₃ OCl superionic conductor films for solid-state Li-ion batteries

Journal Article · Tue Feb 02 00:00:00 EST 2016 · Advanced Science

DOI:https://doi.org/10.1002/advs.201500359· OSTI ID:1240619

Lü, Xujie ^[1]; Howard, John W. ^[2]; Chen, Aiping ^[1]; Zhu, Jinlong ^[2]; Li, Shuai ^[2]; Wu, Gang ^[3]; Dowden, Paul ^[1]; Xu, Hongwu ^[1]; Zhao, Yusheng ^[2]; Jia, Quanxi ^[1]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Univ. of Nevada, Las Vegas, NV (United States)
Univ. at Buffalo, NY (United States)

Electrical energy storage becomes increasingly more important It was reported by McKinsey that the potential economic impac of improved energy storage could be 90 to 635 billion per year by 2025. [ 1 ] Although Li-ion batteries (LIBs) are powerin billions of portable electronic products as well as hybrid an electric vehicles, the safety issues related to the corrosive an fl ammable liquid electrolytes in current commercialized LIB must be addressed. [ 2–4 ] Replacing liquid electrolytes with solidstat inorganic electrolytes has been considered as the ultimat solution to address the safety issues. In addition, the solid-stat electrolytes can be readily integrated with a metallic lithiu anode, allowing solid-state LIBs with potentially high energ densities. Thus far, solid-state electrolytes have not been widel used in the commercial products because their ionic conductivitie are not high enough to meet the requirements for highperformanc Li batteries. [ 5–7 ] Hence, it is extremely importan to develop advanced solid-state electrolytes with high ionic conductivit and good compatibility with cathode and anode material for all-solid-state LIBs.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Univ. of Nevada, Las Vegas, NV (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E); USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC52-06NA25396; NA0001982

OSTI ID:: 1240619

Alternate ID(s):: OSTI ID: 1332394

Report Number(s):: LA-UR-15-26439

Journal Information:: Advanced Science, Journal Name: Advanced Science; ISSN 2198-3844

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 132 works

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Title: Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries

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Title: Antiperovskite Li ₃ OCl superionic conductor films for solid-state Li-ion batteries