Growth Kinetics and Morphology of Barite Crystals Derived from Face-Specific Growth Rates

Godinho, Jose R.  A.; Stack, Andrew G.

doi:10.1021/cg501507p

Title: Growth Kinetics and Morphology of Barite Crystals Derived from Face-Specific Growth Rates

Journal Article · Mon Mar 30 00:00:00 EDT 2015 · Crystal Growth and Design

DOI:https://doi.org/10.1021/cg501507p· OSTI ID:1325464

Godinho, Jose R. A. ^[1]; Stack, Andrew G. ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division

Here we investigate the growth kinetics and morphology of barite (BaSO₄) crystals by measuring the growth rates of the (001), (210), (010), and (100) surfaces using vertical scanning interferometry. Solutions with saturation indices 1.1, 2.1, and 3.0 without additional electrolyte, in 0.7 M NaCl, or in 1.3 mM SrCl2 are investigated. Face-specific growth rates are inhibited in the SrCl₂ solution relative to a solution without electrolyte, except for (100). Contrarily, growth of all faces is promoted in the NaCl solution. The variation of face-specific rates is solution-specific, which leads to a. change of the crystal morphology and overall growth rate of crystals. The measured face-specific growth rates are used to model the growth of single crystals. Modeled crystals have a morphology and size similar to those grown from solution. Based on the model the time dependence of surface area and growth rates is analyzed. Growth rates change with time due to surface area normalization for small crystals and large growth intervals. By extrapolating rates to crystals with large surfaces areas, time-independent growth rates are 0.783, 2.96, and 0.513 mmol∙m^-2∙h^-1, for saturation index 2.1 solutions without additional electrolyte, NaCl, and SrCl₂, respectively.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1325464

Journal Information:: Crystal Growth and Design, Vol. 15, Issue 5; ISSN 1528-7483

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 42 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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Title: Growth Kinetics and Morphology of Barite Crystals Derived from Face-Specific Growth Rates

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