Materials Data on V8O by Materials Project

Dataset · Tue Jul 14 00:00:00 EDT 2020

DOI:https://doi.org/10.17188/1286656· OSTI ID:1286656

The Materials Project

V8O crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. there are three inequivalent V sites. In the first V site, V is bonded in a distorted body-centered cubic geometry to eight V atoms. There are a spread of V–V bond distances ranging from 2.54–2.70 Å. In the second V site, V is bonded in a single-bond geometry to four equivalent V and one O atom. The V–O bond length is 1.95 Å. In the third V site, V is bonded in an L-shaped geometry to four equivalent V and two equivalent O atoms. Both V–O bond lengths are 2.13 Å. O is bonded to six V atoms to form edge-sharing OV6 octahedra.

• Research Organization: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
• Sponsoring Organization: USDOE Office of Science (SC), Basic Energy Sciences (BES)
• Contributing Organization: MIT; UC Berkeley; Duke; U Louvain
• DOE Contract Number: AC02-05CH11231; EDCBEE
• OSTI ID: 1286656
• Report Number(s): mp-714972
• Resource Relation: Related Information: https://materialsproject.org/citing
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
crystal structure
V8O
O-V