Materials Data on AgH4WS4N by Materials Project

Dataset · Thu Jul 16 00:00:00 EDT 2020

DOI:https://doi.org/10.17188/1280313· OSTI ID:1280313

The Materials Project

WAgS4NH4 is I4/mcm-derived structured and crystallizes in the tetragonal I-4 space group. The structure is one-dimensional and consists of two ammonium molecules and two WAgS4 ribbons oriented in the (0, 0, 1) direction. In each WAgS4 ribbon, W6+ is bonded to four equivalent S2- atoms to form WS4 tetrahedra that share edges with two equivalent AgS4 tetrahedra. All W–S bond lengths are 2.23 Å. Ag1+ is bonded to four equivalent S2- atoms to form distorted AgS4 tetrahedra that share edges with two equivalent WS4 tetrahedra. All Ag–S bond lengths are 2.56 Å. S2- is bonded in a distorted L-shaped geometry to one W6+ and one Ag1+ atom.

• Research Organization: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
• Sponsoring Organization: USDOE Office of Science (SC), Basic Energy Sciences (BES)
• Contributing Organization: MIT; UC Berkeley; Duke; U Louvain
• DOE Contract Number: AC02-05CH11231; EDCBEE
• OSTI ID: 1280313
• Report Number(s): mp-643431
• Resource Relation: Related Information: https://materialsproject.org/citing
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
crystal structure
AgH4WS4N
Ag-H-N-S-W