Visible and near-infrared photothermal catalyzed hydrogenation of gaseous CO2 over nanostructured Pd@Nb2O5

Jia, Jia; O'Brien, Paul G.; He, Le; Qiao, Qiao; Fei, Teng; Reyes, Laura M.; Burrow, Timothy E.; Dong, Yuchan; Liao, Kristine; Varela, Maria; Pennycook, Stephen J.; Hmadeh, Mohamad; Helmy, Amr S.; Kherani, Nazir P.; Perovic, Doug D.; Ozin, Geoffrey A.

doi:10.1002/advs.201600189

Title: Visible and near-infrared photothermal catalyzed hydrogenation of gaseous CO₂ over nanostructured Pd@Nb₂O₅

Journal Article · Tue Jul 05 00:00:00 EDT 2016 · Advanced Science

DOI:https://doi.org/10.1002/advs.201600189· OSTI ID:1329168

Jia, Jia ^[1]; O'Brien, Paul G. ^[1]; He, Le ^[2]; Qiao, Qiao ^[3]; Fei, Teng ^[1]; Reyes, Laura M. ^[1]; Burrow, Timothy E. ^[1]; Dong, Yuchan ^[1]; Liao, Kristine ^[1]; Varela, Maria ^[4]; Pennycook, Stephen J. ^[5]; Hmadeh, Mohamad ^[6]; Helmy, Amr S. ^[1]; Kherani, Nazir P. ^[1]; Perovic, Doug D. ^[1]; Ozin, Geoffrey A. ^[1]

Univ. of Toronto, Toronto, ON (Canada)
Soochow Univ., Jiangsu (China)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. Complutense de Madrid, Madrid (Spain)
National Univ. of Singapore (Singapore)
American Univ. of Beirut, Beirut (Lebanon)

The reverse water gas shift (RWGS) reaction driven by Nb₂O₅ nanorod-supported Pd nanocrystals without external heating using visible and near infrared (NIR) light is demonstrated. By measuring the dependence of the RWGS reaction rates on the intensity and spectral power distribution of filtered light incident onto the nanostructured Pd@Nb₂O₅ catalyst, it is determined that the RWGS reaction is activated photothermally. That is the RWGS reaction is initiated by heat generated from thermalization of charge carriers in the Pd nanocrystals that are excited by interband and intraband absorption of visible and NIR light. Taking advantage of this photothermal effect, a visible and NIR responsive Pd@Nb₂O₅ hybrid catalyst that efficiently hydrogenates CO₂ to CO at an impressive rate as high as 1.8 mmol gcat^–1 h^–1 is developed. The mechanism of this photothermal reaction involves H₂ dissociation on Pd nanocrystals and subsequent spillover of H to the Nb₂O₅ nanorods whereupon adsorbed CO₂ is hydrogenated to CO. Here, this work represents a significant enhancement in our understanding of the underlying mechanism of photothermally driven CO₂ reduction and will help guide the way toward the development of highly efficient catalysts that exploit the full solar spectrum to convert gas-phase CO₂ to valuable chemicals and fuels.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1329168

Journal Information:: Advanced Science, Vol. 3, Issue 10; ISSN 2198-3844

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 112 works

Citation information provided by
Web of Science

References (68)

A general framework for the assessment of solar fuel technologies Herron, Jeffrey A.; Kim, Jiyong; Upadhye, Aniruddha A. Energy & Environmental Science, Vol. 8, Issue 1 https://doi.org/10.1039/C4EE01958J	journal	January 2015
An Insight into Artificial Leaves for Sustainable Energy Inspired by Natural Photosynthesis Zhou, Han; Fan, Tongxiang; Zhang, Di ChemCatChem, Vol. 3, Issue 3 https://doi.org/10.1002/cctc.201000266	journal	December 2010
Recent advances in hybrid photocatalysts for solar fuel production Tran, Phong D.; Wong, Lydia H.; Barber, James Energy & Environmental Science, Vol. 5, Issue 3 https://doi.org/10.1039/c2ee02849b	journal	January 2012
Tailoring Cu valence and oxygen vacancy in Cu/TiO2 catalysts for enhanced CO2 photoreduction efficiency Liu, Lianjun; Gao, Fei; Zhao, Huilei Applied Catalysis B: Environmental, Vol. 134-135 https://doi.org/10.1016/j.apcatb.2013.01.040	journal	May 2013
Photochemical and Photoelectrochemical Reduction of CO ₂ Kumar, Bhupendra; Llorente, Mark; Froehlich, Jesse Annual Review of Physical Chemistry, Vol. 63, Issue 1 https://doi.org/10.1146/annurev-physchem-032511-143759	journal	May 2012
Solar fuels editorial Dasgupta, Siddharth; Brunschwig, Bruce S.; Winkler, Jay R. Chemical Society Reviews, Vol. 42, Issue 6 https://doi.org/10.1039/c3cs90016a	journal	January 2013
Composition-dependent activity of Cu–Pt alloy nanocubes for electrocatalytic CO ₂ reduction Zhao, Xueyu; Luo, Binbin; Long, Ran Journal of Materials Chemistry A, Vol. 3, Issue 8 https://doi.org/10.1039/C4TA06608A	journal	January 2015
Recent advances in the photocatalytic conversion of carbon dioxide to fuels with water and/or hydrogen using solar energy and beyond Izumi, Yasuo Coordination Chemistry Reviews, Vol. 257, Issue 1 https://doi.org/10.1016/j.ccr.2012.04.018	journal	January 2013
Photocatalytic Reduction of CO ₂ on TiO ₂ and Other Semiconductors Habisreutinger, Severin N.; Schmidt-Mende, Lukas; Stolarczyk, Jacek K. Angewandte Chemie International Edition, Vol. 52, Issue 29 https://doi.org/10.1002/anie.201207199	journal	June 2013
Photocatalytic CO ₂ Reduction using Non-Titanium Metal Oxides and Sulfides Navalón, Sergio; Dhakshinamoorthy, Amarajothi; Álvaro, Mercedes ChemSusChem, Vol. 6, Issue 4 https://doi.org/10.1002/cssc.201200670	journal	March 2013
Photocatalytic Conversion of CO ₂ into Renewable Hydrocarbon Fuels: State-of-the-Art Accomplishment, Challenges, and Prospects Tu, Wenguang; Zhou, Yong; Zou, Zhigang Advanced Materials, Vol. 26, Issue 27 https://doi.org/10.1002/adma.201400087	journal	May 2014
Zinc Gallogermanate Solid Solution: A Novel Photocatalyst for Efficiently Converting CO ₂ into Solar Fuels Yan, Shicheng; Wang, Jiajia; Gao, Honglin Advanced Functional Materials, Vol. 23, Issue 14 https://doi.org/10.1002/adfm.201202484	journal	November 2012
Photocatalytic Conversion of CO2 in Water over Layered Double Hydroxides Teramura, Kentaro; Iguchi, Shoji; Mizuno, Yuto Angewandte Chemie, Vol. 124, Issue 32 https://doi.org/10.1002/ange.201201847	journal	July 2012
Photocatalytic conversion of carbon dioxide into methanol using optimized layered double hydroxide catalysts Ahmed, Naveed; Morikawa, Motoharu; Izumi, Yasuo Catalysis Today, Vol. 185, Issue 1 https://doi.org/10.1016/j.cattod.2011.08.010	journal	May 2012
Photocatalytic Reduction of CO ₂ to CO in the Presence of H ₂ or CH ₄ as a Reductant over MgO Teramura, Kentaro; Tanaka, Tsunehiro; Ishikawa, Haruka The Journal of Physical Chemistry B, Vol. 108, Issue 1 https://doi.org/10.1021/jp0362943	journal	January 2004
Defect-Rich Ultrathin ZnAl-Layered Double Hydroxide Nanosheets for Efficient Photoreduction of CO ₂ to CO with Water Zhao, Yufei; Chen, Guangbo; Bian, Tong Advanced Materials, Vol. 27, Issue 47 https://doi.org/10.1002/adma.201503730	journal	October 2015
Integration of an Inorganic Semiconductor with a Metal-Organic Framework: A Platform for Enhanced Gaseous Photocatalytic Reactions Li, Rui; Hu, Jiahua; Deng, Mingsen Advanced Materials, Vol. 26, Issue 28 https://doi.org/10.1002/adma.201400428	journal	May 2014
Layered Double Hydroxide Nanostructured Photocatalysts for Renewable Energy Production Zhao, Yufei; Jia, Xiaodan; Waterhouse, Geoffrey I. N. Advanced Energy Materials, Vol. 6, Issue 6 https://doi.org/10.1002/aenm.201501974	journal	December 2015
Anthropogenic Chemical Carbon Cycle for a Sustainable Future Olah, George A.; Prakash, G. K. Surya; Goeppert, Alain Journal of the American Chemical Society, Vol. 133, Issue 33 https://doi.org/10.1021/ja202642y	journal	August 2011
Complete Photocatalytic Reduction of CO ₂ to Methane by H ₂ under Solar Light Irradiation Sastre, Francesc; Puga, Alberto V.; Liu, Lichen Journal of the American Chemical Society, Vol. 136, Issue 19 https://doi.org/10.1021/ja500924t	journal	April 2014
Photomethanation of Gaseous CO ₂ over Ru/Silicon Nanowire Catalysts with Visible and Near-Infrared Photons O'Brien, Paul G.; Sandhel, Amit; Wood, Thomas E. Advanced Science, Vol. 1, Issue 1 https://doi.org/10.1002/advs.201400001	journal	November 2014
Photothermal Conversion of CO ₂ into CH ₄ with H ₂ over Group VIII Nanocatalysts: An Alternative Approach for Solar Fuel Production Meng, Xianguang; Wang, Tao; Liu, Lequan Angewandte Chemie, Vol. 126, Issue 43 https://doi.org/10.1002/ange.201404953	journal	July 2014
Viable Photocatalysts under Solar-Spectrum Irradiation: Nonplasmonic Metal Nanoparticles Sarina, Sarina; Zhu, Huai-Yong; Xiao, Qi Angewandte Chemie International Edition, Vol. 53, Issue 11 https://doi.org/10.1002/anie.201308145	journal	February 2014
Enhancing Catalytic Performance of Palladium in Gold and Palladium Alloy Nanoparticles for Organic Synthesis Reactions through Visible Light Irradiation at Ambient Temperatures Sarina, Sarina; Zhu, Huaiyong; Jaatinen, Esa Journal of the American Chemical Society, Vol. 135, Issue 15 https://doi.org/10.1021/ja400527a	journal	April 2013
Large-scale, low-cost synthesis of monodispersed gold nanorods using a gemini surfactant Xu, Yong; Zhao, Yang; Chen, Lei Nanoscale, Vol. 7, Issue 15 https://doi.org/10.1039/C5NR00343A	journal	January 2015
Effects of Intra- and Interband Transitions on Electron-Phonon Coupling and Electron Heat Capacity After Short-Pulsed Laser Heating Hopkins, Patrick E.; Duda, John C.; Salaway, Richard N. Nanoscale and Microscale Thermophysical Engineering, Vol. 12, Issue 4 https://doi.org/10.1080/15567260802591985	journal	December 2008
Pd nanoparticles formation by femtosecond laser irradiation and the nonlinear optical properties at 532 nm using nanosecond laser pulses Fan, Guanghua; Qu, Shiliang; Wang, Qiang Journal of Applied Physics, Vol. 109, Issue 2 https://doi.org/10.1063/1.3533738	journal	January 2011
Refractive Index Susceptibility of the Plasmonic Palladium Nanoparticle: Potential as the Third Plasmonic Sensing Material Sugawa, Kosuke; Tahara, Hironobu; Yamashita, Ayane ACS Nano, Vol. 9, Issue 2 https://doi.org/10.1021/nn506800a	journal	January 2015
Nonlinear optical absorption and refraction in Ru, Pd, and Au nanoparticle suspensions Ganeev, R. A.; Boltaev, G. S.; Tugushev, R. I. Applied Physics B, Vol. 100, Issue 3 https://doi.org/10.1007/s00340-010-3979-9	journal	March 2010
Size-Dependence of Surface Plasmon Resonance and Oxidation for Pd Nanocubes Synthesized via a Seed Etching Process Xiong, Yujie; Chen, Jingyi; Wiley, Benjamin Nano Letters, Vol. 5, Issue 7 https://doi.org/10.1021/nl0508826	journal	July 2005
Ultraviolet–visible absorption spectra of the colloidal metallic elements Creighton, J. Alan; Eadon, Desmond G. J. Chem. Soc., Faraday Trans., Vol. 87, Issue 24 https://doi.org/10.1039/FT9918703881	journal	January 1991
Defective TiO2 with oxygen vacancies: synthesis, properties and photocatalytic applications Pan, Xiaoyang; Yang, Min-Quan; Fu, Xianzhi Nanoscale, Vol. 5, Issue 9 https://doi.org/10.1039/c3nr00476g	journal	January 2013
Adsorption CO2 on the perfect and oxygen vacancy defect surfaces of anatase TiO2 and its photocatalytic mechanism of conversion to CO Pipornpong, Waranyu; Wanbayor, Raina; Ruangpornvisuti, Vithaya Applied Surface Science, Vol. 257, Issue 24 https://doi.org/10.1016/j.apsusc.2011.06.013	journal	October 2011
Self-Doped Ti ³⁺ Enhanced Photocatalyst for Hydrogen Production under Visible Light Zuo, Fan; Wang, Le; Wu, Tao Journal of the American Chemical Society, Vol. 132, Issue 34 https://doi.org/10.1021/ja103843d	journal	September 2010
Spontaneous Dissociation of CO ₂ to CO on Defective Surface of Cu(I)/TiO _{2– x} Nanoparticles at Room Temperature Liu, Lianjun; Zhao, Cunyu; Li, Ying The Journal of Physical Chemistry C, Vol. 116, Issue 14 https://doi.org/10.1021/jp300932b	journal	March 2012
Cu(II) Oxide Amorphous Nanoclusters Grafted Ti ³⁺ Self-Doped TiO ₂ : An Efficient Visible Light Photocatalyst Liu, Min; Qiu, Xiaoqing; Miyauchi, Masahiro Chemistry of Materials, Vol. 23, Issue 23 https://doi.org/10.1021/cm203025b	journal	December 2011
Size-Dependent Electrocatalytic Reduction of CO ₂ over Pd Nanoparticles Gao, Dunfeng; Zhou, Hu; Wang, Jing Journal of the American Chemical Society, Vol. 137, Issue 13 https://doi.org/10.1021/jacs.5b00046	journal	March 2015
Pd-Catalyzed Electrohydrogenation of Carbon Dioxide to Formate: High Mass Activity at Low Overpotential and Identification of the Deactivation Pathway Min, Xiaoquan; Kanan, Matthew W. Journal of the American Chemical Society, Vol. 137, Issue 14 https://doi.org/10.1021/ja511890h	journal	April 2015
Photochemical Reduction of CO ₂ Using TiO ₂ : Effects of Organic Adsorbates on TiO ₂ and Deposition of Pd onto TiO ₂ Yui, Tatsuto; Kan, Akira; Saitoh, Chieko ACS Applied Materials & Interfaces, Vol. 3, Issue 7 https://doi.org/10.1021/am200425y	journal	June 2011
Methanol synthesis from CO2/H2 using Ga2O3–Pd/silica catalysts: Kinetic modeling Chiavassa, Dante L.; Collins, Sebastián E.; Bonivardi, Adrian L. Chemical Engineering Journal, Vol. 150, Issue 1 https://doi.org/10.1016/j.cej.2009.02.013	journal	July 2009
Hydrogen Spillover in Ga2O3–Pd/SiO2 Catalysts for Methanol Synthesis from CO2/H2 Collins, Sebastián E.; Chiavassa, Dante L.; Bonivardi, Adrian L. Catalysis Letters, Vol. 103, Issue 1-2 https://doi.org/10.1007/s10562-005-6507-5	journal	September 2005
An infrared study of the intermediates of methanol synthesis from carbon dioxide over Pd/-GaO Collins, S.; Baltanas, M.; Bonivardi, A. Journal of Catalysis, Vol. 226, Issue 2 https://doi.org/10.1016/j.jcat.2004.06.012	journal	September 2004
Bifunctional Mechanism of CO ₂ Methanation on Pd-MgO/SiO ₂ Catalyst: Independent Roles of MgO and Pd on CO ₂ Methanation Kim, Hyun You; Lee, Hyuck Mo; Park, Jung-Nam The Journal of Physical Chemistry C, Vol. 114, Issue 15 https://doi.org/10.1021/jp100938v	journal	March 2010
Recent advances in catalytic hydrogenation of carbon dioxide Wang, Wei; Wang, Shengping; Ma, Xinbin Chemical Society Reviews, Vol. 40, Issue 7 https://doi.org/10.1039/c1cs15008a	journal	January 2011
Heterogeneous Catalysis on Atomically Dispersed Supported Metals: CO ₂ Reduction on Multifunctional Pd Catalysts Kwak, Ja Hun; Kovarik, Libor; Szanyi, János ACS Catalysis, Vol. 3, Issue 9 https://doi.org/10.1021/cs4001392	journal	August 2013
Efficient Coupling of Solar Energy to Catalytic Hydrogenation by Using Well-Designed Palladium Nanostructures Long, Ran; Rao, Zhoulv; Mao, Keke Angewandte Chemie International Edition, Vol. 54, Issue 8 https://doi.org/10.1002/anie.201407785	journal	October 2014
Directly Hydrothermal Growth of Single Crystal Nb3O7(OH) Nanorod Film for High Performance Dye-Sensitized Solar Cells Zhang, Haimin; Wang, Yun; Yang, Dongjiang Advanced Materials, Vol. 24, Issue 12 https://doi.org/10.1002/adma.201104650	journal	February 2012
The Rational Design of a Single-Component Photocatalyst for Gas-Phase CO ₂ Reduction Using Both UV and Visible Light Hoch, Laura B.; Wood, Thomas E.; O'Brien, Paul G. Advanced Science, Vol. 1, Issue 1 https://doi.org/10.1002/advs.201400013	journal	December 2014
A Plasmonic Molybdenum Oxide Hybrid with Reversible Tunability for Visible-Light-Enhanced Catalytic Reactions Cheng, Hefeng; Qian, Xufang; Kuwahara, Yasutaka Advanced Materials, Vol. 27, Issue 31 https://doi.org/10.1002/adma.201501172	journal	July 2015
Effective work function of Pt, Pd, and Re on atomic layer deposited HfO2 Gu, Diefeng; Dey, Sandwip K.; Majhi, Prashant Applied Physics Letters, Vol. 89, Issue 8 https://doi.org/10.1063/1.2336718	journal	August 2006
A Temperature-Programmed and Transient Kinetic Study of CO2Activation and Methanation over CeO2Supported Noble Metals Leitenburg, Carla de; Trovarelli, Alessandro; Kašpar, Jan Journal of Catalysis, Vol. 166, Issue 1 https://doi.org/10.1006/jcat.1997.1498	journal	February 1997
Catalytic reduction of CO ₂ by H ₂ for synthesis of CO, methanol and hydrocarbons: challenges and opportunities Porosoff, Marc D.; Yan, Binhang; Chen, Jingguang G. Energy & Environmental Science, Vol. 9, Issue 1 https://doi.org/10.1039/C5EE02657A	journal	January 2016
Mechanism of CO ₂ Hydrogenation on Pd/Al ₂ O ₃ Catalysts: Kinetics and Transient DRIFTS-MS Studies Wang, Xiang; Shi, Hui; Kwak, Ja Hun ACS Catalysis, Vol. 5, Issue 11 https://doi.org/10.1021/acscatal.5b01464	journal	September 2015
Coke removal from deactivated Co–Ni steam reforming catalyst using different gasifying agents: An analysis of the gas–solid reaction kinetics Alenazey, F.; Cooper, C.; Dave, C. Catalysis Communications, Vol. 10, Issue 4 https://doi.org/10.1016/j.catcom.2008.10.010	journal	January 2009
Selective conversion of syngas to light olefins Jiao, F.; Li, J.; Pan, X. Science, Vol. 351, Issue 6277 https://doi.org/10.1126/science.aaf1835	journal	March 2016
Coking and regeneration of palladium-doped H₃PW₁₂O₄₀/SiO₂ catalysts Siddiqui, M. R. H.; Holmes, S.; He, H. Catalysis Letters, Vol. 66, Issue 1/2, p. 53-57 https://doi.org/10.1023/A:1019083103395	journal	January 2000
Effects of Temperature on the Raman Spectra and Dispersed Oxides Xie, Shuibo; Iglesia, Enrique; Bell, Alexis T. The Journal of Physical Chemistry B, Vol. 105, Issue 22 https://doi.org/10.1021/jp004434s	journal	June 2001
Temperature dependence of Raman-active optical phonons in Bi ₂ Se ₃ and Sb ₂ Te ₃ Kim, Y.; Chen, X.; Wang, Z. Applied Physics Letters, Vol. 100, Issue 7 https://doi.org/10.1063/1.3685465	journal	February 2012
Advantage of anti-Stokes Raman scattering for high-temperature measurements Fujimori, Hirotaka; Kakihana, Masato; Ioku, Koji Applied Physics Letters, Vol. 79, Issue 7 https://doi.org/10.1063/1.1394174	journal	August 2001
Temperature-Dependent Anti-Stokes/Stokes Ratios under Surface-Enhanced Raman Scattering Conditions Maher, R. C.; Cohen, L. F.; Gallop, J. C. The Journal of Physical Chemistry B, Vol. 110, Issue 13 https://doi.org/10.1021/jp056466r	journal	April 2006
Shift of the frequency and Stokes-anti-Stokes ratio of Raman spectra from diamond powders Nachal'naya, T. A.; Andreyev, V. D.; Gabrusenok, E. V. Diamond and Related Materials, Vol. 3, Issue 11-12 https://doi.org/10.1016/0925-9635(94)90146-5	journal	November 1994
Raman study of laser-induced heating effects in free-standing silicon nanocrystals Han, Lihao; Zeman, Miro; Smets, Arno H. M. Nanoscale, Vol. 7, Issue 18 https://doi.org/10.1039/C5NR00468C	journal	January 2015
In Situ Vibrational Spectroscopy Studies of Supported Niobium Oxide Catalysts Burcham, Loyd J.; Datka, Jerzy; Wachs, Israel E. The Journal of Physical Chemistry B, Vol. 103, Issue 29 https://doi.org/10.1021/jp990289a	journal	July 1999
Photocatalytic CO ₂ Reduction with H ₂ O on TiO ₂ Nanocrystals: Comparison of Anatase, Rutile, and Brookite Polymorphs and Exploration of Surface Chemistry Liu, Lianjun; Zhao, Huilei; Andino, Jean M. ACS Catalysis, Vol. 2, Issue 8 https://doi.org/10.1021/cs300273q	journal	July 2012
Facile preparation of black Nb ⁴⁺ self-doped K ₄ Nb ₆ O ₁₇ microspheres with high solar absorption and enhanced photocatalytic activity Zhou, Chao; Zhao, Yufei; Shang, Lu Chemical Communications, Vol. 50, Issue 67 https://doi.org/10.1039/C4CC04432K	journal	January 2014
New Hydrogen-Evolution Heteronanostructured Photocatalysts: Pt-Nb ₃ O ₇ (OH) and Cu-Nb ₃ O ₇ (OH) Hmadeh, Mohamad; Hoepfner, Veronika; Larios, Eduardo ChemSusChem, Vol. 7, Issue 8 https://doi.org/10.1002/cssc.201402173	journal	June 2014
Photoreduction of CO2 on BiOCl nanoplates with the assistance of photoinduced oxygen vacancies Zhang, Ling; Wang, Wenzhong; Jiang, Dong Nano Research, Vol. 8, Issue 3 https://doi.org/10.1007/s12274-014-0564-2	journal	September 2014
CO ₂ as a Probe for Monitoring the Surface Defects on TiO ₂ (110)Temperature-Programmed Desorption Thompson, Tracy L.; Diwald, Oliver; Yates, John T. The Journal of Physical Chemistry B, Vol. 107, Issue 42 https://doi.org/10.1021/jp030430m	journal	October 2003

Cited By (16)

Alumina‐Supported CoFe Alloy Catalysts Derived from Layered‐Double‐Hydroxide Nanosheets for Efficient Photothermal CO ₂ Hydrogenation to Hydrocarbons Chen, Guangbo; Gao, Rui; Zhao, Yufei Advanced Materials, Vol. 30, Issue 3 https://doi.org/10.1002/adma.201704663	journal	December 2017
Emerging Applications of Plasmons in Driving CO ₂ Reduction and N ₂ Fixation Yang, Jianhua; Guo, Yanzhen; Lu, Wenzheng Advanced Materials, Vol. 30, Issue 48 https://doi.org/10.1002/adma.201802227	journal	July 2018
Towards Solar Methanol: Past, Present, and Future Tountas, Athanasios A.; Peng, Xinyue; Tavasoli, Alexandra V. Advanced Science, Vol. 6, Issue 8 https://doi.org/10.1002/advs.201801903	journal	February 2019
Full-Spectrum Solar-Light-Activated Photocatalysts for Light-Chemical Energy Conversion Wang, Xiaoning; Wang, Fulei; Sang, Yuanhua Advanced Energy Materials, Vol. 7, Issue 23 https://doi.org/10.1002/aenm.201700473	journal	June 2017
Size-Tunable Photothermal Germanium Nanocrystals Sun, Wei; Zhong, Grace; Kübel, Christian Angewandte Chemie, Vol. 129, Issue 22 https://doi.org/10.1002/ange.201701321	journal	April 2017
Von Sonnenlicht zu Brennstoffen: aktuelle Fortschritte der C ₁ ‐Solarchemie Chen, Guangbo; Waterhouse, Geoffrey I. N.; Shi, Run Angewandte Chemie, Vol. 131, Issue 49 https://doi.org/10.1002/ange.201814313	journal	September 2019
Kopplung von Solarenergie und Wärmeenergie zur Kohlendioxidreduktion: Aktueller Stand und Perspektiven Wang, Zhou‐jun; Song, Hui; Liu, Huimin Angewandte Chemie, Vol. 132, Issue 21 https://doi.org/10.1002/ange.201907443	journal	February 2020
From Solar Energy to Fuels: Recent Advances in Light-Driven C ₁ Chemistry Chen, Guangbo; Waterhouse, Geoffrey I. N.; Shi, Run Angewandte Chemie International Edition, Vol. 58, Issue 49 https://doi.org/10.1002/anie.201814313	journal	September 2019
Coupling of Solar Energy and Thermal Energy for Carbon Dioxide Reduction: Status and Prospects Wang, Zhou-jun; Song, Hui; Liu, Huimin Angewandte Chemie International Edition https://doi.org/10.1002/anie.201907443	journal	February 2020
Surface Plasmon Resonance-Enhanced Visible-NIR-Driven Photocatalytic and Photothermal Catalytic Performance by Ag/Mesoporous Black TiO ₂ Nanotube Heterojunctions Qiao, Panzhe; Sun, Bojing; Li, Haoze Chemistry - An Asian Journal, Vol. 14, Issue 1 https://doi.org/10.1002/asia.201801428	journal	November 2018
Polymorph selection towards photocatalytic gaseous CO2 hydrogenation Yan, Tingjiang; Wang, Lu; Liang, Yan Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-10524-2	journal	June 2019
Enhanced photothermal reduction of gaseous CO ₂ over silicon photonic crystal supported ruthenium at ambient temperature O’Brien, Paul G.; Ghuman, Kulbir K.; Jelle, Abdinoor A. Energy & Environmental Science, Vol. 11, Issue 12 https://doi.org/10.1039/c8ee02347f	journal	January 2018
Light-driven thermocatalytic CO ₂ reduction over surface-passivated β-Mo ₂ C nanowires: enhanced catalytic stability by light Bai, Yujie; Zhao, Jie; Feng, Shuaijun Chemical Communications, Vol. 55, Issue 32 https://doi.org/10.1039/c9cc01479a	journal	January 2019
Graphene nanocrystals in CO ₂ photoreduction with H ₂ O for fuel production Darkwah, Williams Kweku; Teye, Godfred Kwesi; Ao, Yanhui Nanoscale Advances, Vol. 2, Issue 3 https://doi.org/10.1039/c9na00756c	journal	January 2020
Reduction of carbon dioxide on photoexcited nanoparticles of VIII group metals Dai, Xinyan; Sun, Yugang Nanoscale, Vol. 11, Issue 36 https://doi.org/10.1039/c9nr05971g	journal	January 2019
Size-Tunable Photothermal Germanium Nanocrystals Sun, Wei; Zhong, Grace; Kübel, Christian Angewandte Chemie International Edition, Vol. 56, Issue 22 https://doi.org/10.1002/anie.201701321	journal	April 2017

Similar Records

Photothermal Catalyst Engineering: Hydrogenation of Gaseous CO₂ with High Activity and Tailored Selectivity

Journal Article · Tue Jul 25 00:00:00 EDT 2017 · Advanced Science · OSTI ID:1329168

Jia, Jia; Wang, Hong; Lu, Zhuole; +25 more

Mo ₂ TiC ₂ MXene-Supported Ru Clusters for Efficient Photothermal Reverse Water–Gas Shift

Journal Article · Fri Dec 30 00:00:00 EST 2022 · ACS Nano · OSTI ID:1329168

Wu, Zhiyi; Shen, Jiahui; Li, Chaoran; +17 more

Magnetic/NIR-responsive drug carrier, multicolor cell imaging, and enhanced photothermal therapy of gold capped magnetite-fluorescent carbon hybrid nanoparticles

Journal Article · Wed Mar 25 00:00:00 EDT 2015 · Nanoscale · OSTI ID:1329168

Wang, Hui; Cao, Guixin; Gai, Zheng; +3 more

Related Subjects

77 NANOSCIENCE AND NANOTECHNOLOGY

Title: Visible and near-infrared photothermal catalyzed hydrogenation of gaseous CO2 over nanostructured Pd@Nb2O5

Citation Formats

References (68)

Cited By (16)

Similar Records

Related Subjects

Title: Visible and near-infrared photothermal catalyzed hydrogenation of gaseous CO₂ over nanostructured Pd@Nb₂O₅