Reactivity of a Carbon-Supported Single-Site Molybdenum Dioxo Catalyst for Biodiesel Synthesis

Mouat, Aidan R.; Lohr, Tracy L.; Wegener, Evan C.; Miller, Jeffrey T.; Delferro, Massimiliano; Stair, Peter C.; Marks, Tobin J.

doi:10.1021/acscatal.6b01717

Title: Reactivity of a Carbon-Supported Single-Site Molybdenum Dioxo Catalyst for Biodiesel Synthesis

Journal Article · Tue Aug 23 00:00:00 EDT 2016 · ACS Catalysis

DOI:https://doi.org/10.1021/acscatal.6b01717· OSTI ID:1326936

Mouat, Aidan R.; Lohr, Tracy L.; Wegener, Evan C.; Miller, Jeffrey T.; Delferro, Massimiliano; Stair, Peter C.; Marks, Tobin J.

A single-site molybdenum dioxo catalyst, (O_c)₂Mo(=O)₂@C, was prepared via direct grafting of MoO₂Cl₂(dme) (dme = 1,2-dimethoxyethane) on high-surface- area activated carbon. The physicochemical and chemical properties of this catalyst were fully characterized by N₂ physisorption, ICP-AES/OES, PXRD, STEM, XPS, XAS, temperature-programmed reduction with H₂ (TPR-H₂), and temperature-programmed NH₃ desorption (TPD-NH₃). The single-site nature of the Mo species is corroborated by XPS and TPR-H₂ data, and it exhibits the lowest reported MoO_x Tmax of reduction reported to date, suggesting a highly reactive MoVI center. (O_c)₂Mo(=O)₂@C catalyzes the transesterification of a variety of esters and triglycerides with ethanol, exhibiting high activity at moderate temperatures (60-90 °C) and with negligible deactivation. (O_c)₂Mo(=O)₂@C is resistant to water and can be recycled at least three times with no loss of activity. The transesterification reaction is determined experimentally to be first order in [ethanol] and first order in [Mo] with ΔH = 10.5(8) kcal mol^-1 and ΔS = -32(2) eu. The low energy of activation is consistent with the moderate conditions needed to achieve rapid turnover. This highly active carbon-supported single-site molybdenum dioxo species is thus an efficient, robust, and lowcost catalyst with significant potential for transesterification processes.

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1326936

Journal Information:: ACS Catalysis, Vol. 6; ISSN 2155-5435

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

References (102)

Principles of biorefineries Kamm, B.; Kamm, M. Applied Microbiology and Biotechnology, Vol. 64, Issue 2 https://doi.org/10.1007/s00253-003-1537-7	journal	April 2004
Chemocatalytic Conversion of Ethanol into Butadiene and Other Bulk Chemicals Angelici, Carlo; Weckhuysen, Bert M.; Bruijnincx, Pieter C. A. ChemSusChem, Vol. 6, Issue 9 https://doi.org/10.1002/cssc.201300214	journal	May 2013
Comparison of Fatty Acid Methyl and Ethyl Esters as Biodiesel Base Stock: a Review on Processing and Production Requirements Yusoff, Mohamad Firdaus Mohamad; Xu, Xuebing; Guo, Zheng Journal of the American Oil Chemists' Society, Vol. 91, Issue 4 https://doi.org/10.1007/s11746-014-2443-0	journal	March 2014
New technology for the production of biodiesel fuel Maeda, Yasuaki; Thanh, Le Tu; Imamura, Kiyoshi Green Chemistry, Vol. 13, Issue 5 https://doi.org/10.1039/c1gc15049a	journal	January 2011
Improving the economics of biodiesel production through the use of low value lipids as feedstocks: vegetable oil soapstock Haas, Michael J. Fuel Processing Technology, Vol. 86, Issue 10 https://doi.org/10.1016/j.fuproc.2004.11.004	journal	June 2005
Transesterification to Biodiesel with Superhydrophobic Porous Solid Base Catalysts Liu, Fujian; Li, Wei; Sun, Qi ChemSusChem, Vol. 4, Issue 8 https://doi.org/10.1002/cssc.201100166	journal	May 2011
Nanoporous catalysts for biomass conversion Wang, Liang; Xiao, Feng-Shou Green Chemistry, Vol. 17, Issue 1 https://doi.org/10.1039/C4GC01622J	journal	January 2015
CeO2 as a versatile and reusable catalyst for transesterification of esters with alcohols under solvent-free conditions Tamura, Masazumi; Hakim Siddiki, S. M. A.; Shimizu, Ken-ichi Green Chemistry, Vol. 15, Issue 6 https://doi.org/10.1039/c3gc40408k	journal	January 2013
Thermal and catalytic pyrolysis of Karanja seed to produce liquid fuel Shadangi, Krushna Prasad; Mohanty, Kaustubha Fuel, Vol. 115 https://doi.org/10.1016/j.fuel.2013.07.053	journal	January 2014
A two-step continuous ultrasound assisted production of biodiesel fuel from waste cooking oils: A practical and economical approach to produce high quality biodiesel fuel Thanh, Le Tu; Okitsu, Kenji; Sadanaga, Yasuhiro Bioresource Technology, Vol. 101, Issue 14 https://doi.org/10.1016/j.biortech.2010.02.060	journal	July 2010
Tin-Catalyzed Esterification and Transesterification Reactions: A Review Ferreira, Arthur Batista; Lemos Cardoso, Abiney; da Silva, Márcio José ISRN Renewable Energy, Vol. 2012 https://doi.org/10.5402/2012/142857	journal	November 2012
Molybdenum Trioxide Catalyst for Transesterification of Dimethyl Carbonate and Phenyl Acetate to Diphenyl Carbonate Cao, Ping; Yang, Xiangui; Tang, Congming Chinese Journal of Catalysis, Vol. 30, Issue 9 https://doi.org/10.1016/S1872-2067(08)60127-8	journal	September 2009
Reactivity and surface properties of silica supported molybdenum oxide catalysts for the transesterification of dimethyl oxalate with phenol Ma, Xinbin; Gong, Jinlong; Wang, Shengping Catalysis Communications, Vol. 5, Issue 3 https://doi.org/10.1016/j.catcom.2003.12.001	journal	March 2004
Surface Organometallic and Coordination Chemistry toward Single-Site Heterogeneous Catalysts: Strategies, Methods, Structures, and Activities Copéret, Christophe; Comas-Vives, Aleix; Conley, Matthew P. Chemical Reviews, Vol. 116, Issue 2 https://doi.org/10.1021/acs.chemrev.5b00373	journal	January 2016
Supported Single-Site Organometallic Catalysts for the Synthesis of High-Performance Polyolefins Stalzer, Madelyn M.; Delferro, Massimiliano; Marks, Tobin J. Catalysis Letters, Vol. 145, Issue 1, p. 3-14 https://doi.org/10.1007/s10562-014-1427-x	journal	November 2014
Single-Site Organozirconium Catalyst Embedded in a Metal–Organic Framework Klet, Rachel C.; Tussupbayev, Samat; Borycz, Joshua Journal of the American Chemical Society, Vol. 137, Issue 50 https://doi.org/10.1021/jacs.5b11350	journal	December 2015
Benzene Selectivity in Competitive Arene Hydrogenation: Effects of Single-Site Catalyst···Acidic Oxide Surface Binding Geometry Gu, Weixing; Stalzer, Madelyn Marie; Nicholas, Christopher P. Journal of the American Chemical Society, Vol. 137, Issue 21, p. 6770-6780 https://doi.org/10.1021/jacs.5b03254	journal	April 2015
State of the Art and Perspectives in the “Molecular Approach” Towards Well-Defined Heterogeneous Catalysts Conley, Matthew P.; Copéret, Christophe Topics in Catalysis, Vol. 57, Issue 10-13 https://doi.org/10.1007/s11244-014-0245-0	journal	March 2014
A Well-Defined Silica-Supported Tungsten Oxo Alkylidene Is a Highly Active Alkene Metathesis Catalyst Conley, Matthew P.; Mougel, Victor; Peryshkov, Dmitry V. Journal of the American Chemical Society, Vol. 135, Issue 51 https://doi.org/10.1021/ja410052u	journal	December 2013
Surface structural-chemical characterization of a single-site d0 heterogeneous arene hydrogenation catalyst having 100% active sites Williams, L. A.; Guo, N.; Motta, A. Proceedings of the National Academy of Sciences, Vol. 110, Issue 2 https://doi.org/10.1073/pnas.1220240110	journal	December 2012
Metathesis of Alkanes and Related Reactions Basset, Jean-Marie; Coperet, Christophe; Soulivong, Daravong Accounts of Chemical Research, Vol. 43, Issue 2, p. 323-334 https://doi.org/10.1021/ar900203a	journal	February 2010
Homogeneous and Heterogeneous Catalysis: Bridging the Gap through Surface Organometallic Chemistry Copéret, Christophe; Chabanas, Mathieu; Petroff Saint-Arroman, Romain Angewandte Chemie International Edition, Vol. 42, Issue 2, p. 156-181 https://doi.org/10.1002/anie.200390072	journal	January 2003
Silica-Supported, Single-Site Titanium Catalysts for Olefin Epoxidation. A Molecular Precursor Strategy for Control of Catalyst Structure Jarupatrakorn, Jonggol; Tilley, T. Don Journal of the American Chemical Society, Vol. 124, Issue 28 https://doi.org/10.1021/ja0202208	journal	July 2002
Synthesis, Characterization, and Catalytic Performance of Single-Site Iron(III) Centers on the Surface of SBA-15 Silica Nozaki, Chika; Lugmair, Claus G.; Bell, Alexis T. Journal of the American Chemical Society, Vol. 124, Issue 44 https://doi.org/10.1021/ja020388t	journal	November 2002
Common Pathways in Ethanolysis of Kraft Lignin to Platform Chemicals over Molybdenum-Based Catalysts Ma, Xiaolei; Ma, Rui; Hao, Wenyue ACS Catalysis, Vol. 5, Issue 8 https://doi.org/10.1021/acscatal.5b01159	journal	July 2015
Surface properties and catalytic activity of a Mo-fixed catalyst. Structure of the active site and mechanism for selective oxidation of ethyl alcohol Iwasawa, Yasuhiro; Nakano, Yasuo; Ogasawara, Sadao Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 74, Issue 0 https://doi.org/10.1039/f19787402968	journal	January 1978
Structures of molybdenum silica catalysts reduced by ethanol, and their relations to catalytic oxidation reactions Kikutani, Y. Journal of Molecular Catalysis A: Chemical, Vol. 142, Issue 2 https://doi.org/10.1016/S1381-1169(98)00309-4	journal	June 1999
Structures of molybdenum silica catalysts reduced by ethanol, and their relations to catalytic oxidation reactions Kikutani, Y. Journal of Molecular Catalysis A: Chemical, Vol. 142, Issue 2 https://doi.org/10.1016/S1381-1169(98)00310-0	journal	June 1999
Catalytic air oxidation of olefins using molybdenum dioxo complexes with dissymmetric tridentate O,N,S-donor Schiff base ligands derived from o-hydroxyacetophenone and S-benzyldithiocarbazate or S-methyldithiocarbazate Rao, Sumita N.; Kathale, N.; Rao, N. N. Inorganica Chimica Acta, Vol. 360, Issue 14 https://doi.org/10.1016/j.ica.2007.05.035	journal	November 2007
Molybdenum( vi ) cis-dioxo complexes bearing sugar derived chiral Schiff-base ligands: synthesis, characterization, and catalytic applications Zhao, Jin; Zhou, Xiangge; Santos, Ana M. Dalton Trans., Issue 19 https://doi.org/10.1039/B306039J	journal	January 2003
A novel tridentate Schiff base dioxo-molybdenum(VI) complex: Synthesis, crystal structure and catalytic performance in green oxidation of sulfides by urea hydrogen peroxide Sheikhshoaie, Iran; Rezaeifard, Abdolreza; Monadi, Niaz Polyhedron, Vol. 28, Issue 4 https://doi.org/10.1016/j.poly.2008.12.044	journal	March 2009
Dioxomolybdenum(VI) and dioxotungsten(VI) complexes: efficient catalytic activity for crosslinking reaction in ethylene-vinyl acetate copolymer/alkoxysilane composites: DIOXOMOLYBDENUM(VI) AND DIOXOTUNGSTEN(VI) COMPLEXES Adachi, Kenta; Toyomura, Shoko; Miyakuni, Yuko Polymers for Advanced Technologies, Vol. 26, Issue 6 https://doi.org/10.1002/pat.3491	journal	March 2015
Transesterification of Diethyl Oxalate with Phenol over Sol-Gel MoO3/TiO2 Catalysts Kotbagi, Trupti; Nguyen, Duy Luan; Lancelot, Christine ChemSusChem, Vol. 5, Issue 8 https://doi.org/10.1002/cssc.201100802	journal	July 2012
Solid Mixed-Metal-Oxide Catalysts for Biodiesel Production: A Review Chang, Fei; Zhou, Quan; Pan, Hu Energy Technology, Vol. 2, Issue 11 https://doi.org/10.1002/ente.201402089	journal	October 2014
MoO2(acac)2 immobilized on polymers as catalysts for cyclohexene epoxidation: Effect of the degree of crosslinking Reyes, Patricio; Borda, Gloria; Gnecco, Juan Journal of Applied Polymer Science, Vol. 93, Issue 4 https://doi.org/10.1002/app.20594	journal	January 2004
Heterogenization of chiral molybdenum(VI) dioxo complexes on mesoporous materials and their application in catalysis Sakthivel, Ayyamperumal; Zhao, Jin; Raudaschl-Sieber, Gabriele Applied Catalysis A: General, Vol. 281, Issue 1-2 https://doi.org/10.1016/j.apcata.2004.11.035	journal	March 2005
Porous carbon-supported catalysts for energy and environmental applications: A short review Yang, Yunxia; Chiang, Ken; Burke, Nick Catalysis Today, Vol. 178, Issue 1 https://doi.org/10.1016/j.cattod.2011.08.028	journal	December 2011
Stability of functionalized activated carbon in hot liquid water Van Pelt, Adam H.; Simakova, Olga A.; Schimming, Sarah M. Carbon, Vol. 77 https://doi.org/10.1016/j.carbon.2014.05.015	journal	October 2014
Amorphous Carbon with SO ₃ H Groups as a Solid Brønsted Acid Catalyst Nakajima, Kiyotaka; Hara, Michikazu ACS Catalysis, Vol. 2, Issue 7 https://doi.org/10.1021/cs300103k	journal	May 2012
Glucan Adsorption on Mesoporous Carbon Nanoparticles: Effect of Chain Length and Internal Surface Chung, Po-Wen; Charmot, Alexandre; Gazit, Oz M. Langmuir, Vol. 28, Issue 43 https://doi.org/10.1021/la3030364	journal	October 2012
Synthesis of MO2Cl2(N,N,N',N'-tetramethylethylenediamine) (M = Mo and W) and crystal structure of WO2Cl2(N,N,N',N'-tetramethylethylenediamine) —an unprecedented coordination geometry in the WO2Cl2 Core Dreisch, Klaus; Andersson, Carlaxel; Sta»handske, Claes Polyhedron, Vol. 11, Issue 17 https://doi.org/10.1016/S0277-5387(00)83688-8	journal	January 1992
Synthesis and Catalytic Epoxidation Activity with TBHP and H ₂ O ₂ of Dioxo-, Oxoperoxo-, and Oxodiperoxo Molybdenum(VI) and Tungsten(VI) Compounds Containing Monodentate or Bidentate Phosphine Oxide Ligands: Crystal Structures of WCl ₂ (O) ₂ (OPMePh ₂ ) ₂ , WCl ₂ (O)(O ₂ )(OPMePh ₂ ) ₂ , MoCl ₂ (O) ₂ dppmO ₂ ·C ₄ H ₁₀ O, WCl ₂ (O) ₂ dppmO ₂ , Mo(O)(O ₂ ) ₂ dppmO ₂ , and W(O)(O ₂ ) ₂ dppmO ₂ Jimtaisong, Ampa; Luck, Rudy L. Inorganic Chemistry, Vol. 45, Issue 25 https://doi.org/10.1021/ic061455d	journal	November 2006
New dioxo–molybdenum(vi) and –tungsten(vi) complexes with N-capped tripodal N2O2 tetradentate ligands: Synthesis, structures and catalytic activities towards olefin epoxidation Wong, Yee-Lok; Tong, Lok H.; Dilworth, Jonathan R. Dalton Transactions, Vol. 39, Issue 19 https://doi.org/10.1039/b926864b	journal	January 2010
Sol–gel synthesis, characterization and catalytic property of silicas modified with oxomolybdenum complexes Wang, Ge; Feng, Linsheng; Luck, Rudy L. Journal of Molecular Catalysis A: Chemical, Vol. 241, Issue 1-2 https://doi.org/10.1016/j.molcata.2005.06.050	journal	November 2005
An operando Raman study of structure and reactivity of alumina-supported molybdenum oxide catalysts for the oxidative dehydrogenation of ethane Christodoulakis, A.; Heracleous, E.; Lemonidou, A. Journal of Catalysis, Vol. 242, Issue 1 https://doi.org/10.1016/j.jcat.2006.05.024	journal	August 2006
Structure and Density of Mo and Acid Sites in Mo-Exchanged H-ZSM5 Catalysts for Nonoxidative Methane Conversion Borry, Richard W.; Kim, Young Ho; Huffsmith, Anne The Journal of Physical Chemistry B, Vol. 103, Issue 28 https://doi.org/10.1021/jp990866v	journal	July 1999
Raman Spectroscopy of Monolayer-Type Catalysts: Supported Molybdenum Oxides Mestl, Gerhard; Srinivasan, T. K. K. Catalysis Reviews, Vol. 40, Issue 4 https://doi.org/10.1080/01614949808007114	journal	November 1998
The Effect of Acid-Base Properties of Supported Molybdenum Oxide in Propylene Oxidation Desikan, A. N.; Zhang, W. M.; Oyama, S. T. Journal of Catalysis, Vol. 157, Issue 2 https://doi.org/10.1006/jcat.1995.1340	journal	December 1995
Application of dynamic photoluminescence spectroscopy to the study of the active surface sites on supported molybdenum/silica catalysts: features of anchored and impregnated catalysts Anpo, Masakazu; Kondo, Masao; Louis, Catherine Journal of the American Chemical Society, Vol. 111, Issue 24 https://doi.org/10.1021/ja00206a004	journal	November 1989
Characterization of Mo/Al2O3 catalysts by low-temperature oxygen chemisorption Nag, N. Journal of Catalysis, Vol. 92, Issue 2 https://doi.org/10.1016/0021-9517(85)90279-9	journal	April 1985
Evaluation of Modified Boehm Titration Methods for Use with Biochars Fidel, Rivka B.; Laird, David A.; Thompson, Michael L. Journal of Environmental Quality, Vol. 42, Issue 6 https://doi.org/10.2134/jeq2013.07.0285	journal	November 2013
Activity of Molybdenum Oxide Catalyst Supported on Al2O3, TiO2, and SiO2 Matrix in the Oxidative Dehydrogenation of n-Butane Setnička, Michal; Tišler, Zdeněk; Kubička, David Topics in Catalysis, Vol. 58, Issue 14-17 https://doi.org/10.1007/s11244-015-0453-2	journal	August 2015
Hydroisomerization-cracking of n-octane on heteropolyacid H3PW12O40 supported on ZrO2, SiO2 and carbon Yori, Juan C.; Grau, Javier M.; Benítez, Viviana M. Applied Catalysis A: General, Vol. 286, Issue 1 https://doi.org/10.1016/j.apcata.2005.03.003	journal	May 2005
Characterization and reactivity of molybdenum oxide catalysts supported on zirconia Bhaskar, Thallada; Reddy, Kondakindi Rajender; Kumar, Chinthala Praveen Applied Catalysis A: General, Vol. 211, Issue 2 https://doi.org/10.1016/S0926-860X(00)00874-7	journal	April 2001
An XPS study of amorphous MoO3/SiO films deposited by co-evaporation Anwar, M.; Hogarth, C. A.; Bulpett, R. Journal of Materials Science, Vol. 25, Issue 3 https://doi.org/10.1007/BF01045385	journal	March 1990
Generation of XPS Auger lines by bremsstrahlung Wagner, C. D.; Taylor, J. Ashley Journal of Electron Spectroscopy and Related Phenomena, Vol. 20, Issue 1 https://doi.org/10.1016/0368-2048(80)85008-0	journal	January 1980
Assessment of the surface chemistry of carbon blacks by TGA-MS, XPS and inverse gas chromatography using statistical chemometric analysis Strzemiecka, Beata; Voelkel, Adam; Donate-Robles, Jessica Applied Surface Science, Vol. 316 https://doi.org/10.1016/j.apsusc.2014.07.174	journal	October 2014
Combined XPS and TPD study of oxygen-functionalized carbon nanofibers grown on sintered metal fibers Rosenthal, Dirk; Ruta, Marina; Schlögl, Robert Carbon, Vol. 48, Issue 6 https://doi.org/10.1016/j.carbon.2010.01.029	journal	May 2010
Polymerization of Ethylene by Silica-Supported Dinuclear Cr ^III Sites through an Initiation Step Involving CH Bond Activation Conley, Matthew P.; Delley, Murielle F.; Siddiqi, Georges Angewandte Chemie International Edition, Vol. 53, Issue 7 https://doi.org/10.1002/anie.201308983	journal	January 2014
Quantifying accessible sites and reactivity on titania–silica (photo)catalysts: Refining TOF calculations Eaton, Todd R.; Campos, Michael P.; Gray, Kimberly A. Journal of Catalysis, Vol. 309 https://doi.org/10.1016/j.jcat.2013.09.015	journal	January 2014
Counting Active Sites on Titanium Oxide-Silica Catalysts for Hydrogen Peroxide Activation through In Situ Poisoning with Phenylphosphonic Acid Eaton, Todd R.; Boston, Andrew M.; Thompson, Anthony B. ChemCatChem, Vol. 6, Issue 11 https://doi.org/10.1002/cctc.201402611	journal	October 2014
Supported organoactinides. Surface chemistry and catalytic properties of alumina-bound cyclopentadienyl and pentamethylcyclopentadienyl thorium and uranium hydrocarbyls and hydrides He, Ming Yuan; Xiong, Guoxing; Toscano, Paul J. Journal of the American Chemical Society, Vol. 107, Issue 3 https://doi.org/10.1021/ja00289a016	journal	February 1985
Surface Organozirconium Electrophiles Activated by Chemisorption on “Super Acidic” Sulfated Zirconia as Hydrogenation and Polymerization Catalysts. A Synthetic, Structural, and Mechanistic Catalytic Study Ahn, Hongsang; Nicholas, Christopher P.; Marks, Tobin J. Organometallics, Vol. 21, Issue 9 https://doi.org/10.1021/om020056x	journal	April 2002
Single-Face/All- cis Arene Hydrogenation by a Supported Single-Site d ⁰ Organozirconium Catalyst Stalzer, Madelyn Marie; Nicholas, Christopher P.; Bhattacharyya, Alak Angewandte Chemie International Edition, Vol. 55, Issue 17 https://doi.org/10.1002/anie.201600345	journal	March 2016
Design Strategies for the Molecular Level Synthesis of Supported Catalysts Wegener, Staci L.; Marks, Tobin J.; Stair, Peter C. Accounts of Chemical Research, Vol. 45, Issue 2 https://doi.org/10.1021/ar2001342	journal	August 2011
Zirconium Hydrocarbyl Chemisorption on Sulfated Metal Oxides: New Supports, Chemisorption Pathways, and Implications for Catalysis Nicholas, Christopher P.; Marks, Tobin J. Langmuir, Vol. 20, Issue 22 https://doi.org/10.1021/la0492106	journal	October 2004
Sulfated Tin Oxide Nanoparticles as Supports for Molecule-Based Olefin Polymerization Catalysts Nicholas, Christopher P.; Marks, Tobin J. Nano Letters, Vol. 4, Issue 8 https://doi.org/10.1021/nl049255r	journal	August 2004
Synthesis, Spectroscopy, and Catalytic Properties of Cationic Organozirconium Adsorbates on “Super Acidic” Sulfated Alumina. “Single-Site” Heterogeneous Catalysts with Virtually 100 Active Sites Nicholas, Christopher P.; Ahn, Hongsang; Marks, Tobin J. Journal of the American Chemical Society, Vol. 125, Issue 14 https://doi.org/10.1021/ja0212213	journal	April 2003
Supported Organometallics. Highly Electrophilic Cationic Metallocene Hydrogenation and Polymerization Catalysts Formed via Protonolytic Chemisorption on Sulfated Zirconia Ahn, Hongsang; Marks, Tobin J. Journal of the American Chemical Society, Vol. 120, Issue 51 https://doi.org/10.1021/ja9825682	journal	December 1998
Kinetics of palm oil transesterification in a batch reactor Darnoko, D.; Cheryan, Munir Journal of the American Oil Chemists' Society, Vol. 77, Issue 12 https://doi.org/10.1007/s11746-000-0198-y	journal	December 2000
Catalytic Ethanolysis of Kraft Lignin into High‐Value Small‐Molecular Chemicals over a Nanostructured α‐Molybdenum Carbide Catalyst Ma, Rui; Hao, Wenyue; Ma, Xiaolei Angewandte Chemie, Vol. 126, Issue 28 https://doi.org/10.1002/ange.201402752	journal	June 2014
Effect of oxomolybdate species dispersion on direct methanol oxidation to dimethoxymethane over MoO _x /TiO ₂ catalysts Faye, Jérémy; Capron, Mickaël; Takahashi, Atsushi Energy Science & Engineering, Vol. 3, Issue 2 https://doi.org/10.1002/ese3.53	journal	December 2014
The Enhancing Effect of Brønsted Acidity of Supported MoO _x Species on their Activity and Selectivity in Ethylene/ trans -2-Butene Metathesis Hahn, Tobias; Bentrup, Ursula; Armbrüster, Marc ChemCatChem, Vol. 6, Issue 6 https://doi.org/10.1002/cctc.201400040	journal	April 2014
Zirconia-Supported MoO _x Catalysts for the Selective Oxidation of Dimethyl Ether to Formaldehyde: Structure, Redox Properties, and Reaction Pathways Liu, Haichao; Cheung, Patricia; Iglesia, Enrique The Journal of Physical Chemistry B, Vol. 107, Issue 17 https://doi.org/10.1021/jp0221744	journal	April 2003
Molybdenum oxide supported on nanostructured MgO: Influence of the alkaline support properties on MoOx structure and catalytic behavior in selective oxidation Scholz, J.; Walter, A.; Hahn, A. H. P. Microporous and Mesoporous Materials, Vol. 180 https://doi.org/10.1016/j.micromeso.2013.05.032	journal	November 2013
Selective Autooxidation of Ethanol over Titania-Supported Molybdenum Oxide Catalysts: Structure and Reactivity Caro, Carlos; Thirunavukkarasu, K.; Anilkumar, M. Advanced Synthesis & Catalysis, Vol. 354, Issue 7 https://doi.org/10.1002/adsc.201000841	journal	April 2012
Properties of molybdate species supported on silica Liu, Tuan-Chi; Forissier, Michel; Coudurier, Gisèle Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 85, Issue 7 https://doi.org/10.1039/f19898501607	journal	January 1989
Structure and dispersion of molybdenum oxide supported on alumina and titania Desikan, Anantha N.; Huang, Lily; Oyama, S. Ted Journal of the Chemical Society, Faraday Transactions, Vol. 88, Issue 22 https://doi.org/10.1039/ft9928803357	journal	January 1992
High-resolution molybdenum K-edge X-ray absorption spectroscopy analyzed with time-dependent density functional theory Lima, Frederico A.; Bjornsson, Ragnar; Weyhermüller, Thomas Physical Chemistry Chemical Physics, Vol. 15, Issue 48 https://doi.org/10.1039/c3cp53133c	journal	January 2013
Core-electron binding energies in free and supported metal clusters Wertheim, G. K. Zeitschrift f�r Physik B Condensed Matter, Vol. 66, Issue 1 https://doi.org/10.1007/BF01312762	journal	March 1987
Controlled Synthesis and Characterization of Highly Dispersed Molybdenum Oxide Supported on Silica SBA-15 Thielemann, Jörg P.; Weinberg, Gisela; Hess, Christian ChemCatChem, Vol. 3, Issue 11 https://doi.org/10.1002/cctc.201100154	journal	August 2011
An XPS study of the dispersion of MoO3 on TiO2–ZrO2, TiO2–SiO2, TiO2–Al2O3, SiO2–ZrO2, and SiO2–TiO2–ZrO2 mixed oxides Reddy, Benjaram M.; Chowdhury, Biswajit; Smirniotis, Panagiotis G. Applied Catalysis A: General, Vol. 211, Issue 1 https://doi.org/10.1016/S0926-860X(00)00834-6	journal	March 2001
XANES Mo L -Edges and XPS Study of Mo Loaded in HY Zeolite Lede, E. J.; Requejo, F. G.; Pawelec, B. The Journal of Physical Chemistry B, Vol. 106, Issue 32 https://doi.org/10.1021/jp014648p	journal	July 2002
Electrochromism in some thin‐film transition‐metal oxides characterized by x‐ray electron spectroscopy Colton, Richard J.; Guzman, Alberto M.; Rabalais, J. Wayne Journal of Applied Physics, Vol. 49, Issue 1 https://doi.org/10.1063/1.324349	journal	January 1978
X-ray photoelectron spectroscopy of inorganic and organometallic compounds of molybdenum Grim, Samuel O.; Matienzo, Luis J. Inorganic Chemistry, Vol. 14, Issue 5 https://doi.org/10.1021/ic50147a013	journal	May 1975
SBA-15-supported molybdenum oxides as efficient catalysts for selective oxidation of ethane to formaldehyde and acetaldehyde by oxygen Lou, Y.; Wang, H.; Zhang, Q. Journal of Catalysis, Vol. 247, Issue 2 https://doi.org/10.1016/j.jcat.2007.02.011	journal	April 2007
Silica-Alumina-Supported Acidic Molybdenum Catalysts - TPR and XRD Characterization Rajagopal, S.; Marini, H. J.; Marzari, J. A. Journal of Catalysis, Vol. 147, Issue 2 https://doi.org/10.1006/jcat.1994.1159	journal	June 1994
Importance of Internal Porosity for Glucan Adsorption in Mesoporous Carbon Materials Chung, Po-Wen; Charmot, Alexandre; Click, Timothy Langmuir, Vol. 31, Issue 26 https://doi.org/10.1021/acs.langmuir.5b01115	journal	February 2015
Synergistic Effect between Defect Sites and Functional Groups on the Hydrolysis of Cellulose over Activated Carbon Foo, Guo Shiou; Sievers, Carsten ChemSusChem, Vol. 8, Issue 3 https://doi.org/10.1002/cssc.201402928	journal	December 2014
Thermodynamically Leveraged Tandem Catalysis for Ester RC(O)O–R′ Bond Hydrogenolysis. Scope and Mechanism Lohr, Tracy L.; Li, Zhi; Assary, Rajeev S. ACS Catalysis, Vol. 5, Issue 6 https://doi.org/10.1021/acscatal.5b00950	journal	May 2015
Selective Ether/Ester C–O Cleavage of an Acetylated Lignin Model via Tandem Catalysis Lohr, Tracy L.; Li, Zhi; Marks, Tobin J. ACS Catalysis, Vol. 5, Issue 11 https://doi.org/10.1021/acscatal.5b01972	journal	October 2015
An experimental and theoretical study of the adsorption of aromatics possessing electron-withdrawing and electron-donating functional groups by chemically modified activated carbons Radovic, L. R.; Silva, I. F.; Ume, J. I. Carbon, Vol. 35, Issue 9 https://doi.org/10.1016/S0008-6223(97)00072-9	journal	January 1997
Effects of surface properties of activated carbons on adsorption behavior of selected aromatics Leng, C. -C.; Pinto, N. G. Carbon, Vol. 35, Issue 9 https://doi.org/10.1016/S0008-6223(97)00091-2	journal	January 1997
Selective adsorption of organic homologues onto activated carbon from dilute aqueous solutions. Solvophobic interaction approach and correlations of molar adsorptivity with physicochemical parameters Belfort, Georges Environmental Science & Technology, Vol. 13, Issue 8 https://doi.org/10.1021/es60156a006	journal	August 1979
Reversible catalytic dehydrogenation of alcohols for energy storage Bonitatibus, Peter J.; Chakraborty, Sumit; Doherty, Mark D. Proceedings of the National Academy of Sciences, Vol. 112, Issue 6 https://doi.org/10.1073/pnas.1420199112	journal	January 2015
Dialkyl and diaryl carbonates by carbonate interchange reaction with dimethyl carbonate Shaikh, Abbas Alli G.; Sivaram, Swaminathan Industrial & Engineering Chemistry Research, Vol. 31, Issue 4 https://doi.org/10.1021/ie00004a028	journal	April 1992
Electronic Structure of the Hydroxo and Methoxo Oxometalate Anions MO ₃ (OH) ^- and MO ₃ (OCH ₃ ) ^- (M = Cr, Mo, and W) Waters, Tom; Wang, Xue-Bin; Li, Shenggang The Journal of Physical Chemistry A, Vol. 109, Issue 51 https://doi.org/10.1021/jp054666x	journal	December 2005
Catalysis of esterification reactions by oxo-molybdenum-alkoxides: X-ray structures of Cl2(O)Mo(μ-nPr)2(μ-HOnPr)Mo(O)Cl2 and Cl2(O)Mo(μ-OEt)2(μ2-η1η1-HOCH2CH2OH)Mo(O)Cl2 Hunger, Marc; Limberg, Christian; Zsolnai, László Polyhedron, Vol. 17, Issue 22 https://doi.org/10.1016/S0277-5387(98)00184-3	journal	November 1998
Mechanisms of Methane Activation and Transformation on Molybdenum Oxide Based Catalysts Fu, Gang; Xu, Xin; Lu, Xin Journal of the American Chemical Society, Vol. 127, Issue 11 https://doi.org/10.1021/ja0441099	journal	March 2005
Methanol Selective Oxidation to Formaldehyde over Iron‐Molybdate Catalysts Soares, Ana Paula Vieira; Portela, Manuel Farinha; Kiennemann, Alain Catalysis Reviews, Vol. 47, Issue 1 https://doi.org/10.1081/CR-200049088	journal	February 2005
Hydrogen Atom Abstraction by Metal−Oxo Complexes: Understanding the Analogy with Organic Radical Reactions Mayer, James M. Accounts of Chemical Research, Vol. 31, Issue 8 https://doi.org/10.1021/ar970171h	journal	August 1998
Preface Grasselli, Robert K.; Oyama, S. Ted; Gaffney, Anne M. Studies in Surface Science and Catalysis https://doi.org/10.1016/S0167-2991(97)80965-2	book	January 1997

Cited By (4)

Efficient Chemoselective Reduction of N ‐Oxides and Sulfoxides Using a Carbon‐Supported Molybdenum‐Dioxo Catalyst and Alcohol Li, Jiaqi; Liu, Shengsi; Lohr, Tracy L. ChemCatChem, Vol. 11, Issue 16 https://doi.org/10.1002/cctc.201900436	journal	May 2019
An eco-friendly synthesis of 4-aryl-substituted pyrano-fuzed coumarins as potential pharmacological active heterocycles using molybdenum oxide nanoparticles as an effective and recyclable catalyst Pourshojaei, Yaghoub; Jadidi, Mohammad-Hossein; Eskandari, Khalil Research on Chemical Intermediates, Vol. 44, Issue 7 https://doi.org/10.1007/s11164-018-3363-7	journal	March 2018
Second-generation hexavalent molybdenum oxo-amidinate precursors for atomic layer deposition Jurca, T.; Peters, A. W.; Mouat, A. R. Dalton Transactions, Vol. 46, Issue 4 https://doi.org/10.1039/c6dt03952a	journal	January 2017
Highly active two dimensional α-MoO _3−x for the electrocatalytic hydrogen evolution reaction Datta, R. S.; Haque, F.; Mohiuddin, M. Journal of Materials Chemistry A, Vol. 5, Issue 46 https://doi.org/10.1039/c7ta07705j	journal	January 2017

Similar Records

Reactivity of a Carbon-Supported Single-Site Molybdenum Dioxo Catalyst for Biodiesel Synthesis

Journal Article · Tue Aug 23 00:00:00 EDT 2016 · ACS Catalysis · OSTI ID:1326936

Mouat, Aidan R.; Lohr, Tracy L.; Wegener, Evan C.; +4 more

Synthesis and Structure–Activity Characterization of a Single-Site MoO₂ Catalytic Center Anchored on Reduced Graphene Oxide

Journal Article · Thu Dec 16 00:00:00 EST 2021 · Journal of the American Chemical Society · OSTI ID:1326936

Liu, Yiqi; Li, Jiaqi; Das, Anusheela; +7 more

Effect of the K-Mo interaction in K-MoO[sub 3]/[gamma]-Al[sub 2]O[sub 3] catalysts on the properties of alcohol synthesis from syngas

Journal Article · Tue Mar 01 00:00:00 EST 1994 · Journal of Catalysis; (United States) · OSTI ID:1326936

Jiang, Ming; Bian, Guo-Zhu; Fu, Yi-Lu

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
biodiesel
heterogeneous catalysis
molybdenum
supported catalysts
transesterification

Title: Reactivity of a Carbon-Supported Single-Site Molybdenum Dioxo Catalyst for Biodiesel Synthesis

Citation Formats

References (102)

Cited By (4)

Similar Records

Related Subjects