Supported Tetrahedral Oxo-Sn Catalyst: Single Site, Two Modes of Catalysis

Beletskiy, Evgeny V.; Hou, Xianliang; Shen, Zhongliang; Gallagher, James R.; Miller, Jeffrey T.; Wu, Yuyang; Li, Tiehu; Kung, Mayfair C.; Kung, Harold H.

doi:10.1021/jacs.5b13436

Title: Supported Tetrahedral Oxo-Sn Catalyst: Single Site, Two Modes of Catalysis

Journal Article · Thu Mar 17 00:00:00 EDT 2016 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.5b13436· OSTI ID:1307612

Beletskiy, Evgeny V.; Hou, Xianliang; Shen, Zhongliang; Gallagher, James R.; Miller, Jeffrey T.; Wu, Yuyang; Li, Tiehu; Kung, Mayfair C.; Kung, Harold H.

Mild calcination in ozone of a (POSS)-Sn- (POSS) complex grafted on silica generated a heterogenized catalyst that mostly retained the tetrahedral coordination of its homogeneous precursor, as evidenced by spectroscopic characterizations using EXAFS, NMR, UV-vis, and DRIFT. The Sn centers are accessible and uniform and can be quantified by stoichiometric pyridine poisoning. This Sn-catalyst is active in hydride transfer reactions as a typical solid Lewis acid. However, the Sn centers can also create Brønsted acidity with alcohol by binding the alcohol strongly as alkoxide and transferring the hydroxyl H to the neighboring Sn-O-Si bond. The resulting acidic silanol is active in epoxide ring opening and acetalization reactions.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Institute for Atom-efficient Chemical Transformations (IACT); Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1307612

Journal Information:: Journal of the American Chemical Society, Vol. 138, Issue 13; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

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Bi-functional heterogeneous catalysts for carbon dioxide conversion: enhanced performances at low temperature Comès, Adrien; Collard, Xavier; Fusaro, Luca RSC Advances, Vol. 8, Issue 45 https://doi.org/10.1039/c8ra03878c	journal	January 2018
Actinide Endohedral and Exohedral Cubic Siloxanes: An(IV)@(HSiO_1.5)₈ and An(IV)&(RSiO_1.5)₈ (An = U, Np, Pu; R = H, Cl, OH) Duan, Meigang; Li, Peng; Zhao, Huifeng European Journal of Inorganic Chemistry, Vol. 2019, Issue 43, p. 4660-4667 https://doi.org/10.1002/ejic.201900952	journal	November 2019
ZrO ₂ -SBA-15 catalysts for the one-pot cascade synthesis of GVL from furfural Iglesias, J.; Melero, J. A.; Morales, G. Catalysis Science & Technology, Vol. 8, Issue 17 https://doi.org/10.1039/c8cy01121d	journal	January 2018
Heterogeneous catalysts for the cyclization of dicarboxylic acids to cyclic anhydrides as monomers for bioplastic production Rashed, Md. N.; Siddiki, S. M. A. H.; Ali, Md. A. Green Chemistry, Vol. 19, Issue 14 https://doi.org/10.1039/c7gc00538e	journal	January 2017
Preparation of carboxyethyltin group-functionalized highly ordered mesoporous organosilica composite material with double acid sites He, Si-Qing; Wang, Jing; Wu, Dan-Dan Journal of Materials Science, Vol. 54, Issue 6 https://doi.org/10.1007/s10853-018-03207-8	journal	December 2018

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