Deoxygenation of Unhindered Alcohols via Reductive Dealkylation of Derived Phosphate Esters
Journal Article
·
· Journal of Organic Chemistry
- Univ. of Illinois, Chicago, IL (United States). Dept. of Chemistry
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Biosciences Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Biochemistry and Cellular & Molecular Biology
Primary alcohols can be deoxygenated cleanly and in high yield by reduction of derived diphenyl phosphate esters with lithium triethylborohydride in tetrahydrofuran at room temperature. Selective deoxygenation of a primary alcohol in the presence of a secondary alcohol was demonstrated. The two-step process can be performed in one pot, making it both simple and convenient.
- Research Organization:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Organization:
- USDOE; Work for Others (WFO)
- Grant/Contract Number:
- AC05-00OR22725
- OSTI ID:
- 1327565
- Journal Information:
- Journal of Organic Chemistry, Vol. 81; ISSN 0022-3263
- Publisher:
- American Chemical SocietyCopyright Statement
- Country of Publication:
- United States
- Language:
- English
Cited by: 5 works
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