Determination of the mechanism and extent of surface degradation in Ni-based cathode materials after repeated electrochemical cycling

Hwang, Sooyeon; Kim, Se Young; Chung, Kyung Yoon; Stach, Eric A.; Kim, Seung Min; Chang, Wonyoung

doi:10.1063/1.4963723

Title: Determination of the mechanism and extent of surface degradation in Ni-based cathode materials after repeated electrochemical cycling

Journal Article · Tue Sep 27 00:00:00 EDT 2016 · APL Materials

DOI:https://doi.org/10.1063/1.4963723· OSTI ID:1328533

Hwang, Sooyeon ^[1];

^[1]; Chung, Kyung Yoon ^[1];

^[2]; Kim, Seung Min ^[3]; Chang, Wonyoung ^[1]

Center for Energy Convergence, Korea Institute of Science and Technology (KIST), Seoul 02792, South Korea
Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973, USA
Carbon Composite Materials Research Centre, Institute of Advanced Composite Materials, KIST, Wanju-gun 55324, South Korea

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0012704

OSTI ID:: 1328533

Alternate ID(s):: OSTI ID: 1420461

Journal Information:: APL Materials, Journal Name: APL Materials Vol. 4 Journal Issue: 9; ISSN 2166-532X

Publisher:: American Institute of PhysicsCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 18 works

Citation information provided by
Web of Science

References (26)

An Electron Energy-Loss Spectrometry Study of Charge Compensation in LiNi _0.8 Co _0.2 O ₂ Graetz, J.; Ahn, C. C.; Yazami, R. The Journal of Physical Chemistry B, Vol. 107, Issue 13 https://doi.org/10.1021/jp026484y	journal	April 2003
Extraction of EELS white-line intensities of manganese compounds: Methods, accuracy, and valence sensitivity Riedl, T.; Gemming, T.; Wetzig, K. Ultramicroscopy, Vol. 106, Issue 4-5 https://doi.org/10.1016/j.ultramic.2005.09.002	journal	March 2006
Understanding local degradation of cycled Ni-rich cathode materials at high operating temperature for Li-ion batteries Hwang, Sooyeon; Kim, Dong Hyun; Chung, Kyung Yoon Applied Physics Letters, Vol. 105, Issue 10 https://doi.org/10.1063/1.4895336	journal	September 2014
Significant Improvement of Electrochemical Performance of AlF₃-Coated Li[Ni_0.8Co_0.1Mn_0.1]O₂ Cathode Materials Woo, S.-U.; Yoon, C. S.; Amine, K. Journal of The Electrochemical Society, Vol. 154, Issue 11, p. A1005-A1009 https://doi.org/10.1149/1.2776160	journal	January 2007
Review—High-Capacity Li[Ni _1- _x Co _x _/2 Mn _x _/2 ]O ₂ ( x = 0.1, 0.05, 0) Cathodes for Next-Generation Li-Ion Battery Yoon, Chong S.; Choi, Moon Ho; Lim, Byung-Beom Journal of The Electrochemical Society, Vol. 162, Issue 14 https://doi.org/10.1149/2.0101514jes	journal	January 2015
Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries Lin, Feng; Markus, Isaac M.; Nordlund, Dennis Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4529	journal	March 2014
Nickel-Rich Layered Microspheres Cathodes: Lithium/Nickel Disordering and Electrochemical Performance Fu, Chaochao; Li, Guangshe; Luo, Dong ACS Applied Materials & Interfaces, Vol. 6, Issue 18 https://doi.org/10.1021/am5030726	journal	September 2014
Degradation analysis of a Ni-based layered positive-electrode active material cycled at elevated temperatures studied by scanning transmission electron microscopy and electron energy-loss spectroscopy Kojima, Y.; Muto, S.; Tatsumi, K. Journal of Power Sources, Vol. 196, Issue 18 https://doi.org/10.1016/j.jpowsour.2011.05.017	journal	September 2011
EELS analysis of cation valence states and oxygen vacancies in magnetic oxides Wang, Z. L.; Yin, J. S.; Jiang, Y. D. Micron, Vol. 31, Issue 5 https://doi.org/10.1016/S0968-4328(99)00139-0	journal	October 2000
Electronic Structure of Lithium Nickel Oxides by Electron Energy Loss Spectroscopy Koyama, Yukinori; Mizoguchi, Teruyasu; Ikeno, Hidekazu The Journal of Physical Chemistry B, Vol. 109, Issue 21 https://doi.org/10.1021/jp050486b	journal	June 2005
Capacity-Fading Mechanisms of LiNiO[sub 2]-Based Lithium-Ion Batteries Muto, Shunsuke; Sasano, Yusuke; Tatsumi, Kazuyoshi Journal of The Electrochemical Society, Vol. 156, Issue 5 https://doi.org/10.1149/1.3076137	journal	January 2009
Observation of anisotropic microstructural changes during cycling in LiNi0.5Co0.2Mn0.3O2 cathode material Kuriyama, Hiromichi; Saruwatari, Hidesato; Satake, Hideki Journal of Power Sources, Vol. 275 https://doi.org/10.1016/j.jpowsour.2014.10.197	journal	February 2015
3D Woven-Like Carbon Micropattern Decorated with Silicon Nanoparticles for Use in Lithium-Ion Batteries Kang, Da-Young; Kim, Cheolho; Gueon, Donghee ChemSusChem, Vol. 8, Issue 20 https://doi.org/10.1002/cssc.201501041	journal	September 2015
White lines and $d$ -band occupancy for the $3 d$ transition-metal oxides and lithium transition-metal oxides Graetz, Jason; Ahn, Channing C.; Ouyang, Hao Physical Review B, Vol. 69, Issue 23 https://doi.org/10.1103/PhysRevB.69.235103	journal	June 2004
Atomic-Resolution Visualization of Distinctive Chemical Mixing Behavior of Ni, Co, and Mn with Li in Layered Lithium Transition-Metal Oxide Cathode Materials Yan, Pengfei; Zheng, Jianming; Lv, Dongping Chemistry of Materials, Vol. 27, Issue 15 https://doi.org/10.1021/acs.chemmater.5b02016	journal	July 2015
Investigating the Reversibility of Structural Modifications of Li _x Ni _y Mn _z Co _{1– y – z} O ₂ Cathode Materials during Initial Charge/Discharge, at Multiple Length Scales Hwang, Sooyeon; Kim, Seung Min; Bak, Seong-Min Chemistry of Materials, Vol. 27, Issue 17 https://doi.org/10.1021/acs.chemmater.5b02457	journal	August 2015
Building better batteries Armand, M.; Tarascon, J.-M. Nature, Vol. 451, Issue 7179, p. 652-657 https://doi.org/10.1038/451652a	journal	February 2008
Evolution of Lattice Structure and Chemical Composition of the Surface Reconstruction Layer in Li _1.2 Ni _0.2 Mn _0.6 O ₂ Cathode Material for Lithium Ion Batteries Yan, Pengfei; Nie, Anmin; Zheng, Jianming Nano Letters, Vol. 15, Issue 1 https://doi.org/10.1021/nl5038598	journal	December 2014
Identifying surface structural changes in layered Li-excess nickel manganese oxides in high voltage lithium ion batteries: A joint experimental and theoretical study Xu, Bo; Fell, Christopher R.; Chi, Miaofang Energy & Environmental Science, Vol. 4, Issue 6 https://doi.org/10.1039/c1ee01131f	journal	January 2011
Understanding the Degradation Mechanisms of LiNi _0.5 Co _0.2 Mn _0.3 O ₂ Cathode Material in Lithium Ion Batteries Jung, Sung-Kyun; Gwon, Hyeokjo; Hong, Jihyun Advanced Energy Materials, Vol. 4, Issue 1 https://doi.org/10.1002/aenm.201300787	journal	August 2013
Balancing stability and specific energy in Li-rich cathodes for lithium ion batteries: a case study of a novel Li–Mn–Ni–Co oxide Li, Qi; Li, Guangshe; Fu, Chaochao Journal of Materials Chemistry A, Vol. 3, Issue 19 https://doi.org/10.1039/C5TA00929D	journal	January 2015
Electrical Energy Storage for the Grid: A Battery of Choices Dunn, B.; Kamath, H.; Tarascon, J. -M. Science, Vol. 334, Issue 6058 https://doi.org/10.1126/science.1212741	journal	November 2011
Capacity Fade Mechanisms and Side Reactions in Lithium-Ion Batteries Arora, Pankaj; White, Ralph E.; Doyle, Marc Journal of The Electrochemical Society, Vol. 145, Issue 10, p. 3647-3667 https://doi.org/10.1149/1.1838857	journal	January 1998
Nanoscale Phase Separation, Cation Ordering, and Surface Chemistry in Pristine Li _1.2 Ni _0.2 Mn _0.6 O ₂ for Li-Ion Batteries Gu, Meng; Genc, Arda; Belharouak, Ilias Chemistry of Materials, Vol. 25, Issue 11 https://doi.org/10.1021/cm4009392	journal	May 2013
Correlation between dissolution behavior and electrochemical cycling performance for LiNi1/3Co1/3Mn1/3O2-based cells Zheng, Honghe; Sun, Qingna; Liu, Gao Journal of Power Sources, Vol. 207 https://doi.org/10.1016/j.jpowsour.2012.01.122	journal	June 2012
First Evidence of Manganese–Nickel Segregation and Densification upon Cycling in Li-Rich Layered Oxides for Lithium Batteries Boulineau, Adrien; Simonin, Loïc; Colin, Jean-François Nano Letters, Vol. 13, Issue 8 https://doi.org/10.1021/nl4019275	journal	July 2013

Similar Records

Origin of Phase Separation in Ni-Rich Layered Oxide Cathode Materials During Electrochemical Cycling

Journal Article · Thu Oct 19 00:00:00 EDT 2023 · Chemistry of Materials · OSTI ID:1328533

Liu, Sizhan; West, Patrick J.; Zhong, Hui; +7 more

On the P2-Na_xCo_1–y (Mn_2/3Ni_1/3)yO₂ Cathode Materials for Sodium-Ion Batteries: Synthesis, Electrochemical Performance, and Redox Processes Occurring during the Electrochemical Cycling

Journal Article · Fri Nov 03 00:00:00 EDT 2017 · ACS Applied Materials and Interfaces · OSTI ID:1328533

Doubaji, Siham; Ma, Lu; Asfaw, Habtom Desta; +8 more

Accelerated Evolution of Surface Chemistry Determined by Temperature and Cycling History in Nickel-Rich Layered Cathode Materials

Journal Article · Tue Jun 19 00:00:00 EDT 2018 · ACS Applied Materials and Interfaces · OSTI ID:1328533

Steiner, James D.; Mu, Linqin; Walsh, Julia; +6 more

Title: Determination of the mechanism and extent of surface degradation in Ni-based cathode materials after repeated electrochemical cycling

Citation Formats

References (26)

Similar Records

Related Subjects