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Title: Synthesis of substituted pyrazines

Patent ·
OSTI ID:1327969

A method for synthesizing a pyrazine-containing material according to one embodiment includes contacting an iminodiacetonitrile derivative with a base and a reagent selected from a group consisting of hydroxylamine, a hydroxylamine salt, an aliphatic primary amine, a secondary amine, an aryl-substituted alkylamine a heteroaryl-substituted alkyl amine, an alcohol, an alkanolamine and an aryl alcoholamine. Additional methods and several reaction products are presented. ##STR00001##

Research Organization:
Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC52-07NA27344
Assignee:
Lawrence Livermore National Security, LLC (Livermore, CA)
Patent Number(s):
9,458,115
Application Number:
12/426,774
OSTI ID:
1327969
Resource Relation:
Patent File Date: 2009 Apr 20
Country of Publication:
United States
Language:
English

References (8)

2-Aminopyrazines and the preparation of 2-aminopyrazines and pyrazines patent December 1985
The unusually mild and facile basic hydrolysis of N-nitroso-2-(methylamino)acetonitrile journal November 1976
Theoretical Calculation and Molecular Design for High Explosives: Theoretical Study on Polynitropyrazines and TheirN-oxides journal August 2004
New synthesis of 2-amino-6-alkoxypyrazines from N-nitrosobis (cyanomethyl) amine and alkoxides journal March 1979
Molecular design of analogues of 2,6-diamino-3,5-dinitropyrazine-1-oxide journal January 2004
MATERIALS SCIENCE: Muscles Made from Metal journal April 2003
Surface-Stress Induced Macroscopic Bending of Nanoporous Gold Cantilevers journal May 2004
Charge-Induced Reversible Strain in a Metal journal April 2003