Materials Data on V2S5 by Materials Project

Dataset · Wed Jul 15 00:00:00 EDT 2020

DOI:https://doi.org/10.17188/1318315· OSTI ID:1318315

The Materials Project

V2S5 crystallizes in the orthorhombic Pmmn space group. The structure is two-dimensional and consists of one V2S5 sheet oriented in the (0, 1, 0) direction. V5+ is bonded to five S2- atoms to form a mixture of distorted edge and corner-sharing VS5 trigonal bipyramids. There are a spread of V–S bond distances ranging from 2.02–2.42 Å. There are three inequivalent S2- sites. In the first S2- site, S2- is bonded in a single-bond geometry to one V5+ atom. In the second S2- site, S2- is bonded in a distorted bent 150 degrees geometry to two equivalent V5+ atoms. In the third S2- site, S2- is bonded in a distorted trigonal non-coplanar geometry to three equivalent V5+ atoms.

• Research Organization: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
• Sponsoring Organization: USDOE Office of Science (SC), Basic Energy Sciences (BES)
• Contributing Organization: MIT; UC Berkeley; Duke; U Louvain
• DOE Contract Number: AC02-05CH11231; EDCBEE
• OSTI ID: 1318315
• Report Number(s): mvc-11754
• Resource Relation: Related Information: https://materialsproject.org/citing
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
crystal structure
V2S5
S-V