Adsorption of small hydrocarbons on rutile TiO2(110)

Chen, Long; Smith, R. Scott; Kay, Bruce D.; Dohnálek, Zdenek

doi:10.1016/j.susc.2015.11.002

Title: Adsorption of small hydrocarbons on rutile TiO2(110)

Journal Article · Mon Aug 01 00:00:00 EDT 2016 · Surface Science

DOI:https://doi.org/10.1016/j.susc.2015.11.002· OSTI ID:1322493

Chen, Long; Smith, R. Scott; Kay, Bruce D.; Dohnálek, Zdenek

Temperature programmed desorption and molecular beam scattering were used to study the adsorption and desorption of small hydrocarbons (n-alkanes, 1-alkenes and 1-alkynes with 1 - 4 carbon atoms of C1-C4) on rutile TiO2(110). We show that the sticking coefficients for all the hydrocarbons are close to unity (> 0.95) at an adsorption temperature of 60 K. The desorption energies for hydrocarbons of the same chain length increase from n-alkanes to 1-alkenes and to 1-alkynes. This trend is likely a consequence of an additional dative bonding of the alkene and alkyne π system to the coordinatively unsaturated Ti5c sites. Similar to previous studies on the adsorption of n-alkanes on metal and metal oxide surfaces, we find the desorption energies within each group (n-alkanes vs. 1-alkenes vs. 1-alkynes) from Ti5c sites increase linearly with the chain length. The absolute saturation coverages of each hydrocarbon on Ti5c sites were also determined. The saturation coverage of CH4, is found to be ~ 2/3 monolayer (ML). The saturation coverages of C2-C4 hydrocarbons are found nearly independent of the chain length with values of ~1/2 ML for n-alkanes and 1-alkenes and 2/3 ML for 1-alkynes. This result is surprising considering their similar sizes.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Environmental Molecular Sciences Laboratory (EMSL)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1322493

Report Number(s):: PNNL-SA-113158; 48368; KC0302010

Journal Information:: Surface Science, Vol. 650; ISSN 0039-6028

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

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