Inverse oxide/metal catalysts in fundamental studies and practical applications: A perspective of recent developments

Rodriguez, José A.; Liu, Ping; Graciani, Jesús; Senanayake, Sanjaya D.; Grinter, David C.; Stacchiola, Dario; Hrbek, Jan; Fernández-Sanz, Javier

doi:10.1021/acs.jpclett.6b00499

Title: Inverse oxide/metal catalysts in fundamental studies and practical applications: A perspective of recent developments

Journal Article · Tue Jun 21 00:00:00 EDT 2016 · Journal of Physical Chemistry Letters

DOI:https://doi.org/10.1021/acs.jpclett.6b00499· OSTI ID:1326742

Rodriguez, José A. ^[1]; Liu, Ping ^[1]; Graciani, Jesús ^[2]; Senanayake, Sanjaya D. ^[3]; Grinter, David C. ^[3]; Stacchiola, Dario ^[3]; Hrbek, Jan ^[3]; Fernández-Sanz, Javier ^[2]

Brookhaven National Lab. (BNL), Upton, NY (United States); State Univ. of New York (SUNY), Stony Brook, NY (United States)
Univ. de Sevilla, Sevilla (Spain)
Brookhaven National Lab. (BNL), Upton, NY (United States)

Inverse oxide/metal catalysts have shown to be excellent systems for studying the role of the oxide and oxide–metal interface in catalytic reactions. These systems can have special structural and catalytic properties due to strong oxide–metal interactions difficult to attain when depositing a metal on a regular oxide support. Oxide phases that are not seen or are metastable in a bulk oxide can become stable in an oxide/metal system opening the possibility for new chemical properties. Using these systems, it has been possible to explore fundamental properties of the metal–oxide interface (composition, structure, electronic state), which determine catalytic performance in the oxidation of CO, the water–gas shift and the hydrogenation of CO₂ to methanol. Recently, there has been a significant advance in the preparation of oxide/metal catalysts for technical or industrial applications. In conclusion, one goal is to identify methods able to control in a precise way the size of the deposited oxide particles and their structure on the metal substrate.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC00112704

OSTI ID:: 1326742

Report Number(s):: BNL-112633-2016-JA; R&D Project: CO027; KC0302010

Journal Information:: Journal of Physical Chemistry Letters, Vol. 7, Issue 13; ISSN 1948-7185

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 90 works

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