Materials Data on Zn3Si3(AgO6)2 by Materials Project

Dataset · Wed Apr 29 00:00:00 EDT 2020

DOI:https://doi.org/10.17188/1320646· OSTI ID:1320646

The Materials Project

Zn3Si3(AgO6)2 crystallizes in the cubic Ia-3d space group. The structure is three-dimensional. Ag3+ is bonded to six equivalent O2- atoms to form AgO6 octahedra that share corners with six equivalent SiO4 tetrahedra. All Ag–O bond lengths are 2.17 Å. Zn2+ is bonded in a body-centered cubic geometry to eight equivalent O2- atoms. There are four shorter (2.30 Å) and four longer (2.36 Å) Zn–O bond lengths. Si4+ is bonded to four equivalent O2- atoms to form SiO4 tetrahedra that share corners with four equivalent AgO6 octahedra. The corner-sharing octahedral tilt angles are 58°. All Si–O bond lengths are 1.66 Å. O2- is bonded in a 4-coordinate geometry to one Ag3+, two equivalent Zn2+, and one Si4+ atom.

• Research Organization: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
• Sponsoring Organization: USDOE Office of Science (SC), Basic Energy Sciences (BES)
• Contributing Organization: MIT; UC Berkeley; Duke; U Louvain
• DOE Contract Number: AC02-05CH11231; EDCBEE
• OSTI ID: 1320646
• Report Number(s): mvc-3646
• Resource Relation: Related Information: https://materialsproject.org/citing
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
crystal structure
Zn3Si3(AgO6)2
Ag-O-Si-Zn