Materials Data on PuCoH24C4N6O13 by Materials Project
PuO2Co(NH3)2(NH3)3(CO2)3H2CO3NH7O2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six ammonia molecules, two ammonia dihydrate molecules, six formic acid molecules, two monohydrate methylene glycol molecules, two plutonium;dihydrate molecules, and two Co(NH3)2 clusters. In each Co(NH3)2 cluster, Co1+ is bonded in a distorted linear geometry to two equivalent N3- atoms. Both Co–N bond lengths are 1.73 Å. N3- is bonded in a 1-coordinate geometry to one Co1+ and three H1+ atoms. There are a spread of N–H bond distances ranging from 0.83–1.45 Å. There are three inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the third H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Organization:
- MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- OSTI ID:
- 1288343
- Report Number(s):
- mp-744896
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
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