Au and Pt nanoparticle supported catalysts tailored for H-2 production: From models to powder catalysts

Baber, A. E.; Rodriguez, J. A.; Senanayake, S. D.

doi:10.1016/j.apcata.2015.12.012

Title: Au and Pt nanoparticle supported catalysts tailored for H-2 production: From models to powder catalysts

Journal Article · Thu Dec 10 00:00:00 EST 2015 · Applied Catalysis. A, General

DOI:https://doi.org/10.1016/j.apcata.2015.12.012· OSTI ID:1303016

Baber, A. E. ^[1]; Rodriguez, J. A. ^[2]; Senanayake, S. D. ^[3]

James Madison Univ., Harrisonburg, VA (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)

The use of metal nanoparticles (NPs), including Au and Pt, supported over oxides has been pivotal, and is ever increasing in enabling catalytic reactions which target the production of hydrogen. We review here the most recent works pertaining to the fundamental understanding of the structure, morphology, growth, characterization, and intrinsic phenomenological properties of Au– and Pt– based catalysts that influence the reactivity and selectivity to target hydrogen production. We draw on surface science and theoretical methods of model and powder catalysts using high resolution imaging, spectroscopy, scattering experiments, and theoretical studies. Based on these insights we identify key aspects of studies of supported metal nanoparticle (NP) catalysts for several reactions. The main focus of this review is on the intersection of catalytic chemistry related to the water-gas shift (WGS), oxygenate steam reforming (OSR), and solarassisted reactions (SAR).

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC00112704; SC0012704.

OSTI ID:: 1303016

Alternate ID(s):: OSTI ID: 1250228

Report Number(s):: BNL-112496-2016-JA; R&D Project: CO009; KC0302010

Journal Information:: Applied Catalysis. A, General, Vol. 518; ISSN 0926-860X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 28 works

Citation information provided by
Web of Science

References (207)

An Investigation of the Reaction Pathway for Ethylene Hydrogenation on Pd(111) Stacchiola, D.; Azad, S.; Burkholder, L. The Journal of Physical Chemistry B, Vol. 105, Issue 45 https://doi.org/10.1021/jp012553h	journal	November 2001
Interaction of CO with OH on Au(111): HCOO, CO ₃ , and HOCO as Key Intermediates in the Water-Gas Shift Reaction Senanayake, Sanjaya D.; Stacchiola, Dario; Liu, Ping The Journal of Physical Chemistry C, Vol. 113, Issue 45 https://doi.org/10.1021/jp908169s	journal	October 2009
Mechanistic Studies of Water–Gas-Shift Reaction on Transition Metals Lin, Chia-Hao; Chen, Chung-Liang; Wang, Jeng-Han The Journal of Physical Chemistry C, Vol. 115, Issue 38 https://doi.org/10.1021/jp2034467	journal	September 2011
Formic Acid Dehydrogenation on Ni(111) and Comparison with Pd(111) and Pt(111) Luo, Qiquan; Feng, Gang; Beller, Matthias The Journal of Physical Chemistry C, Vol. 116, Issue 6 https://doi.org/10.1021/jp209998r	journal	February 2012
CO-Induced Diffusion of Ni Atoms to the Surface of Ni–Au Clusters on TiO ₂ (110) Tenney, Samuel A.; He, Wei; Roberts, Christopher C. The Journal of Physical Chemistry C, Vol. 115, Issue 22 https://doi.org/10.1021/jp2014258	journal	May 2011
Nucleation, Growth, and Adsorbate-Induced Changes in Composition for Co–Au Bimetallic Clusters on TiO ₂ Galhenage, Randima P.; Ammal, Salai C.; Yan, Hui The Journal of Physical Chemistry C, Vol. 116, Issue 46 https://doi.org/10.1021/jp307888p	journal	November 2012
Methanol Reaction on Pt–Au Clusters on TiO ₂ (110): Methoxy-Induced Diffusion of Pt Tenney, Samuel A.; Shah, S. Islamuddin; Yan, Hui The Journal of Physical Chemistry C, Vol. 117, Issue 51 https://doi.org/10.1021/jp409618j	journal	December 2013
Redox Pathways for HCOOH Decomposition over CeO ₂ Surfaces Senanayake, Sanjaya D.; Mullins, David R. The Journal of Physical Chemistry C, Vol. 112, Issue 26 https://doi.org/10.1021/jp8016425	journal	June 2008
Site Requirements for the Adsorption and Reaction of Oxygenates on Metal Oxide Surfaces Vohs, John M. Chemical Reviews, Vol. 113, Issue 6 https://doi.org/10.1021/cr300328u	journal	November 2012
Monoethanolamine Adsorption on TiO ₂ (110): Bonding, Structure, and Implications for Use as a Model Solid-Supported CO ₂ Capture Material Müller, Kathrin; Lu, Deyu; Senanayake, Sanjaya D. The Journal of Physical Chemistry C, Vol. 118, Issue 3 https://doi.org/10.1021/jp409098p	journal	January 2014
Electronic Structure of Magnesia−Ceria Model Catalysts, CO ₂ Adsorption, and CO ₂ Activation: A Synchrotron Radiation Photoelectron Spectroscopy Study Staudt, Thorsten; Lykhach, Yaroslava; Tsud, Nataliya The Journal of Physical Chemistry C, Vol. 115, Issue 17 https://doi.org/10.1021/jp200382y	journal	April 2011
Determining the Behavior of RuOx Nanoparticles in Mixed-Metal Oxides: Structural and Catalytic Properties of RuO2/TiO2(110) Surfaces Yang, Fan; Kundu, Shankhamala; Vidal, Alba B. Angewandte Chemie International Edition, Vol. 50, Issue 43 https://doi.org/10.1002/anie.201103798	journal	September 2011
Fundamental Studies of Well-Defined Surfaces of Mixed-Metal Oxides: Special Properties of MO _x /TiO ₂ (110) {M = V, Ru, Ce, or W} Stacchiola, Darío J.; Senanayake, Sanjaya D.; Liu, Ping Chemical Reviews, Vol. 113, Issue 6 https://doi.org/10.1021/cr300316v	journal	December 2012
Water-Gas Shift Reaction on a Highly Active Inverse CeO x /Cu(111) Catalyst: Unique Role of Ceria Nanoparticles Rodriguez, José A.; Graciani, Jesús; Evans, Jaime Angewandte Chemie, Vol. 121, Issue 43 https://doi.org/10.1002/ange.200903918	journal	October 2009
Probing the reaction intermediates for the water–gas shift over inverse CeOx/Au(111) catalysts Senanayake, Sanjaya D.; Stacchiola, Dario; Evans, Jaime Journal of Catalysis, Vol. 271, Issue 2 https://doi.org/10.1016/j.jcat.2010.02.024	journal	May 2010
Unique Properties of Ceria Nanoparticles Supported on Metals: Novel Inverse Ceria/Copper Catalysts for CO Oxidation and the Water-Gas Shift Reaction Senanayake, Sanjaya D.; Stacchiola, Dario; Rodriguez, Jose A. Accounts of Chemical Research, Vol. 46, Issue 8 https://doi.org/10.1021/ar300231p	journal	January 2013
The Unique Properties of the Oxide-Metal Interface: Reaction of Ethanol on an Inverse Model CeO _x –Au(111) Catalyst Senanayake, S. D.; Mudiyanselage, K.; Bruix, A. The Journal of Physical Chemistry C, Vol. 118, Issue 43 https://doi.org/10.1021/jp507966v	journal	October 2014
Chemistry of thiophene on Mo(110), MoCx and MoSx surfaces: photoemission studies Rodriguez, José A.; Dvorak, Joseph; Jirsak, Tomas Surface Science, Vol. 457, Issue 1-2 https://doi.org/10.1016/S0039-6028(00)00416-7	journal	June 2000
Catalytic Properties of Molybdenum Carbide, Nitride and Phosphide: A Theoretical Study Liu, Ping; Rodriguez, José A. Catalysis Letters, Vol. 91, Issue 3/4 https://doi.org/10.1023/B:CATL.0000007163.01772.19	journal	December 2003
Characterization of Molybdenum Carbide Nanoparticles Formed on Au(111) Using Reactive-Layer Assisted Deposition Horn, Jillian M.; Song, Zhen; Potapenko, Denis V. The Journal of Physical Chemistry B, Vol. 109, Issue 1 https://doi.org/10.1021/jp044837i	journal	January 2005
Desulfurization of Thiophene on Au/TiC(001): Au−C Interactions and Charge Polarization Rodriguez, José A.; Liu, Ping; Takahashi, Yoshiro Journal of the American Chemical Society, Vol. 131, Issue 24 https://doi.org/10.1021/ja901522a	journal	June 2009
Fundamentals of Methanol Synthesis on Metal Carbide Based Catalysts: Activation of CO2 and H2 Posada-Pérez, Sergio; Viñes, Francesc; Rodriguez, José A. Topics in Catalysis, Vol. 58, Issue 2-3 https://doi.org/10.1007/s11244-014-0355-8	journal	December 2014
Atomic-Scale Insights into Hydrodesulfurization ^† Kushmerick, J. G.; Kandel, S. A.; Han, P. The Journal of Physical Chemistry B, Vol. 104, Issue 14 https://doi.org/10.1021/jp993319i	journal	April 2000
Binding and Mobility of Atomically Resolved Cobalt Clusters on Molybdenum Disulfide Kandel, S. A.; Weiss, P. S. The Journal of Physical Chemistry B, Vol. 105, Issue 34 https://doi.org/10.1021/jp011264q	journal	August 2001
Coverage Effects and the Nature of the Metal−Sulfur Bond in S/Au(111): High-Resolution Photoemission and Density-Functional Studies Rodriguez, José A.; Dvorak, Joseph; Jirsak, Tomas Journal of the American Chemical Society, Vol. 125, Issue 1 https://doi.org/10.1021/ja021007e	journal	January 2003
Interaction of oxygen with TiN(001):N↔O exchange and oxidation process Graciani, J.; Fdez Sanz, J.; Asaki, T. The Journal of Chemical Physics, Vol. 126, Issue 24 https://doi.org/10.1063/1.2743418	journal	June 2007
Au ↔ N Synergy and N-Doping of Metal Oxide-Based Photocatalysts Graciani, Jesús; Nambu, Akira; Evans, Jaime Journal of the American Chemical Society, Vol. 130, Issue 36 https://doi.org/10.1021/ja802861u	journal	August 2008
Ordered cerium oxide thin films grown on Ru(0001) and Ni(111) Mullins, D.R.; Radulovic, P.V.; Overbury, S.H. Surface Science, Vol. 429, Issue 1-3, p. 186-198 https://doi.org/10.1016/S0039-6028(99)00369-6	journal	June 1999
Gold supported on well-ordered ceria films: nucleation, growth and morphology in CO oxidation reaction Lu, J. -L.; Gao, H. -J.; Shaikhutdinov, S. Catalysis Letters, Vol. 114, Issue 1-2 https://doi.org/10.1007/s10562-007-9039-3	journal	February 2007
Water Gas Shift Reaction on Cu and Au Nanoparticles Supported on CeO2(111) and ZnO(000): Intrinsic Activity and Importance of Support Interactions Rodriguez, José A.; Liu, Ping; Hrbek, Jan Angewandte Chemie International Edition, Vol. 46, Issue 8 https://doi.org/10.1002/anie.200603931	journal	February 2007
A New Type of Strong Metal–Support Interaction and the Production of H ₂ through the Transformation of Water on Pt/CeO ₂ (111) and Pt/CeO _x /TiO ₂ (110) Catalysts Bruix, Albert; Rodriguez, José A.; Ramírez, Pedro J. Journal of the American Chemical Society, Vol. 134, Issue 21 https://doi.org/10.1021/ja302070k	journal	May 2012
Mechanism for the water–gas shift reaction on monofunctional platinum and cause of catalyst deactivation Flaherty, David W.; Yu, Wen-Yueh; Pozun, Zachary D. Journal of Catalysis, Vol. 282, Issue 2 https://doi.org/10.1016/j.jcat.2011.06.024	journal	September 2011
Growth of Pt Nanoparticles on Reducible CeO ₂ (111) Thin Films: Effect of Nanostructures and Redox Properties of Ceria Zhou, Yinghui; Perket, Justin M.; Zhou, Jing The Journal of Physical Chemistry C, Vol. 114, Issue 27 https://doi.org/10.1021/jp1007279	journal	June 2010
STM studies of Au nano-clusters on TiO2(1 1 0) Spiridis, N.; Haber, J.; Korecki, J. Vacuum, Vol. 63, Issue 1-2 https://doi.org/10.1016/S0042-207X(01)00176-2	journal	July 2001
Understanding the Nucleation and Growth of Metals on TiO ₂ : Co Compared to Au, Ni, and Pt Galhenage, Randima P.; Yan, Hui; Tenney, Samuel A. The Journal of Physical Chemistry C, Vol. 117, Issue 14 https://doi.org/10.1021/jp401283k	journal	March 2013
Adsorption and diffusion of Pt and Au on the stoichiometric and reduced Ti O 2 rutile (110) surfaces Iddir, Hakim; Öğüt, Serdar; Browning, Nigel D. Physical Review B, Vol. 72, Issue 8 https://doi.org/10.1103/PhysRevB.72.081407	journal	August 2005
Enhanced Bonding of Gold Nanoparticles on Oxidized TiO2(110) Matthey, D.; Wang, J. G.; Wendt, S. Science, Vol. 315, Issue 5819 https://doi.org/10.1126/science.1135752	journal	March 2007
High catalytic activity of Au/CeOx/TiO2(110) controlled by the nature of the mixed-metal oxide at the nanometer level Park, J. B.; Graciani, J.; Evans, J. Proceedings of the National Academy of Sciences, Vol. 106, Issue 13 https://doi.org/10.1073/pnas.0812604106	journal	March 2009
Gold, Copper, and Platinum Nanoparticles Dispersed on CeO _x /TiO ₂ (110) Surfaces: High Water-Gas Shift Activity and the Nature of the Mixed-Metal Oxide at the Nanometer Level Park, Joon B.; Graciani, Jesus; Evans, Jaime Journal of the American Chemical Society, Vol. 132, Issue 1 https://doi.org/10.1021/ja9087677	journal	January 2010
Identification of an Adsorbed Hydroxyl Species on the Pt(111) Surface Fisher, Galen B.; Sexton, Brett A. Physical Review Letters, Vol. 44, Issue 10 https://doi.org/10.1103/PhysRevLett.44.683	journal	March 1980
Vibrational and structural properties of OH adsorbed on Pt(111) Bedürftig, K.; Völkening, S.; Wang, Y. The Journal of Chemical Physics, Vol. 111, Issue 24 https://doi.org/10.1063/1.480472	journal	December 1999
Erratum: Adsorption and diffusion of Pt and Au on the stoichiometric and reduced ${TiO}_{2}$ rutile (110) surfaces [Phys. Rev. B 72 , 081407(R) (2005)] Iddir, Hakim; Öğüt, Serdar; Browning, Nigel D. Physical Review B, Vol. 73, Issue 3 https://doi.org/10.1103/PhysRevB.73.039902	journal	January 2006
High Water−Gas Shift Activity in TiO ₂ (110) Supported Cu and Au Nanoparticles: Role of the Oxide and Metal Particle Size Rodríguez, José A.; Evans, Jaime; Graciani, Jesús The Journal of Physical Chemistry C, Vol. 113, Issue 17 https://doi.org/10.1021/jp900483u	journal	April 2009
On the difficulties of present theoretical models to predict the oxidation state of atomic Au adsorbed on regular sites of CeO[sub 2](111) Branda, María Marta; Castellani, Norberto J.; Grau-Crespo, Ricardo The Journal of Chemical Physics, Vol. 131, Issue 9 https://doi.org/10.1063/1.3216102	journal	January 2009
Enhanced Stability of Gold Clusters Supported on Hydroxylated MgO(001) Surfaces Brown, Matthew A.; Carrasco, Esther; Sterrer, Martin Journal of the American Chemical Society, Vol. 132, Issue 12 https://doi.org/10.1021/ja100343m	journal	March 2010
Oxidation of Au by Surface OH: Nucleation and Electronic Structure of Gold on Hydroxylated MgO(001) Brown, Matthew A.; Fujimori, Yuichi; Ringleb, Franziska Journal of the American Chemical Society, Vol. 133, Issue 27 https://doi.org/10.1021/ja204798z	journal	July 2011
Charge-Mediated Adsorption Behavior of CO on MgO-Supported Au Clusters Lin, Xiao; Yang, Bing; Benia, Hadj-Mohamed Journal of the American Chemical Society, Vol. 132, Issue 22 https://doi.org/10.1021/ja101188x	journal	June 2010
Quantum Well States in Two-Dimensional Gold Clusters on MgO Thin Films Lin, X.; Nilius, N.; Freund, H. -J. Physical Review Letters, Vol. 102, Issue 20 https://doi.org/10.1103/PhysRevLett.102.206801	journal	May 2009
Observable consequences of formation of Au anions from deposition of Au atoms on ultrathin oxide films Giordano, Livia; Martinez, Umberto; Sicolo, Sabrina The Journal of Chemical Physics, Vol. 127, Issue 14 https://doi.org/10.1063/1.2794339	journal	October 2007
CO Adsorption on One-, Two-, and Three-Dimensional Au Clusters Supported on MgO/Ag(001) Ultrathin Films Sicolo, Sabrina; Giordano, Livia; Pacchioni, Gianfranco The Journal of Physical Chemistry C, Vol. 113, Issue 23 https://doi.org/10.1021/jp9023266	journal	May 2009
Identification of Active Gold Nanoclusters on Iron Oxide Supports for CO Oxidation Herzing, A. A.; Kiely, C. J.; Carley, A. F. Science, Vol. 321, Issue 5894 https://doi.org/10.1126/science.1159639	journal	September 2008
Visualizing Gas Molecules Interacting with Supported Nanoparticulate Catalysts at Reaction Conditions Yoshida, H.; Kuwauchi, Y.; Jinschek, J. R. Science, Vol. 335, Issue 6066 https://doi.org/10.1126/science.1213194	journal	January 2012
Metallic Corner Atoms in Gold Clusters Supported on Rutile Are the Dominant Active Site during Water−Gas Shift Catalysis Williams, W. Damion; Shekhar, Mayank; Lee, Wen-Sheng Journal of the American Chemical Society, Vol. 132, Issue 40 https://doi.org/10.1021/ja1064262	journal	October 2010
Size and Support Effects for the Water–Gas Shift Catalysis over Gold Nanoparticles Supported on Model Al ₂ O ₃ and TiO ₂ Shekhar, Mayank; Wang, Jun; Lee, Wen-Sheng Journal of the American Chemical Society, Vol. 134, Issue 10 https://doi.org/10.1021/ja210083d	journal	February 2012
Control of Metal Nanocrystal Size Reveals Metal-Support Interface Role for Ceria Catalysts Cargnello, M.; Doan-Nguyen, V. V. T.; Gordon, T. R. Science, Vol. 341, Issue 6147 https://doi.org/10.1126/science.1240148	journal	July 2013
Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts Fu, Q. Science, Vol. 301, Issue 5635 https://doi.org/10.1126/science.1085721	journal	August 2003
Insights into the reactivity of supported Au nanoparticles: combining theory and experiments Janssens, Ton V. W.; Clausen, Bjerne S.; Hvolbæk, Britt Topics in Catalysis, Vol. 44, Issue 1-2 https://doi.org/10.1007/s11244-007-0335-3	journal	June 2007
Hydrogen Dissociation by Gold Clusters Fujitani, Tadahiro; Nakamura, Isao; Akita, Tomoki Angewandte Chemie International Edition, Vol. 48, Issue 50 https://doi.org/10.1002/anie.200905380	journal	November 2009
Au/TiO2 Nanosized Samples: A Catalytic, TEM, and FTIR Study of the Effect of Calcination Temperature on the CO Oxidation Boccuzzi, Flora; Chiorino, Anna; Manzoli, Maela Journal of Catalysis, Vol. 202, Issue 2 https://doi.org/10.1006/jcat.2001.3290	journal	September 2001
Catalysis of Gold Nanoparticles Deposited on Metal Oxides Haruta, Masatake CATTECH, Vol. 6, Issue 3, p. 102-115 https://doi.org/10.1023/A:1020181423055	journal	January 2002
A Au/Cu 2 O–TiO 2 system for photo-catalytic hydrogen production. A pn-junction effect or a simple case of in situ reduction? Sinatra, L.; LaGrow, A. P.; Peng, W. Journal of Catalysis, Vol. 322 https://doi.org/10.1016/j.jcat.2014.11.012	journal	February 2015
Can a Single Atom Serve as the Active Site in Some Heterogeneous Catalysts? Thomas, John Meurig; Saghi, Zineb; Gai, Pratibha L. Topics in Catalysis, Vol. 54, Issue 10-12 https://doi.org/10.1007/s11244-011-9677-y	journal	May 2011
Atomically Dispersed Supported Metal Catalysts Flytzani-Stephanopoulos, Maria; Gates, Bruce C. Annual Review of Chemical and Biomolecular Engineering, Vol. 3, Issue 1 https://doi.org/10.1146/annurev-chembioeng-062011-080939	journal	July 2012
Band Bending in Semiconductors: Chemical and Physical Consequences at Surfaces and Interfaces Zhang, Zhen; Yates, John T. Chemical Reviews, Vol. 112, Issue 10 https://doi.org/10.1021/cr3000626	journal	June 2012
Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis Yang, Xiao-Feng; Wang, Aiqin; Qiao, Botao Accounts of Chemical Research, Vol. 46, Issue 8 https://doi.org/10.1021/ar300361m	journal	April 2013
Understanding nano effects in catalysis Yang, Fan; Deng, Dehui; Pan, Xiulian National Science Review, Vol. 2, Issue 2 https://doi.org/10.1093/nsr/nwv024	journal	May 2015
Multicomponent Au/MgO catalysts designed for selective oxidation of carbon monoxideApplication of a combinatorial approach Tompos, András; Hegedűs, Mihály; Margitfalvi, József L. Applied Catalysis A: General, Vol. 334, Issue 1-2 https://doi.org/10.1016/j.apcata.2007.10.022	journal	January 2008
Gold catalysts prepared by coprecipitation for low-temperature oxidation of hydrogen and of carbon monoxide Haruta, M. Journal of Catalysis, Vol. 115, Issue 2 https://doi.org/10.1016/0021-9517(89)90034-1	journal	February 1989
Ultrastable single-atom gold catalysts with strong covalent metal-support interaction (CMSI) Qiao, Botao; Liang, Jin-Xia; Wang, Aiqin Nano Research, Vol. 8, Issue 9 https://doi.org/10.1007/s12274-015-0796-9	journal	July 2015
Single-atom catalysis of CO oxidation using Pt1/FeOx Qiao, Botao; Wang, Aiqin; Yang, Xiaofeng Nature Chemistry, Vol. 3, Issue 8 https://doi.org/10.1038/nchem.1095	journal	July 2011
Hydrogen and/or syngas from steam reforming of glycerol. Study of platinum catalysts Pompeo, Francisco; Santori, Gerardo; Nichio, Nora N. International Journal of Hydrogen Energy, Vol. 35, Issue 17 https://doi.org/10.1016/j.ijhydene.2010.06.011	journal	September 2010
Promotion of Phenol Photodecomposition over TiO ₂ Using Au, Pd, and Au–Pd Nanoparticles Su, Ren; Tiruvalam, Ramchandra; He, Qian ACS Nano, Vol. 6, Issue 7 https://doi.org/10.1021/nn301718v	journal	June 2012
When Gold Is Not Noble: Nanoscale Gold Catalysts Sanchez, A.; Abbet, S.; Heiz, U. The Journal of Physical Chemistry A, Vol. 103, Issue 48 https://doi.org/10.1021/jp9935992	journal	December 1999
FTIR study of low-temperature water-gas shift reaction on gold/ceria catalyst Tabakova, Tatyana; Boccuzzi, Flora; Manzoli, Maela Applied Catalysis A: General, Vol. 252, Issue 2 https://doi.org/10.1016/S0926-860X(03)00493-9	journal	October 2003
The Role of F-Centers in Catalysis by Au Supported on MgO Yan, Zhen; Chinta, Sivadinarayana; Mohamed, Ahmed A. Journal of the American Chemical Society, Vol. 127, Issue 6 https://doi.org/10.1021/ja043652m	journal	February 2005
CO ₂ Hydrogenation to Methanol on Supported Au Catalysts under Moderate Reaction Conditions: Support and Particle Size Effects Hartadi, Yeusy; Widmann, Daniel; Behm, R. Jürgen ChemSusChem, Vol. 8, Issue 3 https://doi.org/10.1002/cssc.201402645	journal	October 2014
Comparison of the activity of Au/CeO2 and Au/Fe2O3 catalysts for the CO oxidation and the water-gas shift reactions Deng, Weiling; Carpenter, Colin; Yi, Nan Topics in Catalysis, Vol. 44, Issue 1-2 https://doi.org/10.1007/s11244-007-0293-9	journal	June 2007
Activation of Gold on Titania: Adsorption and Reaction of SO ₂ on Au/TiO ₂ (110) Rodriguez, José A.; Liu, Gang; Jirsak, Tomas Journal of the American Chemical Society, Vol. 124, Issue 18 https://doi.org/10.1021/ja020115y	journal	May 2002
Junction effect interactions in methanol synthesis catalysts Frost, J. C. Nature, Vol. 334, Issue 6183 https://doi.org/10.1038/334577a0	journal	August 1988
In situ time-resolved characterization of Au–CeO2 and AuOx–CeO2 catalysts during the water-gas shift reaction: Presence of Au and O vacancies in the active phase Wang, X.; Rodriguez, J. A.; Hanson, J. C. The Journal of Chemical Physics, Vol. 123, Issue 22 https://doi.org/10.1063/1.2136876	journal	December 2005
Gold catalysts for pure hydrogen production in the water–gas shift reaction: activity, structure and reaction mechanism Burch, Robbie Phys. Chem. Chem. Phys., Vol. 8, Issue 47 https://doi.org/10.1039/B607837K	journal	January 2006
Gold-based catalysts for the water–gas shift reaction: Active sites and reaction mechanism☆ Rodriguez, José A. Catalysis Today, Vol. 160, Issue 1 https://doi.org/10.1016/j.cattod.2010.06.030	journal	February 2011
Structure and Reactivity of a Mononuclear Gold-Complex Catalyst Supported on Magnesium Oxide Guzman, Javier; Gates, Bruce C. Angewandte Chemie International Edition, Vol. 42, Issue 6 https://doi.org/10.1002/anie.200390191	journal	February 2003
A mononuclear gold complex catalyst supported on MgO: spectroscopic characterization during ethylene hydrogenation catalysis Guzman, J. Journal of Catalysis, Vol. 226, Issue 1 https://doi.org/10.1016/j.jcat.2004.05.014	journal	August 2004
Catalysis by Gold: Isolated Surface Au3+ Ions are Active Sites for Selective Hydrogenation of 1,3-Butadiene over Au/ZrO2 Catalysts Zhang, Xin; Shi, Hui; Xu, Bo-Qing Angewandte Chemie International Edition, Vol. 44, Issue 43 https://doi.org/10.1002/anie.200502101	journal	November 2005
Alkali-Stabilized Pt-OHx Species Catalyze Low-Temperature Water-Gas Shift Reactions Zhai, Y.; Pierre, D.; Si, R. Science, Vol. 329, Issue 5999 https://doi.org/10.1126/science.1192449	journal	September 2010
Alkali-Metal-Promoted Pt/TiO2 Opens a More Efficient Pathway to Formaldehyde Oxidation at Ambient Temperatures Zhang, Changbin; Liu, Fudong; Zhai, Yanping Angewandte Chemie International Edition, Vol. 51, Issue 38 https://doi.org/10.1002/anie.201202034	journal	August 2012
Atomically Dispersed Au–(OH) _x Species Bound on Titania Catalyze the Low-Temperature Water-Gas Shift Reaction Yang, Ming; Allard, Lawrence F.; Flytzani-Stephanopoulos, Maria Journal of the American Chemical Society, Vol. 135, Issue 10 https://doi.org/10.1021/ja312646d	journal	March 2013
Catalytically active Au-O(OH) _x - species stabilized by alkali ions on zeolites and mesoporous oxides Yang, Ming; Li, Sha; Wang, Yuan Science, Vol. 346, Issue 6216 https://doi.org/10.1126/science.1260526	journal	November 2014
On the origin of the catalytic activity of gold nanoparticles for low-temperature CO oxidation Lopez, N. Journal of Catalysis, Vol. 223, Issue 1 https://doi.org/10.1016/j.jcat.2004.01.001	journal	April 2004
Photoassisted hydrogen production from a water-ethanol solution: a comparison of activities of AuTiO2 and PtTiO2 Bamwenda, Gratian R.; Tsubota, Susumu; Nakamura, Toshiko Journal of Photochemistry and Photobiology A: Chemistry, Vol. 89, Issue 2 https://doi.org/10.1016/1010-6030(95)04039-I	journal	July 1995
Size- and support-dependency in the catalysis of gold Haruta, Masatake Catalysis Today, Vol. 36, Issue 1 https://doi.org/10.1016/S0920-5861(96)00208-8	journal	April 1997
Influence of the conditions of thermal treatments and of storage on the size of the gold particles in Au/TiO2 samples Zanella, Rodolfo; Louis, Catherine Catalysis Today, Vol. 107-108 https://doi.org/10.1016/j.cattod.2005.07.008	journal	October 2005
Bio-ethanol catalytic steam reforming over supported metal catalysts Auprêtre, Fabien; Descorme, Claude; Duprez, Daniel Catalysis Communications, Vol. 3, Issue 6 https://doi.org/10.1016/S1566-7367(02)00118-8	journal	June 2002
Metal-catalysed steam reforming of ethanol in the production of hydrogen for fuel cell applications Breen, J. P.; Burch, R.; Coleman, H. M. Applied Catalysis B: Environmental, Vol. 39, Issue 1 https://doi.org/10.1016/S0926-3373(02)00075-9	journal	November 2002
Production of hydrogen for fuel cells by steam reforming of ethanol over supported noble metal catalysts Liguras, Dimitris K.; Kondarides, Dimitris I.; Verykios, Xenophon E. Applied Catalysis B: Environmental, Vol. 43, Issue 4 https://doi.org/10.1016/S0926-3373(02)00327-2	journal	July 2003
Performance of NiO–MgO solid solution-supported Pt catalysts in oxidative steam reforming of methane Nurunnabi, Mohammad; Li, Baitao; Kunimori, Kimio Applied Catalysis A: General, Vol. 292 https://doi.org/10.1016/j.apcata.2005.06.022	journal	September 2005
Catalytic Conversion of Ethanol to Hydrogen Using Combinatorial Methods Duan, Shici; Senkan, Selim Industrial & Engineering Chemistry Research, Vol. 44, Issue 16 https://doi.org/10.1021/ie049202k	journal	August 2005
Photo-catalytic production of hydrogen form ethanol over M/TiO2 catalysts (M=Pd, Pt or Rh) Yang, Y.; Chang, C.; Idriss, H. Applied Catalysis B: Environmental, Vol. 67, Issue 3-4 https://doi.org/10.1016/j.apcatb.2006.05.007	journal	October 2006
Hydrogen formation in ethanol reforming on supported noble metal catalysts Erdőhelyi, András; Raskó, János; Kecskés, Tamara Catalysis Today, Vol. 116, Issue 3 https://doi.org/10.1016/j.cattod.2006.05.073	journal	August 2006
Low Temperature Steam Reforming of Ethanol Over Supported Noble Metal Catalysts Basagiannis, Aristides C.; Panagiotopoulou, Paraskevi; Verykios, Xenophon E. Topics in Catalysis, Vol. 51, Issue 1-4 https://doi.org/10.1007/s11244-008-9130-z	journal	October 2008
Mechanistic Aspects of the Ethanol Steam Reforming Reaction for Hydrogen Production on Pt, Ni, and PtNi Catalysts Supported on γ-Al ₂ O ₃ ^† Sanchez-Sanchez, Maria Cruz; Navarro Yerga, Rufino M.; Kondarides, Dimitris I. The Journal of Physical Chemistry A, Vol. 114, Issue 11 https://doi.org/10.1021/jp906531x	journal	March 2010
Solar light photocatalytic hydrogen production from water over Pt and Au/TiO2(anatase/rutile) photocatalysts: Influence of noble metal and porogen promotion Rosseler, Olivier; Shankar, Muthukonda V.; Du, Maithaa Karkmaz-Le Journal of Catalysis, Vol. 269, Issue 1 https://doi.org/10.1016/j.jcat.2009.11.006	journal	January 2010
Understanding the stability of Co-supported catalysts during ethanol reforming as addressed by in situ temperature and spatial resolved XAFS analysis Ávila-Neto, C. N.; Liberatori, J. W. C.; da Silva, A. M. Journal of Catalysis, Vol. 287 https://doi.org/10.1016/j.jcat.2011.12.013	journal	March 2012
In situ studies of CeO2-supported Pt, Ru, and Pt–Ru alloy catalysts for the water–gas shift reaction: Active phases and reaction intermediates Xu, Wenqian; Si, Rui; Senanayake, Sanjaya D. Journal of Catalysis, Vol. 291 https://doi.org/10.1016/j.jcat.2012.04.013	journal	July 2012
Exploring the Structural and Electronic Properties of Pt/Ceria-Modified TiO ₂ and Its Photocatalytic Activity for Water Splitting under Visible Light Kundu, Shankhamala; Ciston, Jim; Senanayake, Sanjaya D. The Journal of Physical Chemistry C, Vol. 116, Issue 26 https://doi.org/10.1021/jp304475x	journal	June 2012
Pt vs. Au in water–gas shift reaction Gonzalez Castaño, M.; Reina, T. R.; Ivanova, S. Journal of Catalysis, Vol. 314 https://doi.org/10.1016/j.jcat.2014.03.014	journal	May 2014
Water-gas shift: comparative screening of metal promoters for metal/ceria systems and role of the metal Jacobs, G. Applied Catalysis A: General, Vol. 258, Issue 2 https://doi.org/10.1016/j.apcata.2003.09.007	journal	February 2004
The Importance of Strongly Bound Pt–CeO x Species for the Water-gas Shift Reaction: Catalyst Activity and Stability Evaluation Pierre, Danny; Deng, Weiling; Flytzani-Stephanopoulos, Maria Topics in Catalysis, Vol. 46, Issue 3-4 https://doi.org/10.1007/s11244-007-9013-8	journal	November 2007
Production of hydrogen via steam reforming of biofuels on Ni/CeO2–Al2O3 catalysts promoted by noble metals Profeti, Luciene P. R.; Ticianelli, Edson A.; Assaf, Elisabete M. International Journal of Hydrogen Energy, Vol. 34, Issue 12 https://doi.org/10.1016/j.ijhydene.2009.03.050	journal	June 2009
Ethanol steam reforming over Rh and Pt catalysts: effect of temperature and catalyst deactivation Bilal, Muhammad; Jackson, S. David Catal. Sci. Technol., Vol. 3, Issue 3 https://doi.org/10.1039/C2CY20703F	journal	January 2013
Low-temperature water-gas shift reaction over Au/CeO2 catalysts Andreeva, D.; Idakiev, V.; Tabakova, T. Catalysis Today, Vol. 72, Issue 1-2 https://doi.org/10.1016/S0920-5861(01)00477-1	journal	February 2002
Low temperature water-gas shift: Examining the efficiency of Au as a promoter for ceria-based catalysts prepared by CVD of a Au precursor Jacobs, Gary; Ricote, Sandrine; Patterson, Patricia M. Applied Catalysis A: General, Vol. 292 https://doi.org/10.1016/j.apcata.2005.06.003	journal	September 2005
Effects of gold nanoparticles deposition on the photocatalytic activity of titanium dioxide under visible light Dozzi, Maria Vittoria; Prati, Laura; Canton, Patrizia Physical Chemistry Chemical Physics, Vol. 11, Issue 33 https://doi.org/10.1039/b907317e	journal	January 2009
Influence of Excitation Wavelength (UV or Visible Light) on the Photocatalytic Activity of Titania Containing Gold Nanoparticles for the Generation of Hydrogen or Oxygen from Water Gomes Silva, Cláudia; Juárez, Raquel; Marino, Tiziana Journal of the American Chemical Society, Vol. 133, Issue 3 https://doi.org/10.1021/ja1086358	journal	January 2011
The effect of gold loading and particle size on photocatalytic hydrogen production from ethanol over Au/TiO2 nanoparticles Murdoch, M.; Waterhouse, G. I. N.; Nadeem, M. A. Nature Chemistry, Vol. 3, Issue 6 https://doi.org/10.1038/nchem.1048	journal	May 2011
Effect of Ceria on Gold–Titania Catalysts for the Water–Gas Shift Reaction: Fundamental Studies for Au/CeO _x /TiO ₂ (110) and Au/CeO _x /TiO ₂ Powders Si, Rui; Tao, Jing; Evans, Jaime The Journal of Physical Chemistry C, Vol. 116, Issue 44 https://doi.org/10.1021/jp3089325	journal	October 2012
Catalytically active structures of SiO ₂ -supported Au nanoparticles in low-temperature CO oxidation Qian, Kun; Luo, Liangfeng; Bao, Huizhi Catal. Sci. Technol., Vol. 3, Issue 3 https://doi.org/10.1039/C2CY20481A	journal	January 2013
Influence of the preparation method and dopants nature on the WGS activity of gold catalysts supported on doped by transition metals ceria Tabakova, T.; Ilieva, L.; Ivanov, I. Applied Catalysis B: Environmental, Vol. 136-137 https://doi.org/10.1016/j.apcatb.2013.01.050	journal	June 2013
In situ assembly of well-dispersed Au nanoparticles on TiO2/ZnO nanofibers: A three-way synergistic heterostructure with enhanced photocatalytic activity Zhang, Peng; Shao, Changlu; Li, Xinghua Journal of Hazardous Materials, Vol. 237-238 https://doi.org/10.1016/j.jhazmat.2012.08.054	journal	October 2012
Supported platinum–zinc oxide core–shell nanoparticle catalysts for methanol steam reforming Arroyo-Ramírez, Lisandra; Chen, Chen; Cargnello, Matteo J. Mater. Chem. A, Vol. 2, Issue 45 https://doi.org/10.1039/C4TA04790G	journal	January 2014
Nanoplate-Built ZnO Hollow Microspheres Decorated with Gold Nanoparticles and Their Enhanced Photocatalytic and Gas-Sensing Properties Xia, Weiwei; Mei, Chao; Zeng, Xianghua ACS Applied Materials & Interfaces, Vol. 7, Issue 22 https://doi.org/10.1021/acsami.5b01333	journal	May 2015
Myosin Vb controls biogenesis of post-Golgi Rab10 carriers during axon development Liu, Yang; Xu, Xiao-Hui; Chen, Qi Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3005	journal	June 2013
Pt and Au/TiO2 photocatalysts for methanol reforming: Role of metal nanoparticles in tuning charge trapping properties and photoefficiency Naldoni, Alberto; D’Arienzo, Massimiliano; Altomare, Marco Applied Catalysis B: Environmental, Vol. 130-131 https://doi.org/10.1016/j.apcatb.2012.11.006	journal	February 2013
Gold-plasmon enhanced solar-to-hydrogen conversion on the {001} facets of anatase TiO2 nanosheets Long, Jinlin; Chang, Hongjin; Gu, Quan Energy & Environmental Science, Vol. 7, Issue 3 https://doi.org/10.1039/c3ee43289k	journal	January 2014
Promotion of atomic hydrogen recombination as an alternative to electron trapping for the role of metals in the photocatalytic production of H2 Joo, J. B.; Dillon, R.; Lee, I. Proceedings of the National Academy of Sciences, Vol. 111, Issue 22 https://doi.org/10.1073/pnas.1405365111	journal	May 2014
The critical role of intragap states in the energy transfer from gold nanoparticles to TiO ₂ Naldoni, Alberto; Fabbri, Filippo; Altomare, Marco Physical Chemistry Chemical Physics, Vol. 17, Issue 7 https://doi.org/10.1039/C4CP05775A	journal	January 2015
Analysis of the Promoted Activity and Molecular Mechanism of Hydrogen Production over Fine Au–Pt Alloyed TiO ₂ Photocatalysts Wang, Fenglong; Jiang, Yijiao; Lawes, Douglas J. ACS Catalysis, Vol. 5, Issue 7 https://doi.org/10.1021/acscatal.5b00623	journal	June 2015
Support Effect in High Activity Gold Catalysts for CO Oxidation Comotti, Massimiliano; Li, Wen-Cui; Spliethoff, Bernd Journal of the American Chemical Society, Vol. 128, Issue 3 https://doi.org/10.1021/ja0561441	journal	January 2006
Hydrogen production by photocatalytic steam reforming of methanol on noble metal-modified TiO2 Chiarello, Gian Luca; Aguirre, Myriam H.; Selli, Elena Journal of Catalysis, Vol. 273, Issue 2 https://doi.org/10.1016/j.jcat.2010.05.012	journal	July 2010
Size-dependence of plasmonic Au nanoparticles in photocatalytic behavior of Au/TiO 2 and Au@SiO 2 /TiO 2 Yoo, Seon Mi; Rawal, Sher Bahadur; Lee, Ji Eun Applied Catalysis A: General, Vol. 499 https://doi.org/10.1016/j.apcata.2015.04.003	journal	June 2015
Physicochemical and photocatalytic characterizations of TiO2/Pt nanocomposites Liu, Zhaolin; Guo, Bing; Hong, Liang Journal of Photochemistry and Photobiology A: Chemistry, Vol. 172, Issue 1 https://doi.org/10.1016/j.jphotochem.2004.11.008	journal	May 2005
Enhanced visible photocatalytic activity of hybrid Pt/α-Fe2O3 nanorods Chen, Long; Li, Feng; Ni, Binbin RSC Advances, Vol. 2, Issue 26 https://doi.org/10.1039/c2ra21897f	journal	January 2012
One-Pot Polyol Synthesis of Pt/CeO₂ and Au/CeO₂ Nanopowders as Catalysts for CO Oxidation Pilger, Frank; Testino, Andrea; Lucchini, Mattia Alberto Journal of Nanoscience and Nanotechnology, Vol. 15, Issue 5 https://doi.org/10.1166/jnn.2015.9861	journal	May 2015
Highly ordered mesoporous titania–zirconia photocatalyst for applications in degradation of rhodamine-B and hydrogen evolution Yuan, Quan; Liu, Yang; Li, Le-Le Microporous and Mesoporous Materials, Vol. 124, Issue 1-3 https://doi.org/10.1016/j.micromeso.2009.05.006	journal	August 2009
Tailored Titanium Dioxide Nanomaterials: Anatase Nanoparticles and Brookite Nanorods as Highly Active Photocatalysts Kandiel, Tarek A.; Feldhoff, Armin; Robben, Lars Chemistry of Materials, Vol. 22, Issue 6 https://doi.org/10.1021/cm903472p	journal	March 2010
Comparative study of the photodeposition of Pt, Au and Pd on pre-sulphated TiO2 for the photocatalytic decomposition of phenol Maicu, M.; Hidalgo, M. C.; Colón, G. Journal of Photochemistry and Photobiology A: Chemistry, Vol. 217, Issue 2-3 https://doi.org/10.1016/j.jphotochem.2010.10.020	journal	January 2011
Mesoporous plasmonic Au–TiO2 nanocomposites for efficient visible-light-driven photocatalytic water reduction Fang, Jun; Cao, Shao-Wen; Wang, Zheng International Journal of Hydrogen Energy, Vol. 37, Issue 23 https://doi.org/10.1016/j.ijhydene.2012.09.023	journal	December 2012
Hydrogen Evolution from Water/Alcohol Mixtures: Effective In Situ Generation of an Active Au/TiO2 catalyst Gärtner, Felix; Losse, Sebastian; Boddien, Albert ChemSusChem, Vol. 5, Issue 3 https://doi.org/10.1002/cssc.201100281	journal	October 2011
Photocatalytic H2 and O2 evolution over tungsten oxide dispersed on silica Liu, Gang; Wang, Xiuli; Wang, Xiang Journal of Catalysis, Vol. 293 https://doi.org/10.1016/j.jcat.2012.06.003	journal	September 2012
Sunlight-promoted photocatalytic hydrogen gas evolution from water-suspended cellulose: a systematic study Speltini, Andrea; Sturini, Michela; Dondi, Daniele Photochem. Photobiol. Sci., Vol. 13, Issue 10 https://doi.org/10.1039/C4PP00128A	journal	January 2014
In Situ Photochemical Synthesis of Zn-Doped Cu ₂ O Hollow Microcubes for High Efficient Photocatalytic H ₂ Production Zhang, Longzhou; Jing, Dengwei; Guo, Liejin ACS Sustainable Chemistry & Engineering, Vol. 2, Issue 6 https://doi.org/10.1021/sc500045e	journal	May 2014
Promoting Effect of CeO ₂ in Combustion Synthesized Pt/CeO ₂ Catalyst for CO Oxidation Bera, Parthasarathi; Gayen, Arup; Hegde, M. S. The Journal of Physical Chemistry B, Vol. 107, Issue 25 https://doi.org/10.1021/jp022132f	journal	June 2003
Application of the direct exchange method in the preparation of gold catalysts supported on different oxide materials Ivanova, Svetlana; Pitchon, Véronique; Petit, Corinne Journal of Molecular Catalysis A: Chemical, Vol. 256, Issue 1-2 https://doi.org/10.1016/j.molcata.2006.05.006	journal	August 2006
Immobilization of noble metal nanoparticles on the surface of TiO2 by the sonochemical method: Photocatalytic production of hydrogen from an aqueous solution of ethanol Mizukoshi, Yoshiteru; Makise, Yoji; Shuto, Tatsuya Ultrasonics Sonochemistry, Vol. 14, Issue 3 https://doi.org/10.1016/j.ultsonch.2006.08.001	journal	March 2007
Thermally Stable Pt/CeO₂ Hetero-Nanocomposites with High Catalytic Activity Zhou, Huan-Ping; Wu, Hao-Shuai; Shen, Jie Journal of the American Chemical Society, Vol. 132, Issue 14, p. 4998-4999 https://doi.org/10.1021/ja101110m	journal	April 2010
Impact of Ce–Fe synergism on the catalytic behaviour of Au/CeO ₂ –FeO _x /Al ₂ O ₃ for pure H ₂ production Reina, Tomás Ramírez; Ivanova, Svetlana; Idakiev, Vasko Catal. Sci. Technol., Vol. 3, Issue 3 https://doi.org/10.1039/C2CY20537H	journal	January 2013
Water-gas-shift reaction on metal nanoparticles and surfaces Liu, Ping; Rodriguez, José A. The Journal of Chemical Physics, Vol. 126, Issue 16 https://doi.org/10.1063/1.2722747	journal	April 2007
Studies of the water-gas-shift reaction on ceria-supported Pt, Pd, and Rh: Implications for oxygen-storage properties Bunluesin, T.; Gorte, R. J.; Graham, G. W. Applied Catalysis B: Environmental, Vol. 15, Issue 1-2 https://doi.org/10.1016/S0926-3373(97)00040-4	journal	January 1998
Mechanistic study of water–gas-shift reaction over TiO₂ supported Pt–Re and Pd–Re catalysts Sato, Yasushi; Terada, Keisuke; Hasegawa, Satoshi Applied Catalysis A: General, Vol. 296, Issue 1, p. 80-89 https://doi.org/10.1016/j.apcata.2005.08.009	journal	November 2005
A comparative study of the water gas shift reaction over platinum catalysts supported on CeO2, TiO2 and Ce-modified TiO2 González, I. D.; Navarro, R. M.; Wen, W. Catalysis Today, Vol. 149, Issue 3-4 https://doi.org/10.1016/j.cattod.2009.07.100	journal	January 2010
First-principles study of the $Pt ∕ Ce O_{2} (111)$ interface Yang, Zongxian; Lu, Zhansheng; Luo, Gaixia Physical Review B, Vol. 76, Issue 7 https://doi.org/10.1103/PhysRevB.76.075421	journal	August 2007
Rationalization of Interactions in Precious Metal/Ceria Catalysts Using the d-Band Center Model Acerbi, N.; Tsang, S. C. Edman; Jones, G. Angewandte Chemie International Edition, Vol. 52, Issue 30 https://doi.org/10.1002/anie.201300130	journal	June 2013
Why gold is the noblest of all the metals Hammer, B.; Norskov, J. K. Nature, Vol. 376, Issue 6537 https://doi.org/10.1038/376238a0	journal	July 1995
Mechanism of the Water Gas Shift Reaction on Pt: First Principles, Experiments, and Microkinetic Modeling Grabow, Lars C.; Gokhale, Amit A.; Evans, Steven T. The Journal of Physical Chemistry C, Vol. 112, Issue 12 https://doi.org/10.1021/jp7099702	journal	March 2008
Water Gas Shift Catalysis Ratnasamy, Chandra; Wagner, Jon P. Catalysis Reviews, Vol. 51, Issue 3 https://doi.org/10.1080/01614940903048661	journal	September 2009
Density Functional Theory Comparison of Water Dissociation Steps on Cu, Au, Ni, Pd, and Pt Phatak, Abhijit A.; Delgass, W. Nicholas; Ribeiro, Fabio H. The Journal of Physical Chemistry C, Vol. 113, Issue 17 https://doi.org/10.1021/jp810216b	journal	April 2009
Review of literature on catalysts for biomass gasification Sutton, David; Kelleher, Brian; Ross, Julian R. H. Fuel Processing Technology, Vol. 73, Issue 3 https://doi.org/10.1016/S0378-3820(01)00208-9	journal	November 2001
A review of catalytic issues and process conditions for renewable hydrogen and alkanes by aqueous-phase reforming of oxygenated hydrocarbons over supported metal catalysts Davda, R. R.; Shabaker, J. W.; Huber, G. W. Applied Catalysis B: Environmental, Vol. 56, Issue 1-2, p. 171-186 https://doi.org/10.1016/j.apcatb.2004.04.027	journal	March 2005
Catalysts for methanol steam reforming—A review Sá, Sandra; Silva, Hugo; Brandão, Lúcia Applied Catalysis B: Environmental, Vol. 99, Issue 1-2 https://doi.org/10.1016/j.apcatb.2010.06.015	journal	August 2010
Hydrogen production by sorption enhanced steam reforming of oxygenated hydrocarbons (ethanol, glycerol, n-butanol and methanol): Thermodynamic modelling Lima da Silva, Aline; Müller, Iduvirges Lourdes International Journal of Hydrogen Energy, Vol. 36, Issue 3 https://doi.org/10.1016/j.ijhydene.2010.11.051	journal	February 2011
Production of Hydrogen from Ethanol: Review of Reaction Mechanism and Catalyst Deactivation Mattos, Lisiane V.; Jacobs, Gary; Davis, Burtron H. Chemical Reviews, Vol. 112, Issue 7 https://doi.org/10.1021/cr2000114	journal	April 2012
Toward Understanding Metal-Catalyzed Ethanol Reforming Zanchet, Daniela; Santos, Joao Batista O.; Damyanova, Sonia ACS Catalysis, Vol. 5, Issue 6 https://doi.org/10.1021/cs5020755	journal	May 2015
In situ DRIFTS investigation of the steam reforming of methanol over Pt/ceria Jacobs, Gary; Davis, Burtron H. Applied Catalysis A: General, Vol. 285, Issue 1-2 https://doi.org/10.1016/j.apcata.2005.02.006	journal	May 2005
Adsorption and reactions of ethanol and ethanol–water mixture on alumina-supported Pt catalysts Domok, M.; Toth, M.; Rasko, J. Applied Catalysis B: Environmental, Vol. 69, Issue 3-4 https://doi.org/10.1016/j.apcatb.2006.06.001	journal	January 2007
Steam reforming of ethanol over Pt/ceria with co-fed hydrogen Jacobs, G.; Keogh, R.; Davis, B. Journal of Catalysis, Vol. 245, Issue 2 https://doi.org/10.1016/j.jcat.2006.10.018	journal	January 2007
Spectroscopic identification of adsorbed species derived from adsorption and decomposition of formic acid, methanol, and formaldehyde on cerium oxide Li, C. Journal of Catalysis, Vol. 125, Issue 2 https://doi.org/10.1016/0021-9517(90)90317-D	journal	October 1990
Regulation of reaction intermediate by reactant in the water-gas shift reaction on CeO2, in relation to reactant-promoted mechanism Shido, T.; Iwasawa, Y. Journal of Catalysis, Vol. 136, Issue 2 https://doi.org/10.1016/0021-9517(92)90079-W	journal	August 1992
A Spectroscopic Characterization of the Reduction of Ceria from Electronic Transitions of Intrinsic Point Defects Binet, Claude; Badri, Ahmed; Lavalley, Jean-Claude The Journal of Physical Chemistry, Vol. 98, Issue 25 https://doi.org/10.1021/j100076a025	journal	June 1994
IR study of polycrystalline ceria properties in oxidised and reduced states Binet, Claude; Daturi, Marco; Lavalley, Jean-Claude Catalysis Today, Vol. 50, Issue 2 https://doi.org/10.1016/S0920-5861(98)00504-5	journal	April 1999
Mechanisms of catalyst deactivation Bartholomew, Calvin H. Applied Catalysis A: General, Vol. 212, Issue 1-2 https://doi.org/10.1016/S0926-860X(00)00843-7	journal	April 2001
Beneficial Effects of Noble Metal Addition to Ni/Al2O3 Catalyst for Oxidative Methane-to-Syngas Conversion Choudhary, V. R.; Prabhakar, B.; Rajput, A. M. Journal of Catalysis, Vol. 157, Issue 2 https://doi.org/10.1006/jcat.1995.1342	journal	December 1995
Characterization of alumina-supported Ni and Ni-Pd catalysts for partial oxidation and steam reforming of hydrocarbons Zhang, Jinchang; Wang, Yanhui; Ma, Runyu Applied Catalysis A: General, Vol. 243, Issue 2 https://doi.org/10.1016/S0926-860X(02)00561-6	journal	April 2003
Alumina-supported Ni catalysts modified with silver for the steam reforming of methane: Effect of Ag on the control of coke formation Parizotto, N. V.; Rocha, K. O.; Damyanova, S. Applied Catalysis A: General, Vol. 330 https://doi.org/10.1016/j.apcata.2007.06.022	journal	October 2007
Hydrogen production from ethanol over bimetallic Rh-M/CeO2 (M=Pd or Pt) Sheng, P.; Chiu, W.; Yee, A. Catalysis Today, Vol. 129, Issue 3-4 https://doi.org/10.1016/j.cattod.2006.09.040	journal	December 2007
Bimetallic Pt-Metal catalysts for the decomposition of methanol: Effect of secondary metal on the oxidation state, activity, and selectivity of Pt Croy, Jason R.; Mostafa, S.; Hickman, L. Applied Catalysis A: General, Vol. 350, Issue 2 https://doi.org/10.1016/j.apcata.2008.08.013	journal	November 2008
Ethanol steam reforming over supported ruthenium and ruthenium–platinum catalysts: Comparison of organometallic clusters and inorganic salts as catalyst precursors Koh, Alaric C. W.; Chen, Luwei; Leong, Weng Kee International Journal of Hydrogen Energy, Vol. 34, Issue 14 https://doi.org/10.1016/j.ijhydene.2009.05.044	journal	July 2009
Methanol Steam Reforming over Indium-Promoted Pt/Al ₂ O ₃ Catalyst: Nature of the Active Surface Barbosa, Roland L.; Papaefthimiou, Vasiliki; Law, Yeuk T. The Journal of Physical Chemistry C, Vol. 117, Issue 12 https://doi.org/10.1021/jp309401q	journal	March 2013
Ethanol reactions over Au–Rh/CeO2 catalysts. Total decomposition and H2 formation Sheng, P. Y.; Idriss, H. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 22, Issue 4 https://doi.org/10.1116/1.1705591	journal	July 2004
The Reactions of Ethanol over Au/CeO2 Sheng, P. -Y.; Bowmaker, G. A.; Idriss, H. Applied Catalysis A: General, Vol. 261, Issue 2 https://doi.org/10.1016/j.apcata.2003.10.046	journal	April 2004
A force field for simulating ethanol adsorption on Au(111) surfaces. A DFT study Fartaria, Rui P. S.; Freitas, Filomena F. M.; Silva Fernandes, Fernando M. S. International Journal of Quantum Chemistry, Vol. 107, Issue 11 https://doi.org/10.1002/qua.21402	journal	January 2007
DFT studies for cleavage of C$z.sbnd;C and C$z.sbnd;O bonds in surface species derived from ethanol on Pt(111) Alcala, R. Journal of Catalysis, Vol. 218, Issue 1 https://doi.org/10.1016/S0021-9517(03)00090-3	journal	August 2003
Mechanism of Ethanol Reforming: Theoretical Foundations Wang, Jeng-Han; Lee, C. S.; Lin, M. C. The Journal of Physical Chemistry C, Vol. 113, Issue 16 https://doi.org/10.1021/jp810307h	journal	March 2009
Combined DFT, Microkinetic, and Experimental Study of Ethanol Steam Reforming on Pt Sutton, Jonathan E.; Panagiotopoulou, Paraskevi; Verykios, Xenophon E. The Journal of Physical Chemistry C, Vol. 117, Issue 9 https://doi.org/10.1021/jp312593u	journal	February 2013
Current Status of Hydrogen Production Techniques by Steam Reforming of Ethanol: A Review Haryanto, Agus; Fernando, Sandun; Murali, Naveen Energy & Fuels, Vol. 19, Issue 5 https://doi.org/10.1021/ef0500538	journal	September 2005
A review on reforming bio-ethanol for hydrogen production Ni, Meng; Leung, Dennis Y. C.; Leung, Michael K. H. International Journal of Hydrogen Energy, Vol. 32, Issue 15 https://doi.org/10.1016/j.ijhydene.2007.04.038	journal	October 2007
Supported Single Pt ₁ /Au ₁ Atoms for Methanol Steam Reforming Gu, Xiang-Kui; Qiao, Botao; Huang, Chuan-Qi ACS Catalysis, Vol. 4, Issue 11 https://doi.org/10.1021/cs500740u	journal	October 2014
Hydrogen Formation in the Reactions of Methanol on Supported Au Catalysts Gazsi, A.; Bánsági, T.; Solymosi, F. Catalysis Letters, Vol. 131, Issue 1-2 https://doi.org/10.1007/s10562-009-0052-6	journal	June 2009
Charge Distribution between UV-Irradiated TiO ₂ and Gold Nanoparticles: Determination of Shift in the Fermi Level Jakob, Manuela; Levanon, Haim; Kamat, Prashant V. Nano Letters, Vol. 3, Issue 3 https://doi.org/10.1021/nl0340071	journal	March 2003
Photoelectrochemical cells Grätzel, Michael Nature, Vol. 414, Issue 6861 https://doi.org/10.1038/35104607	journal	November 2001
Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results Linsebigler, Amy L.; Lu, Guangquan.; Yates, John T. Chemical Reviews, Vol. 95, Issue 3 https://doi.org/10.1021/cr00035a013	journal	May 1995
Plasmonic-metal nanostructures for efficient conversion of solar to chemical energy Linic, Suljo; Christopher, Phillip; Ingram, David B. Nature Materials, Vol. 10, Issue 12 https://doi.org/10.1038/nmat3151	journal	November 2011
Visible-light-induced photocatalysis through surface plasmon excitation of gold on titania surfaces Kowalska, Ewa; Mahaney, Orlando Omar Prieto; Abe, Ryu Physical Chemistry Chemical Physics, Vol. 12, Issue 10 https://doi.org/10.1039/b917399d	journal	January 2010
Size dependence of Au NP-enhanced surface plasmon resonance based on differential phase measurement Zeng, Shuwen; Yu, Xia; Law, Wing-Cheung Sensors and Actuators B: Chemical, Vol. 176 https://doi.org/10.1016/j.snb.2012.09.073	journal	January 2013
Quasiquenching size effects in gold nanoclusters embedded in silica matrix Dhara, S.; Kesavamoorthy, R.; Magudapathy, P. Chemical Physics Letters, Vol. 370, Issue 1-2 https://doi.org/10.1016/S0009-2614(03)00104-0	journal	March 2003
Synthesis-Dependent Oxidation State of Platinum on TiO ₂ and Their Influences on the Solar Simulated Photocatalytic Hydrogen Production from Water Parayil, Sreenivasan Koliyat; Kibombo, Harrison S.; Wu, Chia-Ming The Journal of Physical Chemistry C, Vol. 117, Issue 33 https://doi.org/10.1021/jp405727k	journal	August 2013
Catalytic Role of Metal Oxides in Gold-Based Catalysts: A First Principles Study of CO Oxidation on ${T i O}_{2}$ Supported Au Liu, Zhi-Pan; Gong, Xue-Qing; Kohanoff, Jorge Physical Review Letters, Vol. 91, Issue 26 https://doi.org/10.1103/PhysRevLett.91.266102	journal	December 2003
Charge-carrier dynamics in titania powders Schindler, Karl Michael.; Kunst, Marinus. The Journal of Physical Chemistry, Vol. 94, Issue 21 https://doi.org/10.1021/j100384a045	journal	October 1990
Time-resolved infrared absorption study of nine TiO2 photocatalysts Yamakata, Akira; Ishibashi, Taka-aki; Onishi, Hiroshi Chemical Physics, Vol. 339, Issue 1-3 https://doi.org/10.1016/j.chemphys.2007.05.010	journal	October 2007
Electron–hole recombination in the bulk of a rutile TiO2 single crystal studied by sub-nanosecond transient absorption spectroscopy Katoh, Ryuzi; Murai, Miki; Furube, Akihiro Chemical Physics Letters, Vol. 461, Issue 4-6 https://doi.org/10.1016/j.cplett.2008.07.021	journal	August 2008
Explaining the Enhanced Photocatalytic Activity of Degussa P25 Mixed-Phase TiO ₂ Using EPR Hurum, Deanna C.; Agrios, Alexander G.; Gray, Kimberly A. The Journal of Physical Chemistry B, Vol. 107, Issue 19 https://doi.org/10.1021/jp0273934	journal	May 2003
Role of Platinum Deposited on TiO ₂ in Phenol Photocatalytic Oxidation Sun, Bo; Vorontsov, Alexandre V.; Smirniotis, Panagiotis G. Langmuir, Vol. 19, Issue 8 https://doi.org/10.1021/la0264670	journal	April 2003
Band alignment of rutile and anatase TiO2 Scanlon, David O.; Dunnill, Charles W.; Buckeridge, John Nature Materials, Vol. 12, Issue 9 https://doi.org/10.1038/nmat3697	journal	July 2013
Synergistic Effect of pH and Phase in a Nanocrystalline Titania Photocatalyst Kinsinger, Nichola M.; Dudchenko, Alexander; Wong, Ashley ACS Applied Materials & Interfaces, Vol. 5, Issue 13 https://doi.org/10.1021/am401247h	journal	June 2013
Crystalline Mixed Phase (Anatase/Rutile) Mesoporous Titanium Dioxides for Visible Light Photocatalytic Activity Luo, Zhu; Poyraz, Altug S.; Kuo, Chung-Hao Chemistry of Materials, Vol. 27, Issue 1 https://doi.org/10.1021/cm5035112	journal	December 2014
Light Illuminated α−Fe2O3/Pt Nanoparticles as Water Activation Agent for Photoelectrochemical Water Splitting Li, Xiaodong; Wang, Zhi; Zhang, Zemin Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep09130	journal	March 2015
Fabrication of Au/ZnO nanoparticles derived from ZIF-8 with visible light photocatalytic hydrogen production and degradation dye activities He, Liu; Li, Lu; Wang, Tingting Dalton Trans., Vol. 43, Issue 45 https://doi.org/10.1039/C4DT02557A	journal	January 2014

Cited By (4)

Oxide‐Supported Gold Clusters and Nanoparticles in Catalysis: A Computational Chemistry Perspective Tosoni, Sergio; Pacchioni, Gianfranco ChemCatChem, Vol. 11, Issue 1 https://doi.org/10.1002/cctc.201801082	journal	September 2018
Effect of metal nanoparticle size and titania crystallinity on the performance of Au/TiO ₂ catalysts for the promotion of carbon monoxide oxidation at cryogenic temperatures Lee, Ilkeun; Zaera, Francisco The Journal of Chemical Physics, Vol. 151, Issue 5 https://doi.org/10.1063/1.5114928	journal	August 2019
Photocatalytic Hydrogen Production: Role of Sacrificial Reagents on the Activity of Oxide, Carbon, and Sulfide Catalysts Kumaravel, Vignesh; Imam, Muhammad; Badreldin, Ahmed Catalysts, Vol. 9, Issue 3 https://doi.org/10.3390/catal9030276	journal	March 2019
Surface Plasmonic‐Assisted Photocatalysis and Optoelectronic Devices with Noble Metal Nanocrystals: Design, Synthesis, and Applications Zada, Amir; Muhammad, Pir; Ahmad, Waqas Advanced Functional Materials, Vol. 30, Issue 7 https://doi.org/10.1002/adfm.201906744	journal	December 2019

Similar Records

Atomically dispersed single iron sites for promoting Pt and Pt₃Co fuel cell catalysts: performance and durability improvements

Journal Article · Sat Jun 26 00:00:00 EDT 2021 · Energy & Environmental Science · OSTI ID:1303016

Qiao, Zhi; Wang, Chenyu; Li, Chenzhao; +14 more

Au and Pt Remain Unoxidized on a CeO₂-Based Catalyst during the Water–Gas Shift Reaction

Journal Article · Mon Dec 20 00:00:00 EST 2021 · Journal of the American Chemical Society · OSTI ID:1303016

Reina, Tomas R.; Gonzalez-Castaño, Miriam; Lopez-Flores, Victor; +7 more

In-situ and ex-situ comparison of the electrochemical oxidation of SO₂ on carbon supported Pt and Au catalysts

Journal Article · Thu Dec 12 00:00:00 EST 2019 · International Journal of Hydrogen Energy · OSTI ID:1303016

Meekins, Benjamin H.; Thompson, Anthony B.; Gopal, Varsha; +10 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Gold
platinum
supported catalyst
water-gas shift
steam reforming
water splitting

Title: Au and Pt nanoparticle supported catalysts tailored for H-2 production: From models to powder catalysts

Citation Formats

References (207)

Cited By (4)

Similar Records

Related Subjects