A Fully Ordered Triplite, LiCuSO4F

Sun, Meiling; Rousse, Gwenaëlle; Corte, Daniel Dalla; Saubanère, Matthieu; Doublet, Marie-Liesse; Tarascon, Jean-Marie

doi:10.1021/acs.chemmater.5b04478

Title: A Fully Ordered Triplite, LiCuSO₄F

Journal Article · Wed Feb 24 00:00:00 EST 2016 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.5b04478· OSTI ID:1324781

Sun, Meiling ^[1]; Rousse, Gwenaëlle ^[2]; Corte, Daniel Dalla ^[3]; Saubanère, Matthieu ^[4]; Doublet, Marie-Liesse ^[4]; Tarascon, Jean-Marie ^[2]

College de France, Paris Cedex (France); Sorbonne Univ. - UPMC Univ. Paris, Paris (France)
College de France, Paris Cedex (France); Sorbonne Univ. - UPMC Univ. Paris, Paris (France); Réseau sur le Stockage Electrochimique de l’Energie (RS2E), Amiens (France)
College de France, Paris Cedex (France)
Réseau sur le Stockage Electrochimique de l’Energie (RS2E), Amiens (France); ICGM Inst. Charles Gerhardt - CNRS and Univ. Montpellier (France)

Batteries are a major technological challenge in this new century, as they stand as a key way to make a more efficient use of energy. Rechargeable Li-ion batteries, by having the highest energy density of any such device, have emerged as the technology of choice for powering electric vehicles and show great promises for grid applications. For such promises to materialize fully, the quest for new positive electrode materials showing safety, sustainability and cost advantages must continue. Here, progresses have been recently achieved with the arrival of polyanionic compounds. Among them, LiFePO₄ is the most attractive, although its energy density is penalized by the low redox voltage (3.45 V vs Li⁺/Li⁰) of the Fe³⁺/Fe²⁺ redox couple.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

OSTI ID:: 1324781

Journal Information:: Chemistry of Materials, Vol. 28, Issue 6; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: ENGLISH

Citation Metrics:

Cited by: 7 works

Citation information provided by
Web of Science

References (14)

Tuning the Position of the Redox Couples in Materials with NASICON Structure by Anionic Substitution Padhi, A. K. Journal of The Electrochemical Society, Vol. 145, Issue 5 https://doi.org/10.1149/1.1838513	journal	January 1998
Synthesis and electrochemical properties of pure LiFeSO4F in the triplite structure Ati, M.; Melot, B. C.; Chotard, J. -N. Electrochemistry Communications, Vol. 13, Issue 11 https://doi.org/10.1016/j.elecom.2011.08.023	journal	November 2011
A 3.90 V iron-based fluorosulphate material for lithium-ion batteries crystallizing in the triplite structure Barpanda, P.; Ati, M.; Melot, B. C. Nature Materials, Vol. 10, Issue 10 https://doi.org/10.1038/nmat3093	journal	August 2011
A 3.9 V polyanion-type cathode material for Li-ion batteries Liu, Lei; Zhang, Bin; Huang, Xue-jie Progress in Natural Science: Materials International, Vol. 21, Issue 3 https://doi.org/10.1016/S1002-0071(12)60032-X	journal	June 2011
Lithium metal fluorosulfate polymorphs as positive electrodes for Li-ion batteries: synthetic strategies and effect of cation ordering Tripathi, Rajesh; Popov, Guerman; Ellis, Brian L. Energy & Environmental Science, Vol. 5, Issue 3 https://doi.org/10.1039/c2ee03222h	journal	January 2012
Evaluation of Tavorite-Structured Cathode Materials for Lithium-Ion Batteries Using High-Throughput Computing Mueller, Tim; Hautier, Geoffroy; Jain, Anubhav Chemistry of Materials, Vol. 23, Issue 17 https://doi.org/10.1021/cm200753g	journal	September 2011
Li ₂ Cu ₂ O(SO ₄ ) ₂ : a Possible Electrode for Sustainable Li-Based Batteries Showing a 4.7 V Redox Activity vs Li ⁺ /Li ⁰ Sun, Meiling; Rousse, Gwenaëlle; Abakumov, Artem M. Chemistry of Materials, Vol. 27, Issue 8 https://doi.org/10.1021/acs.chemmater.5b00588	journal	April 2015
Synthesis and crystal chemistry of the NaMSO4F family (M=Mg, Fe, Co, Cu, Zn) Reynaud, Marine; Barpanda, Prabeer; Rousse, Gwenaëlle Solid State Sciences, Vol. 14, Issue 1 https://doi.org/10.1016/j.solidstatesciences.2011.09.004	journal	January 2012
Indexing of powder diffraction patterns for low-symmetry lattices by the successive dichotomy method Boultif, A.; Louër, D. Journal of Applied Crystallography, Vol. 24, Issue 6 https://doi.org/10.1107/S0021889891006441	journal	December 1991
The crystal structure of copper fluorophosphate, Cu ₂ (PO ₄ )F Rea, J. R.; Kostiner, E. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 32, Issue 7 https://doi.org/10.1107/S0567740876006821	journal	July 1976
The crystal structure of triplite, (Mn,Fe) ₂ FPO ₄ Waldrop, Lyneve Zeitschrift für Kristallographie - Crystalline Materials, Vol. 130, Issue 1-6 https://doi.org/10.1524/zkri.1969.130.16.1	journal	December 1969
The crystal structure of manganese fluorophosphate, Mn ₂ (PO ₄ )F Rea, J. R.; Kostiner, E. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 28, Issue 8 https://doi.org/10.1107/S0567740872006417	journal	August 1972
Ab initio study of the migration of small polarons in olivine ${Li}_{x} {FePO}_{4}$ and their association with lithium ions and vacancies Maxisch, Thomas; Zhou, Fei; Ceder, Gerbrand Physical Review B, Vol. 73, Issue 10 https://doi.org/10.1103/PhysRevB.73.104301	journal	March 2006
Origin of the 3.6 V to 3.9 V voltage increase in the LiFeSO4F cathodes for Li-ion batteries Ben Yahia, Mouna; Lemoigno, Frédéric; Rousse, Gwenaëlle Energy & Environmental Science, Vol. 5, Issue 11 https://doi.org/10.1039/c2ee22699e	journal	January 2012

Cited By (1)

Li ₂ BaSc(BO ₃ ) ₂ F and LiBa ₂ Pb(BO ₃ ) ₂ F with Layered Structures featuring Special Li−O/F Configurations Chen, Yanna; Zhang, Min; Hu, Cong Chemistry - A European Journal, Vol. 24, Issue 58 https://doi.org/10.1002/chem.201804126	journal	October 2018

Similar Records

A 3.90 V iron-based fluorosulphate material for lithium-ion batteries crystallizing in the triplite structure

Journal Article · Thu Nov 17 00:00:00 EST 2011 · Nat. Mater. · OSTI ID:1324781

Barpanda, P; Ati, M; Melot, B C; +7 more

Mechanism of Exact Transition between Cationic and Anionic Redox Activities in Cathode Material Li₂FeSiO₄

Journal Article · Tue Oct 16 00:00:00 EDT 2018 · Journal of Physical Chemistry Letters · OSTI ID:1324781

Zheng, Jiaxin; Teng, Gaofeng; Yang, Jinlong; +6 more

A new high voltage alluaudite sodium battery insertion material

Journal Article · Wed Jan 04 00:00:00 EST 2023 · Materials Today Chemistry · OSTI ID:1324781

Barman, P.; Jha, P. K.; Chaupatnaik, A.; +6 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
chemical structure
granular materials
electrical energy
electrical conductivity
crystal structure

Title: A Fully Ordered Triplite, LiCuSO4F

Citation Formats

References (14)

Cited By (1)

Similar Records

Related Subjects

Title: A Fully Ordered Triplite, LiCuSO₄F