Determination of the “NiOOH” charge and discharge mechanisms at ideal activity

Merrill, Matthew; Worsley, Marcus; Wittstock, Arne; Biener, Juergen; Stadermann, Michael

doi:10.1016/j.jelechem.2014.01.022

Title: Determination of the “NiOOH” charge and discharge mechanisms at ideal activity

Journal Article · Fri Jan 24 00:00:00 EST 2014 · Journal of Electroanalytical Chemistry

DOI:https://doi.org/10.1016/j.jelechem.2014.01.022· OSTI ID:1305895

Merrill, Matthew ^[1]; Worsley, Marcus ^[1]; Wittstock, Arne ^[1]; Biener, Juergen ^[1]; Stadermann, Michael ^[1]

Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States). Chemical Sciences Div.

Here, optimization of electrodeposition conditions produced Ni(OH)₂ deposits chargeable up to 1.84 ± 0.02 e^– per Ni on and the resulting nickel oxide/hydroxide active material could subsequently deliver 1.58 ± 0.02 e^– per Ni ion (462 mA h/g) over a potential range <0.2 V. The ability of the “NiOOH” active material to deliver an approximately ideal charge and discharge facilitated a coulometric and thermodynamic analysis through which the charge/discharge mechanisms were determined from known enthalpies of formation. The (dis)charge states were confirmed with in situ Raman spectroscopy. The mechanisms were additionally evaluated with respect to pH and potential dependence, charge quantities, hysteresis, and fluoride ion partial inhibition of the charge mechanism. The results indicate that the “NiOOH” (dis)charges as a solid-state system with mechanisms consistent with known nickel and oxygen redox reactions. A defect chemistry mechanism known for the LiNiO₂ system also occurs for “NiOOH” to cause both high activity and hysteresis. Similar to other cation insertion nickel oxides, the activity of the “NiOOH” mechanism is predominantly due to oxygen redox activity and does not involve the Ni4⁺ oxidation state. The “NiOOH” was produced from cathodic electrodeposition of Ni(OH)₂ from nickel nitrate solutions onto highly oriented pyrolytic graphite at ideal electrodeposition current efficiencies and the deposition mechanism was also characterized.

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Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC52-07NA27344

OSTI ID:: 1305895

Report Number(s):: LLNL-JRNL-539131

Journal Information:: Journal of Electroanalytical Chemistry, Vol. 717-718, Issue C; ISSN 1572-6657

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 54 works

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References (60)

Environmentally Friendly Nickel-Zinc Battery for High Rate Application with Higher Specific Energy Phillips, Jeff; Mohanta, Sam; Geng, Mingming ECS Transactions, Vol. 16, Issue 16 https://doi.org/10.1149/1.3087437	journal	August 2009
Electrochemical and Spectroscopic Evidence on the Participation of Quadrivalent Nickel in the Nickel Hydroxide Redox Reaction Corrigan, Dennis A.; Knight, Sandra L. Journal of The Electrochemical Society, Vol. 136, Issue 3, p. 613-619 https://doi.org/10.1149/1.2096697	journal	January 1989
Characterization of Redox States of Nickel Hydroxide Film Electrodes by In Situ Surface Raman Spectroscopy Desilvestro, Johann Journal of The Electrochemical Society, Vol. 135, Issue 4 https://doi.org/10.1149/1.2095818	journal	January 1988
In situ extended x‐ray absorption fine structure spectroscopy of thin‐film nickel hydroxide electrodes Capehart, T. W.; Corrigan, D. A.; Conell, R. S. Applied Physics Letters, Vol. 58, Issue 8 https://doi.org/10.1063/1.104489	journal	February 1991
Dynamic EXAFS study of discharging nickel hydroxide electrode with non-integer Ni valency Farley, N. R. S.; Gurman, S. J.; Hillman, A. R. Electrochimica Acta, Vol. 46, Issue 20-21 https://doi.org/10.1016/S0013-4686(01)00603-X	journal	July 2001
X-Ray Absorption Fine Structure Spectra and the Oxidation State of Nickel in Some of Its Oxycompounds Mansour, A. N. Journal of The Electrochemical Society, Vol. 141, Issue 6 https://doi.org/10.1149/1.2054990	journal	January 1994
In Situ X-Ray Absorption Near-Edge Structure Evidence for Quadrivalent Nickel in Nickel Battery Electrodes O'Grady, W. E. Journal of The Electrochemical Society, Vol. 143, Issue 5 https://doi.org/10.1149/1.1836687	journal	January 1996
In situ X-ray absorption fine structure and optical reflectance studies of electrodeposited nickel hydrous oxide films in alkaline electrolytes Hu, Yining; Bae, In Tae; Mo, Yibo Canadian Journal of Chemistry, Vol. 75, Issue 11 https://doi.org/10.1139/v97-205	journal	November 1997
Quantitative Interpretation of K-Edge NEXAFS Data for Various Nickel Hydroxides and the Charged Nickel Electrode Qian, X.; Sambe, H.; Ramaker, D. E. The Journal of Physical Chemistry B, Vol. 101, Issue 46 https://doi.org/10.1021/jp970435h	journal	November 1997
Electronic State of Nickel in Barium Nickel Oxide, BaNiO ₃ Gottschall, R.; Schöllhorn, R.; Muhler, M. Inorganic Chemistry, Vol. 37, Issue 7 https://doi.org/10.1021/ic9709279	journal	April 1998
Non-cooperative Jahn-Teller effect in LiNiO2: An EXAFS study Rougier, A.; Delmas, C.; Chadwick, A. V. Solid State Communications, Vol. 94, Issue 2 https://doi.org/10.1016/0038-1098(95)00020-8	journal	April 1995
Ab initio study of lithium intercalation in metal oxides and metal dichalcogenides Aydinol, M. K.; Kohan, A. F.; Ceder, G. Physical Review B, Vol. 56, Issue 3 https://doi.org/10.1103/PhysRevB.56.1354	journal	July 1997
Electronic structure of Li-doped NiO van Elp, J.; Eskes, H.; Kuiper, P. Physical Review B, Vol. 45, Issue 4 https://doi.org/10.1103/PhysRevB.45.1612	journal	January 1992
Various aspects of LiNiO ₂ chemistry: A review Kalyani, P.; Kalaiselvi, N. Science and Technology of Advanced Materials, Vol. 6, Issue 6 https://doi.org/10.1016/j.stam.2005.06.001	journal	January 2005
X-ray photoelectron spectroscopic chemical state quantification of mixed nickel metal, oxide and hydroxide systems Biesinger, Mark C.; Payne, Brad P.; Lau, Leo W. M. Surface and Interface Analysis, Vol. 41, Issue 4 https://doi.org/10.1002/sia.3026	journal	April 2009
New interpretations of XPS spectra of nickel metal and oxides Grosvenor, Andrew P.; Biesinger, Mark C.; Smart, Roger St. C. Surface Science, Vol. 600, Issue 9 https://doi.org/10.1016/j.susc.2006.01.041	journal	May 2006
Voltammetric and XPS investigations of nickel hydroxide electrochemically dispersed on gold surface electrodes Casella, Innocenzo G.; Guascito, Maria R.; Sannazzaro, Maria G. Journal of Electroanalytical Chemistry, Vol. 462, Issue 2 https://doi.org/10.1016/S0022-0728(98)00413-6	journal	February 1999
Dissolution and passivation of nickel. An X-ray photoelectron spectroscopic study Dickinson, Thomas; Povey, Andrew F.; Sherwood, Peter M. A. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 73, Issue 0 https://doi.org/10.1039/f19777300327	journal	January 1977
Electronic Structure of Lithium Nickel Oxides by Electron Energy Loss Spectroscopy Koyama, Yukinori; Mizoguchi, Teruyasu; Ikeno, Hidekazu The Journal of Physical Chemistry B, Vol. 109, Issue 21 https://doi.org/10.1021/jp050486b	journal	June 2005
Changes in Chemical Bondings by Li Deintercalation in LiMO ₂ (M=Cr, V, Co and Ni) Koyama, Yukinori; Kim, Yang-Soo; Tanaka, Isao Japanese Journal of Applied Physics, Vol. 38, Issue Part 1, No. 4A https://doi.org/10.1143/JJAP.38.2024	journal	April 1999
Changes in electronic structure by Li ion deintercalation in LiNiO2 from nickel L-edge and O K-edge XANES Uchimoto, Yoshiharu; Sawada, Hiroshi; Yao, Takeshi Journal of Power Sources, Vol. 97-98 https://doi.org/10.1016/S0378-7753(01)00624-3	journal	July 2001
White lines and $d$ -band occupancy for the $3 d$ transition-metal oxides and lithium transition-metal oxides Graetz, Jason; Ahn, Channing C.; Ouyang, Hao Physical Review B, Vol. 69, Issue 23 https://doi.org/10.1103/PhysRevB.69.235103	journal	June 2004
Character of Holes in ${Li}_{x} {Ni}_{1 - x} O$ and Their Magnetic Behavior Kuiper, P.; Kruizinga, G.; Ghijsen, J. Physical Review Letters, Vol. 62, Issue 2 https://doi.org/10.1103/PhysRevLett.62.221	journal	January 1989
Orbital Frustration at the Origin of the Magnetic Behavior in ${LiNiO}_{2}$ Reynaud, F.; Mertz, D.; Celestini, F. Physical Review Letters, Vol. 86, Issue 16 https://doi.org/10.1103/PhysRevLett.86.3638	journal	April 2001
Surface properties of LiCoO2, LiNiO2 and LiNi1−xCoxO2 Moses, Anthony W.; Flores, Harry G. Garcia; Kim, Jong-Gyu Applied Surface Science, Vol. 253, Issue 10 https://doi.org/10.1016/j.apsusc.2006.10.044	journal	March 2007
Charge disproportionation and Jahn-Teller distortion in LiNiO $_{2}$ and NaNiO $_{2}$ : A density functional theory study Chen, Hungru; Freeman, Colin L.; Harding, John H. Physical Review B, Vol. 84, Issue 8 https://doi.org/10.1103/PhysRevB.84.085108	journal	August 2011
The mechanism of electrodeposition and operation of Ni(OH)2 layers Wohlfahrtmehrens, M. Solid State Ionics, Vol. 86-88 https://doi.org/10.1016/0167-2738(96)00192-0	journal	July 1996
Nickel hydroxide electrodeposition from nickel nitrate solutions: mechanistic studies Jayashree, R. S.; Kamath, P. Vishnu Journal of Power Sources, Vol. 93, Issue 1-2 https://doi.org/10.1016/S0378-7753(00)00568-1	journal	February 2001
The Effect of Current and Nickel Nitrate Concentration on the Deposition of Nickel Hydroxide Films Streinz, Christopher C.; Hartman, Andrew P.; Motupally, Sathya Journal of The Electrochemical Society, Vol. 142, Issue 4 https://doi.org/10.1149/1.2044134	journal	April 1995
First principles reaction modeling of the electrochemical interface: Consideration and calculation of a tunable surface potential from atomic and electronic structure Taylor, Christopher D.; Wasileski, Sally A.; Filhol, Jean-Sebastien Physical Review B, Vol. 73, Issue 16 https://doi.org/10.1103/PhysRevB.73.165402	journal	April 2006
Effect of Ions on the Structure of Water: Structure Making and Breaking Marcus, Yizhak Chemical Reviews, Vol. 109, Issue 3 https://doi.org/10.1021/cr8003828	journal	March 2009
Effects of Deposition Potential and Anneal Temperature on the Hexagonal Nanoporous Nickel Hydroxide Films Chemistry of Materials, Vol. 19, Issue 16, p. 3882-3891 https://doi.org/10.1021/cm062720w	journal	July 2007
Electrochemical precipitation of nickel hydroxide Subbaiah, T.; Mallick, S. C.; Mishra, K. G. Journal of Power Sources, Vol. 112, Issue 2 https://doi.org/10.1016/S0378-7753(02)00470-6	journal	November 2002
Efficient electrochromic nickel oxide thin films by electrodeposition Sonavane, A. C.; Inamdar, A. I.; Shinde, P. S. Journal of Alloys and Compounds, Vol. 489, Issue 2 https://doi.org/10.1016/j.jallcom.2009.09.146	journal	January 2010
Synthesis and Electrochemical Investigations of Ni[sub 1−x]O Thin Films and Ni[sub 1−x]O on Three-Dimensional Carbon Substrates for Electrochemical Capacitors Nam, Kyung-Wan; Lee, Eun-Sung; Kim, Jae-Hong Journal of The Electrochemical Society, Vol. 152, Issue 11 https://doi.org/10.1149/1.2039647	journal	January 2005
Metal Oxide Catalysts for the Evolution of O ₂ from H ₂ O Merrill, Matthew D.; Dougherty, Ralph C. The Journal of Physical Chemistry C, Vol. 112, Issue 10 https://doi.org/10.1021/jp710675m	journal	March 2008
Three-dimensional bicontinuous ultrafast-charge and -discharge bulk battery electrodes Zhang, Huigang; Yu, Xindi; Braun, Paul V. Nature Nanotechnology, Vol. 6, Issue 5, p. 277-281 https://doi.org/10.1038/nnano.2011.38	journal	March 2011
Ni(OH) ₂ Nanoplates Grown on Graphene as Advanced Electrochemical Pseudocapacitor Materials Wang, Hailiang; Casalongue, Hernan Sanchez; Liang, Yongye Journal of the American Chemical Society, Vol. 132, Issue 21 https://doi.org/10.1021/ja102267j	journal	June 2010
In Situ Raman Studies on Cathodically Deposited Nickel Hydroxide Films and Electroless Ni−P Electrodes in 1 M KOH Solution Lo, Yi Ling; Hwang, Bing Joe Langmuir, Vol. 14, Issue 4 https://doi.org/10.1021/la9600255	journal	February 1998
Spatial resolution of redox processes within nickel oxide films on gold using real-time surface-enhanced Raman spectroscopy Gosztola, David; Weaver, Michael J. Langmuir, Vol. 5, Issue 3 https://doi.org/10.1021/la00087a034	journal	May 1989
X-ray diffraction and micro-Raman spectroscopy analysis of new nickel hydroxide obtained by electrodialysis Deabate, S.; Fourgeot, F.; Henn, F. Journal of Power Sources, Vol. 87, Issue 1-2 https://doi.org/10.1016/S0378-7753(99)00437-1	journal	April 2000
In Situ Laser Raman Spectroscopic Study of Anodic Corrosion Films on Nickel and Cobalt Melendres, C. A. Journal of The Electrochemical Society, Vol. 131, Issue 10 https://doi.org/10.1149/1.2115232	journal	January 1984
In situ Raman Spectroscopy Study of the Nickel Oxyhydroxide Electrode (NOE) System Johnston, C.; Graves, P. R. Applied Spectroscopy, Vol. 44, Issue 1 https://doi.org/10.1366/0003702904085769	journal	January 1990
Review of the structure and the electrochemistry of nickel hydroxides and oxy-hydroxides Oliva, P.; Leonardi, J.; Laurent, J. F. Journal of Power Sources, Vol. 8, Issue 2 https://doi.org/10.1016/0378-7753(82)80057-8	journal	January 1982
Angle-resolved infrared spectroelectrochemistry. 1. An in situ study of thin-film nickel oxide electrodes Nazri, Gholamabbas; Corrigan, Dennis A.; Maheswari, Shyam P. Langmuir, Vol. 5, Issue 1 https://doi.org/10.1021/la00085a004	journal	January 1989
Extended x-ray absorption fine structure investigations of nickel hydroxides Pandya, K. I.; O'Grady, W. E.; Corrigan, D. A. The Journal of Physical Chemistry, Vol. 94, Issue 1 https://doi.org/10.1021/j100364a005	journal	January 1990
Electrochemical and In Situ Raman Spectroscopic Characterization of Nickel Hydroxide Electrodes Kostecki, Robert Journal of The Electrochemical Society, Vol. 144, Issue 2 https://doi.org/10.1149/1.1837437	journal	January 1997
Structural models for nickel electrode active mass Cornilsen, B. C.; Karjala, P. J.; Loyselle, P. L. Journal of Power Sources, Vol. 22, Issue 3-4 https://doi.org/10.1016/0378-7753(88)80029-6	journal	March 1988
Electrochemical behaviour of the β(II)-Ni(OH)2/β(III)-NiOOH redox couple upon potentiodynamic cycling conditions Deabate, S.; Fourgeot, F.; Henn, F. Electrochimica Acta, Vol. 51, Issue 25 https://doi.org/10.1016/j.electacta.2006.02.012	journal	July 2006
In Situ Raman Study of Nickel Oxide and Gold-Supported Nickel Oxide Catalysts for the Electrochemical Evolution of Oxygen Yeo, Boon Siang; Bell, Alexis T. The Journal of Physical Chemistry C, Vol. 116, Issue 15 https://doi.org/10.1021/jp3007415	journal	April 2012
Photoelectrochemistry of Nickel Hydroxide Thin Films Carpenter, Michael K. Journal of The Electrochemical Society, Vol. 136, Issue 4 https://doi.org/10.1149/1.2096777	journal	January 1989
Redox behavior of the nickel oxide electrode system: quartz crystal microbalance studies Cheek, Graham T.; O'Grady, William E. Journal of Electroanalytical Chemistry, Vol. 421, Issue 1-2 https://doi.org/10.1016/S0022-0728(96)04821-8	journal	January 1997
Osmotic Coefficients and Mean Activity Coefficients of Uni‐univalent Electrolytes in Water at 25°C Hamer, Walter J.; Wu, Yung‐Chi Journal of Physical and Chemical Reference Data, Vol. 1, Issue 4 https://doi.org/10.1063/1.3253108	journal	October 1972
Proton Intercalation Hysteresis in Charging and Discharging Nickel Hydroxide Electrodes Ta, Kathryn Podolske; Newman, John Journal of The Electrochemical Society, Vol. 146, Issue 8 https://doi.org/10.1149/1.1392007	journal	August 1999
In situ time-resolved x-ray absorption near edge structure study of the nickel oxide electrode McBreen, J.; O'Grady, W. E.; Tourillon, G. The Journal of Physical Chemistry, Vol. 93, Issue 17 https://doi.org/10.1021/j100354a010	journal	August 1989
Methods for investigation of ionic reactions in aqueous solutions with half-times as short as 10 ^–9 sec. Application to neutralization and hydrolysis reactions Eigen, M. Discuss. Faraday Soc., Vol. 17, Issue 0 https://doi.org/10.1039/DF9541700194	journal	January 1954
Cyclic voltammetric studies of the effects of time and temperature on the capacitance of electrochemically deposited nickel hydroxide Kalu, E. E.; Nwoga, T. T.; Srinivasan, V. Journal of Power Sources, Vol. 92, Issue 1-2 https://doi.org/10.1016/S0378-7753(00)00520-6	journal	January 2001
Preparation of hexagonal nanoporous nickel hydroxide film and its application for electrochemical capacitor Zhao, Dan-Dan; Bao, Shu-Juan; Zhou, Wen-Jia Electrochemistry Communications, Vol. 9, Issue 5 https://doi.org/10.1016/j.elecom.2006.11.030	journal	May 2007
A Study of the Preparation of NiO[sub x] Electrode via Electrochemical Route for Supercapacitor Applications and Their Charge Storage Mechanism Nam, Kyung-Wan; Kim, Kwang-Bum Journal of The Electrochemical Society, Vol. 149, Issue 3 https://doi.org/10.1149/1.1449951	journal	January 2002
Synthesis of porous NiO nanocrystals with controllable surface area and their application as supercapacitor electrodes Zhang, Xiaojun; Shi, Wenhui; Zhu, Jixin Nano Research, Vol. 3, Issue 9 https://doi.org/10.1007/s12274-010-0024-6	journal	September 2010

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Title: Determination of the “NiOOH” charge and discharge mechanisms at ideal activity

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