Materials Data on WF5 by Materials Project

Dataset · Thu Jul 23 00:00:00 EDT 2020

DOI:https://doi.org/10.17188/1319586· OSTI ID:1319586

The Materials Project

WF5 crystallizes in the orthorhombic Immm space group. The structure is two-dimensional and consists of two WF5 sheets oriented in the (0, 0, 1) direction. W5+ is bonded to eight F1- atoms to form a mixture of edge and corner-sharing WF8 hexagonal bipyramids. There are a spread of W–F bond distances ranging from 1.91–2.21 Å. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted bent 120 degrees geometry to two equivalent W5+ atoms. In the second F1- site, F1- is bonded in a single-bond geometry to one W5+ atom. In the third F1- site, F1- is bonded in a distorted linear geometry to two equivalent W5+ atoms.

• Research Organization: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
• Sponsoring Organization: USDOE Office of Science (SC), Basic Energy Sciences (BES)
• Contributing Organization: MIT; UC Berkeley; Duke; U Louvain
• DOE Contract Number: AC02-05CH11231; EDCBEE
• OSTI ID: 1319586
• Report Number(s): mvc-15907
• Resource Relation: Related Information: https://materialsproject.org/citing
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
crystal structure
WF5
F-W