Doped calcium manganites for advanced high-temperature thermochemical energy storage

Babiniec, Sean M.; Coker, Eric N.; Miller, James E.; Ambrosini, Andrea

doi:10.1002/er.3467

Title: Doped calcium manganites for advanced high-temperature thermochemical energy storage

Journal Article · Wed Dec 16 00:00:00 EST 2015 · International Journal of Energy Research

DOI:https://doi.org/10.1002/er.3467· OSTI ID:1327905

Babiniec, Sean M. ^[1]; Coker, Eric N. ^[1]; Miller, James E. ^[1]; Ambrosini, Andrea ^[1]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Developing efficient thermal storage for concentrating solar power plants is essential to reducing the cost of generated electricity, extending or shifting the hours of operation, and facilitating renewable penetration into the grid. Perovskite materials of the CaB_xMn_1-xO_3-δ family, where B = Al or Ti, promise improvements in cost and energy storage density over other perovskites currently under investigation. Thermogravimetric analysis of the thermal reduction and reoxidation of these materials was used to extract equilibrium thermodynamic parameters. Lastly, the results demonstrate that these novel thermochemical energy storage media display the highest reaction enthalpy capacity for perovskites reported to date, with a reaction enthalpy of 390 kJ/kg, a 56% increase over previously reported compositions.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1327905

Report Number(s):: SAND2016-9419J; 647624

Journal Information:: International Journal of Energy Research, Vol. 40, Issue 2; ISSN 0363-907X

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 67 works

Citation information provided by
Web of Science

References (17)

Entropy of oxidation and redox energetics of CaMnO Bakken, E.; Boeriogoates, J.; Grande, T. Solid State Ionics, Vol. 176, Issue 29-30 https://doi.org/10.1016/j.ssi.2005.06.009	journal	September 2005
Experimental study on optimized composition of mixed carbonate salt for sensible heat storage in solar thermal power plant Wu, Yu-ting; Ren, Nan; Wang, Tao Solar Energy, Vol. 85, Issue 9 https://doi.org/10.1016/j.solener.2011.05.004	journal	September 2011
Considerations in the Design of Materials for Solar-Driven Fuel Production Using Metal-Oxide Thermochemical Cycles Miller, James E.; McDaniel, Anthony H.; Allendorf, Mark D. Advanced Energy Materials, Vol. 4, Issue 2, Article No. 1300469 https://doi.org/10.1002/aenm.201300469	journal	October 2013
Chemical Looping Combustion and Chemical Looping with Oxygen Uncoupling Experiments in a Batch Reactor Using Spray-Dried CaMn _{1– x} M _x O _3−δ (M = Ti, Fe, Mg) Particles as Oxygen Carriers Hallberg, Peter; Jing, Dazheng; Rydén, Magnus Energy & Fuels, Vol. 27, Issue 3 https://doi.org/10.1021/ef3013618	journal	March 2013
Thermochemical energy storage at high temperature via redox cycles of Mn and Co oxides: Pure oxides versus mixed ones Carrillo, Alfonso J.; Moya, Javier; Bayón, Alicia Solar Energy Materials and Solar Cells, Vol. 123 https://doi.org/10.1016/j.solmat.2013.12.018	journal	April 2014
Chemical Structures and Performance of Perovskite Oxides Pena, M.; Fierro, J. Chemical Reviews, Vol. 101, Issue 7, p. 1981-2018 https://doi.org/10.1021/cr980129f	journal	July 2001
Exploitation of thermochemical cycles based on solid oxide redox systems for thermochemical storage of solar heat. Part 3: Cobalt oxide monolithic porous structures as integrated thermochemical reactors/heat exchangers Agrafiotis, Christos; Tescari, Stefania; Roeb, Martin Solar Energy, Vol. 114 https://doi.org/10.1016/j.solener.2014.12.037	journal	April 2015
Oxygen non-stoichiometry, high-temperature properties, and phase diagram of CaMnO3–δ Leonidova, Ekaterina I.; Leonidov, Ilya A.; Patrakeev, Mikhail V. Journal of Solid State Electrochemistry, Vol. 15, Issue 5 https://doi.org/10.1007/s10008-010-1288-1	journal	February 2011
Exploitation of thermochemical cycles based on solid oxide redox systems for thermochemical storage of solar heat. Part 2: Redox oxide-coated porous ceramic structures as integrated thermochemical reactors/heat exchangers Agrafiotis, Christos; Roeb, Martin; Schmücker, Martin Solar Energy, Vol. 114 https://doi.org/10.1016/j.solener.2014.12.036	journal	April 2015
Investigation of La Sr1−Co M1−O3− (M = Mn, Fe) perovskite materials as thermochemical energy storage media Babiniec, Sean M.; Coker, Eric N.; Miller, James E. Solar Energy, Vol. 118 https://doi.org/10.1016/j.solener.2015.05.040	journal	August 2015
Kinetic and thermodynamic considerations for oxygen absorption/desorption using cobalt oxide Hutchings, K.; Wilson, M.; Larsen, P. Solid State Ionics, Vol. 177, Issue 1-2 https://doi.org/10.1016/j.ssi.2005.10.005	journal	January 2006
Technical Challenges and Opportunities for Concentrating Solar Power With Thermal Energy Storage Stekli, Joseph; Irwin, Levi; Pitchumani, Ranga Journal of Thermal Science and Engineering Applications, Vol. 5, Issue 2 https://doi.org/10.1115/1.4024143	journal	May 2013
Solar electricity via an Air Brayton cycle with an integrated two-step thermochemical cycle for heat storage based on Co3O4/CoO redox reactions: Thermodynamic analysis Schrader, Andrew J.; Muroyama, Alexander P.; Loutzenhiser, Peter G. Solar Energy, Vol. 118 https://doi.org/10.1016/j.solener.2015.05.045	journal	August 2015
Nonstoichiometry and thermochemical stability of the perovskite-type La1−xSrxMnO3−δ Mizusaki, J. Solid State Ionics, Vol. 49 https://doi.org/10.1016/0167-2738(91)90076-N	journal	December 1991
Nonstoichiometry and reductive decomposition of CaMnO Bakken, E.; Norby, T.; Stolen, S. Solid State Ionics, Vol. 176, Issue 1-2 https://doi.org/10.1016/j.ssi.2004.07.001	journal	January 2005
Factors Affecting the Efficiency of Solar Driven Metal Oxide Thermochemical Cycles Siegel, Nathan P.; Miller, James E.; Ermanoski, Ivan Industrial & Engineering Chemistry Research, Vol. 52, Issue 9, p. 3276-3286 https://doi.org/10.1021/ie400193q	journal	February 2013
Commentary Creutz, Edward Nuclear Applications, Vol. 3, Issue 6 https://doi.org/10.13182/NT67-A27852	journal	June 1967

Cited By (3)

Progress in thermochemical energy storage for concentrated solar power: A review Liu, Dai; Xin-Feng, Long; Bo, Lou International Journal of Energy Research, Vol. 42, Issue 15 https://doi.org/10.1002/er.4183	journal	August 2018
A novel multicriteria sustainability investigation of energy storage systems Acar, Canan; Beskese, Ahmet; Temur, Gül Tekin International Journal of Energy Research, Vol. 43, Issue 12 https://doi.org/10.1002/er.4459	journal	December 2018
Materials design of perovskite solid solutions for thermochemical applications Vieten, Josua; Bulfin, Brendan; Huck, Patrick Energy & Environmental Science, Vol. 12, Issue 4 https://doi.org/10.1039/c9ee00085b	journal	January 2019

Similar Records

Modified Calcium Manganites for Thermochemical Energy Storage Applications

Journal Article · Thu Apr 14 00:00:00 EDT 2022 · Frontiers in Energy Research · OSTI ID:1327905

Miller, James E.; Babiniec, Sean M.; Coker, Eric N.; +3 more

CSP ELEMENTS: High-Temperature Thermochemical Storage with Redox-Stable Perovskites for Concentrating Solar Power

Technical Report · Wed Nov 30 00:00:00 EST 2016 · OSTI ID:1327905

Jackson, Gregory S; Braun, Robert J; Ma, Zhiwen; +5 more

The favourable thermodynamic properties of Fe-doped CaMnO ₃ for thermochemical heat storage

Journal Article · Tue May 05 00:00:00 EDT 2020 · Journal of Materials Chemistry. A · OSTI ID:1327905

Mastronardo, Emanuela; Qian, Xin; Coronado, Juan M.; +1 more

Related Subjects

25 ENERGY STORAGE

Title: Doped calcium manganites for advanced high-temperature thermochemical energy storage

Citation Formats

References (17)

Cited By (3)

Similar Records

Related Subjects