Materials Data on Ru(SCl3)4 by Materials Project
RuSCl4(SCl2)3Cl2 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four chlorine molecules, twelve sulfur dichloride molecules, and four RuSCl4 clusters. In each RuSCl4 cluster, Ru4+ is bonded in a distorted T-shaped geometry to three Cl1- atoms. There are a spread of Ru–Cl bond distances ranging from 2.37–2.42 Å. S2+ is bonded in a 2-coordinate geometry to two Cl1- atoms. There are one shorter (2.02 Å) and one longer (2.68 Å) S–Cl bond lengths. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Ru4+ atom. In the second Cl1- site, Cl1- is bonded in a distorted water-like geometry to one Ru4+ and one S2+ atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to one S2+ atom. In the fourth Cl1- site, Cl1- is bonded in a distorted single-bond geometry to one Ru4+ atom.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Organization:
- MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- OSTI ID:
- 1278263
- Report Number(s):
- mp-624474
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
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