Materials Data on Rb4CdCl6 by Materials Project
Rb4CdCl6 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. there are three inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a 6-coordinate geometry to six Cl1- atoms. There are a spread of Rb–Cl bond distances ranging from 3.22–3.67 Å. In the second Rb1+ site, Rb1+ is bonded in a 6-coordinate geometry to six Cl1- atoms. There are a spread of Rb–Cl bond distances ranging from 3.18–3.91 Å. In the third Rb1+ site, Rb1+ is bonded in a 6-coordinate geometry to six Cl1- atoms. There are two shorter (3.12 Å) and four longer (3.47 Å) Rb–Cl bond lengths. Cd2+ is bonded in a square co-planar geometry to four Cl1- atoms. There are two shorter (2.50 Å) and two longer (2.63 Å) Cd–Cl bond lengths. There are three inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a 5-coordinate geometry to four Rb1+ and one Cd2+ atom. In the second Cl1- site, Cl1- is bonded to four Rb1+ atoms to form a mixture of distorted edge and corner-sharing ClRb4 trigonal pyramids. In the third Cl1- site, Cl1- is bonded in a 1-coordinate geometry to four Rb1+ and one Cd2+ atom.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Organization:
- MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- OSTI ID:
- 1280450
- Report Number(s):
- mp-644445
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
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